基于角度切割MgO:PPLN晶体的高平均功率、稳定的连续波单振荡光学参量振荡器

报道了一台稳定的、高平均功率连续波光学参量振荡器,该振荡器为单谐振环形腔结构,参量晶体为角度切割的掺氧化镁周期性极化铌酸锂(MgO:PPLN),由一台波长为1064 nm的Nd:YVO4固态激光器泵浦。在9.8 W的泵浦功率下,可得到波长3069.1 nm的闲频光功率2.15 W,其泵浦-闲频光转换效率达21.0%。得益于腔内寄生振荡的减弱以及热自稳效应,振荡器的输出功率在30分钟内的稳定性优于0.19%均方根偏差(rms)。     

外辐射源雷达中基于八单元均匀圆阵天线的测角方法

提出了一种适用于外辐射源雷达的比幅测角方法,利用八单元均匀圆阵天线结合方向图综合技术形成覆盖全空域的十八个波束,用以对目标进行扫描.首先进行波束扫描、杂波相消、距离多普勒处理,然后在距离多普勒平面上进行测角.对参考信号中含有目标回波的情况进行了分析,参考信号中含有目标回波时原始比幅测角方法的测角精度将受到较大的影响,针对该问题,提出了修正的测角方法,修正测角方法与原始方法相比在参考信号含有目标回波时能够更加精确地测量得到目标的方位角.     

基于小波融合和PCA-核模糊聚类的遥感图像变化检测

本文提出了一种变化检测方法以提高算法的鲁棒性、检测精度以及抗噪性.首先对差值法构造的差异图和比值法构造的差异图进行小波融合.然后将融合图像分成互不重叠的小块,并用主成分分析得到图像块的正交基.通过将融合图像中每个像素的邻域小块映射到正交基上使得每个像素用一个特征向量来表示.最后用基于核的模糊C均值对特征向量进行聚类.实验结果显示与使用单一类型差异图的聚类方法相比,本方法由于采用了图像融合的策略而增强了鲁棒性,且由于采用了核模糊聚类,进一步提高了变化检测精度.此外由于使用了特征提取的技术,本方法具有一定的抗噪性能.     

块状高温超导体俘获磁通密度实验测试方法

块状单畴高温超导体的重要特性参数之一"俘获磁通密度"决定了单畴超导体能够冻结住的最大磁通俘获场,实际用户在设计装置时必须了解这些参数.然而,这些数值强烈地依赖于测试方法.随着国内块状单畴超导体的研究、生产、应用的不断发展,市场规模的不断扩大以及国际贸易的开展,迫切需要建立一个与国际接轨的测试标准,统一材料提供方与用户之间对单畴块材性能的表征过程.经国家标准化管理委员会批准,2013年全国超导标准化技术委员会将IEC 61788-9国际标准《SUPERCONDUCTIVITY-Measurements for bulk high temperature superconductors-Trapped flux density of large grain bulk oxide superconductors》(《超导电性:块状高温超导体的测量—大晶粒氧化物超导体的俘获磁通密度》)转化为国家标准,本文主要介绍有关"标准"的转化实施过程.     

Highly Efficient Synthesis of Optically Pure (S)-1-phenyl-1,2-ethanediol by a Self-Sufficient Whole Cell Biocatalyst

Terminal vicinal diols are important chiral building blocks and intermediates in organic synthesis. Reduction of α-hydroxy ketones provides a straightforward approach to access these important compounds. In this study, it has been found that asymmetric reduction of a series of α-hydroxy aromatic ketones and 1-hydroxy-2-pentanone, catalyzed by Candida magnolia carbonyl reductase (CMCR) with glucose dehydrogenase (GDH) from Bacillus subtilis for cofactor regeneration, afforded 1-aryl-1,2-ethanediols and pentane-1,2-diol, respectively, in up to 99 % ee. In order to evaluate the efficiency of the bioreduction, lyophilized recombinant Escherichia coli whole cells coexpressing CMCR and GDH genes were used as the biocatalyst and α-hydroxy acetophenone as the model substrate, and the reaction conditions, such as pH, cosolvent, the amount of biocatalyst and the presences of a cofactor (i.e., NADP⁺), were optimized. Under the optimized conditions (pH 6, 16 h), the bioreduction proceeded smoothly at 1.0 m substrate concentration without the external addition of cofactor, and the product (S)-1-phenyl-1,2-ethanediol was isolated with 90 % yield and 99 % ee. This offers a practical biocatalytic method for the preparation of these important vicinal diols.     

