Dynamics of thin polymer films: Recent insights from incoherent neutron scattering

Incoherent neutron scattering is presented as a powerful tool for interpreting changes in molecular dynamics as a function of film thickness for a range of polymers. Motions on approximately nanosecond and faster timescales are quantified in terms of a mean-square atomic displacement (〈u²〉) from the Debye–Waller factor. Thin-film confinement generally leads to a reduction of 〈u²〉 in comparison with the bulk material, and this effect becomes especially pronounced when the film thickness approaches the unperturbed dimensions of the macromolecule. Generally, there is a suppression (never an enhancement) of 〈u²〉 at temperatures T above the bulk calorimetric glass-transition temperature (T_g). Below T_g, the reduction in the magnitude of 〈u²〉 depends on the polymer and the length scales being probed. Polymers with extensive segmental or local mobility in the glass are particularly susceptible to reductions of 〈u²〉 with confinement, especially at the Q vectors probing these longer length scales, whereas materials lacking these sub-T_g motions are relatively insensitive. Moreover, a reduced 〈u²〉 value correlates with reduced mobility at long time and spatial scales, as measured by diffusion in these thin polymer films. Finally, this reduced thin-film mobility is not reliably predicted by thermodynamic assessments of an apparent T_g, as measured by discontinuities or kinks in the T dependence of the thermal expansion, specific volume, index of refraction, specific heat, and so forth. These measurements illustrate that 〈u²〉 is a powerful and predictive tool for understanding dynamic changes in thin polymer films. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3218–3234, 2004     

Existence of multidimensional traveling waves in the transport of reactive solutes through periodic porous media

We prove the existence of multidimensional traveling-wave solutions to the scalar equation for the transport of solutes (contaminants) with nonlinear adsorption and spatially periodic convection-diffusion-adsorption coefficients under the assumption that the nonlinear adsorption function satisfies the Lax and Oleinik entropy conditions. In the nondegenerate case, we also prove the uniqueness of the traveling waves. These traveling waves are analogues of viscous shock profiles. They propagate with effective speeds that depend on the periodic porous media only up to their mean states, and are given by an averaged Rankine-Hugoniot relation. This is a direct consequence of the fact that the transport equation is in conservation form. We use the sliding domain method, the continuation method, spectral theory, maximum principles, and a priori estimates. In the degenerate case, the traveling waves are weak solutions of a degenerate parabolic equation and are only Holder continuous. We obtain them by taking suitable limits on the non-degenerate traveling waves. The uniqueness of the degenerate traveling waves is open.     

The Regular Near Polygons of Order (s, 2)

In this note we classify the regular near polygons of order (s, 2).     

MRI contrast-dose relationship of manganese(III)tetra(4-sulfonatophenyl) porphyrin with human xenograft tumors in nude mice at 2.0 T

Previously we reported that Mn(III)tetra(4-sulfonatophenyl) porphyrin, MnTPPS₄, is a contrast agent which can effectively enhance tumor detection by MRI. By imaging 30 additional athymic nude mice bearing subcutaneous MCF-7 WT human breast carcinoma xenografts, we have extended dose-contrast relationships over a wide range of intraperitoneal (IP) doses ranging from 0.025 to 0.50 mmol/kg. The benefits of IP injection are higher possible doses on a volume basis and a reduction in toxicity versus IV administration. Full coronal cross-section images have been obtained on a 2-T spectrometer. Although individual tumor masses displayed different distribution patterns, reflective of their internal morphology, single doses of 0.10 mmol/kg or greater were necessary to produce a detectable effect. At a dose of 0.50 mmol/kg, marked enhancement was produced. Multiple small dosages administered over the course of several days before imaging did not produce increased enhancement. Preliminary results on the new porphyrin derivative, MnTPPS₃, indicate that the ratio of the toxic dose to the effective dose may be adjustable to render this class of agents clinically useful.     

可信赖平台模块拒黑客于网外

病毒通过互联网侵袭计算机的报导时有所闻，令人们对网上商务活动更具戒心，何况电子商务往往涉及巨额交易。虽然PC及网络都采用灵活的设计，并对外开放，但这个灵活开放的优点也正是它的弱点。根据IDC 的调查资料显示，系统保安问题一直窒碍网上活动的发展，使电子商务以及其它网上应用程序无法进一步普及。一般计算机用户都知道他们每日收到的电子邮件之中，有很多都附加了暗藏的小应用程序附件，这些小应用程序利用探听文件，趁着计算机重新启动时收集用户密码及信用卡号码等资料。密码专家也发现最广泛使用的电子邮件加密程序 PGP …