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Kinetics of the oxidation of D ‐fructose by cerium(IV) has been investigated both in the absence and presence of surfactants (cetyltrimethylammonium bromide, CTAB, and sodium dodecyl sulfate, SDS) in sulfuric acid medium. The reaction exhibits first‐order kinetics each in [cerium(IV)] and [D ‐fructose] and inverse first order in [H2SO4]. The Arrhenius equation is found to be valid for the reaction between 30–50°C. A detailed mechanism with the associated reaction kinetics is presented and discussed. While SDS has no effect, CTAB increases the reaction rate with the same kinetic behavior in its presence. The catalytic role of CTAB micelles is discussed in terms of the pseudophase model proposed by Menger and Portnoy. The association constant Ks that equals to 286 mol?1 dm3 is found for the association of cerium(IV) with the positive head group of CTAB micelles. The effect of inorganic electrolytes (Na2SO4, NaNO3, NaCl) has also been studied and discussed. © 2005 Wiley Periodicals, Inc. Int J Chem Kinet 38: 18–25, 2006 相似文献
113.
铁基非晶稀土合金的结构转变和结构弛豫 总被引:1,自引:0,他引:1
通过对铁基非晶稀土合金结构转变和结构弛豫过程特征的研究,讨论了该材料的稳定性;认为稀土成份是影响合金品质和应用前景的关键因素。 相似文献
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Raif Kurtaran Cengiz Arici Sefa Durmu Din?er Ulkü Orhan Atakol 《Analytical sciences》2003,19(2):335-336
In the title compound, the coordination around the Cu atom is a distorted square-pyramid involving three N atoms from the ligand and one N atom from the azido group at the basal plane. The Cl atom is located at the apical position. The Cu atom is 0.32(5)A above the basal plane. There are three intramolecular and four weak intermolecular hydrogen bonds in the structure. IR spectra confirm the asymmetric N3 stretching vibrations of the terminal azide group. 相似文献
118.
M. Ashraf Chaudry Noor-ul-islam Din Mohammad 《Journal of Radioanalytical and Nuclear Chemistry》1987,112(1):11-22
Gamma-rays emitted from the surfaces of atmosphere-free extraterrestrial bodies such as asteroids, planets, or moons, can be measured to determine their chemical surface composition. Gamma-rays are emitted from naturally radioactive elements and, in their majority, are induced by the interaction of the energetic galactic cosmic particle radiation. Neutrons of the secondary hadron cascade contribute considerably to the gamma-ray line surface fluxes via nonelastic scattering and neutron-capture reactions. In principle, planetary gamma-ray spectroscopy resembles laboratory applications of prompt activation techniques. However, the evaluation of an orbital gamma-ray spectrum of other bodies than the Moon is difficult, as comparisons to so-called ground truth values, which functioned as standards, are not possible. Future planetary exploration missions will require the evaluation of recorded gamma-ray spectra without such standards. Therefore, in an attempt to overcome some of these difficulties, prompt gamma-ray spectra of planetary constituents were measured in a set of laboratory experiments with neutron-generator and cyclotron produced neutrons of energies up to 78 MeV. The significance of neutron-capture and nonelastic scattering gamma-ray lines for the characterization of major elements were established, and the application of the results to planetary gamma-ray spectroscopy of asteroids is discussed. 相似文献
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The excitation function for the reaction 12C(d, n0)13N was measured at 0° in the energy range of 3.6 to 12.0 MeV deuteron bombarding energy. Angular distributions were measured at 7.0, 8.0, 9.0, 10.5 and 12.0 MeV deuteron bombarding energies. Cross sections are compared with the 12C(d, p0)13C reaction. The yield curves for the neutron and proton groups show a strong similarity in shape. Different sets of deuteron and proton optical-model parameters were used in fitting the 8 MeV energy averaged angular distribution. 相似文献
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Yong?GuoEmail author Bingjun?Din Yongwen?Liu Xijun?Chang Shuangming?Meng 《Mikrochimica acta》2004,144(4):257-261
A novel chromogenic reagent, 2-(2-sulfo-4-acetylphenylazo)-7-(2,4,6-trichlorophenylazo)-1,8-dihydroxynaphthalene-3,6-disulfonic acid 1, was prepared by diazo coupling of 4-acetylaniline-2-sulfonic acid and 2,4,6-trichloroaniline to chromotropic acid through –N=N– groups. Based on this reagent, a simple, sensitive and selective spectrophotometric method was developed for the determination of lead. In 0.20M phosphoric acid medium, lead reacts with 1 to form a 1:2 blue complex with an absorption maximum of 654nm. Beers law is obeyed in the range of 0–0.6mgL–1 of lead. The apparent molar absorptivity is 1.25×105Lmol–1cm–1. The detection limit and quantification limit were found to be 0.63µgL–1 and 2.1µgL–1, respectively. The relative standard deviation for eleven replicate measurements was of 2.6%. The interference of foreign ions was also investigated. All the other foreign ions studied did not interfere with lead determination except for Ca(II) and Ba(II). The interference caused by Ca(II) and Ba(II) can be eliminated by prior extraction of lead with potassium iodide-methylisobutylketone (KI-MIBK). The proposed method was applied to the determination of lead in certified samples with satisfactory results. 相似文献