金等离子体的荷态分配数的计算

在非局域热动力学平衡(Non-LTE)下,采用类氢近似,计算得出电子密度分别为6.0×10~(20) cm~(-3)、1.4×10~(21) cm~(-3)、1.0×10~(22) cm~(-3)和1.7×10~(22) cm~(-3)的条件下的三体复合、辐射复合、双电子复合系数随电子温度的变化,得出总的复合系数随电子温度的变化关系;结合相关的电离系数得出相应的离子占有数的比,最后,计算出一定电子密度和温度条件下Au~(48+)～Au~(52+)离子的离子丰度,从而得到金等离子体的荷态分配数与电子温度和电子密度的关系.     

Determination of organochlorine pesticides in propolis by gas chromatography-electron capture detection using double column series solid-phase extraction

A rapid and reliable method was developed and applied for the simultaneous determination of 17 organochlorine pesticides (OCPs) in propolis. After extraction with hexane and acetone (1:1, v/v), four sorbents (florisil, silica, graphitized carbon, and tandem graphitized carbon plus florisil) were assayed for the clean-up step. The elution solvents hexane and ethyl acetate (1:1, v/v), hexane and dichloromethane (3:7, v/v), and ethyl acetate and hexane (2:8, v/v) were studied. The results showed that the combination of the tandem graphitized carbon and florisil cartridge with the elution solvent of 6mL of ethyl acetate and hexane (2:8, v/v), which was capable of eliminating matrix interference and providing colorless eluates, was the most efficient clean-up procedure for propolis extracts when testing for OCPs. The analytical technique employed was gas chromatography with electron capture detection (GC–ECD). The correlation coefficients from linear regression for the analyzed concentrations (5∼100 μg/kg) were >0.9961. The limits of detection (LODs) varied between 0.8 μg/kg for 4,4′-DDE and 11.4 μg/kg for endosulfan II, and the limits of quantitation (LOQs) ranged from 2.6 to 38.1 μg/kg. The average recoveries varied between 62.6 and 109.6%. Relative standard deviations (RSD%) ranged from 0.8 to 9.4%. Sample analysis indicated that 4,4′-DDE was detected more often in propolis than other pesticides, such as β-HCH, δ-HCH and heptachlor. Figure GC-ECD chromatogram of a standard solution with 0.1 mg/L of OCPs     

污染环境下具有脉冲输入环境毒素的单种群模型的灭绝阈值研究

本文研究了污染环境下具脉冲输入环境毒素的单种群模型.利用乘子理论和小振幅扰动法,当脉冲周期小于一个临界值时,我们得到了种群灭绝周期解是全局渐近稳定的,同时我们还得到了种群持久的条件.从生物学的观点看,污染环境下保护物种的方法是控制环境毒素的排放周期或排放量.我们的结论为资源环境下的生物资源管理提供了策略基础.     

具有奇数通道滤波功能的光子晶体量子阱结构研究

选择适当的结构参数,用传输矩阵法计算模拟光子晶体(AB)m(CD)n(BA)m模型的透射谱,在归一化中心频率1.0（ωa/2πc）处,当光子晶体(CD)n的导带处于光子晶体(AB)m(BA)m的禁带中,且两者均以中心频率处为对称中心时,构成镜像对称的光子晶体量子阱结构。在光量子阱透射谱的中心频率处及对称的两侧,分布着具有规律的奇数局域共振峰,出现明显的量子化效应,透过峰数目和位置都可以通过光子晶体(CD)n的重复周期数n来调节,这一现象可用于设计可调性奇数通道滤波器。     

光学读出红外成像中反光板变形对光学检测灵敏度的影响

在刀口滤波光学读出方法的基础上,讨论了反光板弯曲的情况下,刀口滤波方法的光学检测灵敏度与反光板长度之间的关系.分析表明,在反光板曲率半径一定的情况下,光学检测灵敏度首先随着反光板长度的增加而增大,达到最大值后随着反光板长度的增加而减小.对于不同曲率半径和长度的反光板,分析给出反光板长度L和曲率半径R在满足L2/R=λ(λ为照明光波长)时,光学检测灵敏度达到最大值.实验测量了已制作的像素尺寸分别为200μm,120μm和60μmFPA的光学检测灵敏度,其实验结果和理论分析一致.