Melting and vaporization of salts in a U-LiCl-Li2O system

Summary The electrochemical reduction of uranium oxide in the treatment of spent nuclear fuel requires a characterization of the LiCl-Li₂O salt used as a reaction medium. Physical properties, melting and vaporization are important for the application of the salt and thus they have been investigated by differential scanning calorimetry (DSC) and thermogravimetry (TG), respectively. Experimental data suggest LiCl and Li₂O compound formations, leading to a melting point depression of the LiCl and a co-vaporization of the LiCl-Li₂O salt.     

Superselection rules in quantum theory: Part I. A new proposal for state restriction violation

It is argued that preparation of a quantum state characterized by density operator not commuting with a superselection operatorQ does not by itself constitute an instance of superselection rule violation. It would, however, be an instance of state restriction violation. It is held that superselection rule violation is only possible with simultaneous observable and state restriction violations. It is shown that it is a priori conceivable to subdivide an ensemble whose satisfies[, Q] = 0 into subensembles whose density operators violate the state restrictions. The dynamics of the subdivision process is not considered.     

New information-theoretic foundations for quantum statistics

When the state of a physical system is not fully determined by available data, it should be possible nevertheless to make a systematic guess concerning the unknown state by applying the principles of information theory. The resulting theoretical blend of informational and mechanical constructs should then constitute a modern structure for statistical physics. Such a program has been attempted by a number of authors, most notably Jaynes, with seeming success. However, we demonstrated in a recent publication that the standard list of so-called mutually exclusive and exhaustive quantum states that is commonly employed by these authors is in fact not exhaustive. It follows that the information-theoretic foundations of quantum statistics must be reformulated. The present paper discusses the fundamental problems involved and establishes a format for the correct application of information theory to quantum mechanical situations.Work supported by a grant from Research Corporation.     

A novel frequency-offset monitoring technique for direct-detection DPSK systems

We propose and demonstrate a novel technique to monitor the frequency offset between the optical source and delay interferometer (DI) for direct-detection differential phase-shift-keying (DPSK) systems. In this scheme, a phase-modulated tone is applied to DPSK signals at the transmitter and then detected after being converted into an amplitude-modulated tone at the DI to be used for the monitoring signal. Our experimental demonstration shows that the monitoring range and sensitivity of the proposed scheme are measured to be /spl plusmn/2 GHz and /spl sim/10 MHz, respectively, which we believe are good enough to be used either to generate alarm signals for the frequency offset monitoring or to control the feedback loop of the DI.     

A continuous-wave hybrid AlGaInAs-silicon evanescent laser

We report a novel laser architecture, the hybrid silicon evanescent laser (SEL), that utilizes offset AlGaInAs quantum wells (QWs) bonded to a silicon waveguide. The silicon waveguide is fabricated on a silicon-on-insulator wafer using a complimentary metal-oxide-semiconductor-compatible process, and is subsequently bonded with the AlGaInAs QW structure using low temperature O/sub 2/ plasma-assisted wafer bonding. The optical mode in the SEL is predominantly confined in the passive silicon waveguide and evanescently couples into the III-V active region providing optical gain. The SEL lases continuous wave (CW) at 1568 nm with a threshold of 23 mW. The maximum temperature for CW operation is 60/spl deg/C. The maximum single-sided fiber-coupled CW output power at room temperature is 4.5 mW.     

A miniature UWB planar monopole antenna with 5-GHz band-rejection filter and the time-domain characteristics

A planar monopole antenna with a staircase shape and small volume (25/spl times/26/spl times/1 mm/sup 3/) is proposed in this paper. With the use of a half-bowtie radiating element, the staircase-shape, and a modified ground plane structure, the proposed antenna has a very wide impedance bandwidth measured at about 11.6 GHz (2.9-14.5 GHz, bandwidth ratio about 1:5) below VSWR 2 including the WLAN band notched in the vicinity of 5 GHz. An omnidirectional radiation pattern is obtained. The group delay which is an indication of linearity between two proposed antennas is less than 1 ns. The electrical characteristics in terms of frequency and time domains and physical ones of the proposed antenna make it attractive for use in ultrawideband (UWB) systems.     

Intramitochondrial co-assembly between ATP and nucleopeptides induces cancer cell apoptosis

Mitochondria are essential intracellular organelles involved in many cellular processes, especially adenosine triphosphate (ATP) production. Since cancer cells require high ATP levels for proliferation, ATP elimination can be a unique target for cancer growth inhibition. We describe a newly developed mitochondria-targeting nucleopeptide (MNP) that sequesters ATP by self-assembling with ATP inside mitochondria. MNP interacts strongly with ATP through electrostatic and hydrogen bonding interactions. MNP exhibits higher binding affinity for ATP (−637.5 kJ mol⁻¹) than for adenosine diphosphate (ADP) (−578.2 kJ mol⁻¹). To improve anticancer efficacy, the small-sized MNP/ADP complex formed large assemblies with ATP inside cancer cell mitochondria. ATP sequestration and formation of large assemblies of the MNP/ADP–ATP complex inside mitochondria caused physical stress by large structures and metabolic disorders in cancer cells, leading to apoptosis. This work illustrates a facile approach to developing cancer therapeutics that relies on molecular assemblies.

Mitochondria-targeting nucleopeptide (MNP) can sequester ATP by self-assembling with ATP. A small nanosized MNP/ADP complex forms a large assembly with ATP. Thus, intramitochondrial co-assembly causes stress by large structures and apoptosis.     

Dual-wavelength cascaded Raman fibre laser

Dual-wavelength lasing at 1480 and 1500 nm has been demonstrated from a cascaded Raman fibre laser with a WDM coupler and two pairs of Bragg gratings. Intensity-adjustable, wavelength-tunable laser operation was achieved by tensile stress wavelength tuning of the gratings     

A formation of cobalt silicide on silicon field emitter arrays byelectrical stress

A novel process utilizing electrical stress is proposed for the formation of Co silicide on single crystal silicon (c-Si) FEAs to improve the field emission characteristics. Co silicide FEAs formed by electrical stress (ES) exhibited a significant improvement in turn-on voltage and emission current compared with c-Si FEAs. The improvement mainly comes from the lower effective work function of Co silicide and less blunting of tips during silicidation by electrical stress in an ultra high vacuum (UHV) environment less than 10^-8 torr