Phase-Locked Fibre Array for Coherent Combination and Atmosphere Aberration Compensation

We report a fibre amplifier array that not only achieves coherent beam combination by compensation of phase noises of fibre amplifier, but also accomplishes correction of atmosphere aberration. It is of master-oscillatormultiple-amplifier （MOPA） configuration, which can be phase-locked by the multidither principle or heterodyne detection principle. First laboratory experiments of atmosphere aberration compensation of a three-element fibre amplifier array are reported. The atmosphere aberration is created by a phase screen in the experiment. The phase changes of the beam, which are introduced by the fibre amplifier and the phase screen, are both detected by the heterodyne detection method. Phase modulators are controlled to compensate for the phase in the three paths. No matter whether there is a phase screen producing atmosphere aberration or not, the dim dynamic interference fringes in the far field turn to a clear and stable pattern, and the peak intensity is maximized. It is indicated that the fibre amplifier array is phase-locked, and coherent combination of the three beams is achieved. It can be used not only to obtain high power fibre laser array but also in laser space communication.     

选择性远程DEPT~(13)C NMR新技术用于新阔叶千里光碱氮氧化合物的结构测定和谱峰归属研究

从湖北蟹甲草根茎中分得一个新的生物碱,选择性远程DEPT~(13)C NMR新技术用于识别NMR信号归属和连接被季碳及杂原子分割的质子自旋系统,确定其结构为新阔叶千里光碱的氮氧化物,如(1)所示。     

Mutually Pumped Phase Conjugation of Three Incoherent Beams with a Novel Photorefractive Crystal

Ｍｕｔｕａｌｌｙ　Ｐｕｍｐｅｄ　Ｐｈａｓｅ　Ｃｏｎｊｕｇａｔｉｏｎ　ｏｆ　Ｔｈｒｅｅ　Ｉｎｃｏｈｅｒｅｎｔ　Ｂｅａｍｓ　ｗｉｔｈ　ａ　Ｎｏｖｅｌ　Ｐｈｏｔｏｒｅｆｒａｃｔｉｖｅ　ＣｒｙｓｔａｌＭｕｔｕａｌｌｙＰｕｍｐｅｄＰｈａｓｅＣｏｎｊｕｇａｔｉｏ...     

铜(Ⅱ)-黄原酸配合物微粒体系的光谱研究及其在废水分析中的应用

采用分光光度法和共振散射光谱法研究了Cu(Ⅱ)-黄原酸配合物微粒体系。该配合物微粒体系在410nm处有一吸收峰,其吸光度与黄原酸浓度在1.0～40×10-5mol/L范围成良好线性关系,检出限(3σ)为0.5×10-5mol/L。据此建立了一个测定废水中黄原酸含量的分光光度法.该法灵敏、简便、快速、准确、重复性好,平均回收率为98%～100%,相对标准偏差RSD为0.9%～1.9%.共振散射光谱研究结果表明,该体系存在Cu(Ⅱ)-黄原酸配合物微粒,该微粒在360nm处存在共振散射效应.     

LiCoO2中锂离子固相扩散系数随循环次数的变化

The solid diffusion coefficient of lithium-ion in LiCoO₂ cathode material has been investigated by the capacity intermittent titration technique (CITT) at different voltages and at different charge/discharge cycles. By SEM, XRD and FTIR techniques, the structure of LiCoO₂ was studied before and after charge-discharge cycles, and the relationship between solid diffusion coefficient and crystal structure was further discussed. CITT results show that the value of Li⁺ solid diffusion coefficient of LiCoO₂ is about 10^-12 cm²·s^-1. During the whole charge-discharge cycles, the Li⁺ solid diffusion coefficient decreased within the voltage of 4.0～4.3 V, which is attributed to the change of the structure of LiCoO₂.     

纳米氧化铜的制备及常温脱硫效能研究

采用硝酸铜为原料、氢氧化钠溶液为沉淀剂、使用体积比为1∶1的乙醇-水溶液为分散剂的直接沉淀法制备，通过改变工艺条件得到了三种纳米氧化铜产品，平均粒径分别为25.63，10.74和7.57 nm。采用TG-DTA、FIR、XRD和TEM等对纳米氧化铜进行表征。对产品的常温脱硫活性进行了穿透试验，并与已开发的其他常温精脱硫产品进行了比较，结果表明纳米氧化铜应用于H₂S脱硫，可在常温条件下具有优异的脱硫活性，对H₂S的脱除精度可以达到0.05 mg·m^-3以下。经过优选，产品在3 000 h^-1空速下穿透硫容达到25.3%，高于同类型的其他脱硫剂产品。     

WS2 超细粉体的固相法合成

WS2 超细粉体的固相法合成;WS2;固相反应;过硫系数;高能球磨;粒度     

Current Trend in Synthesis,Post‐Synthetic Modifications and Biological Applications of Nanometal‐Organic Frameworks (NMOFs)

Since the early reports of MOFs and their interesting properties, research involving these materials has grown wide in scope and applications. Various synthetic approaches have ensued in view of obtaining materials with optimised properties, the extensive scope of application spanning from energy, gas sorption, catalysis biological applications has meant exponentially evolved over the years. The far‐reaching synthetic and PSM approaches and porosity control possibilities have continued to serve as a motivation for research on these materials. With respect to the biological applications, MOFs have shown promise as good candidates in applications involving drug delivery, BioMOFs, sensing, imaging amongst others. Despite being a while away from successful entry into the market, observed results in sensing, drug delivery, and imaging put these materials on the spot light as candidates poised to usher in a revolution in biology. In this regard, this review article focuses current approaches in synthesis, post functionalization and biological applications of these materials with particular attention on drug delivery, imaging, sensing and BioMOFs.