固态光聚合反应研究进展

光引发的固态聚合反应一直是令人感兴趣的研究领域.本文综述了固态光聚合的研究进展.着重介绍了双炔类体系,二烯类体系以及(甲基)丙烯酸酯体系的固态光聚合的研究工作以及应用前景.     

基于单片机的汽车防盗报警系统的设计与实现

针对汽车防盗及定位需求的日益增长,基于单片机微处理器、GPS、GPRS等技术,采用模块化的设计方案设计了汽车防盗报警系统,实现了实时定位、短信报警的功能,即系统采集到车辆被盗信息后,启动GPS定位模块,接收车辆位置信息（纬度、经度等）,单片机对该定位数据分析与处理后,通过GPRS网络以短信形式发送至车主手机。通过软硬件调试,系统运行数据显示,该系统实时性强、准确性高,车辆报警响应时间为秒级延时,定位误差在经纬度0．6度以内。     

具有断电续存功能固态存储器的设计

针对飞行器飞行过程中因偶然瞬时断电而导致已存储的数据会被覆盖记录的问题而提出了具有断电续存功能固态存储器的设计方案。以FPGA作为主控芯片,RS-422与LVDS作为硬件通信手段,NAND型FLASH为存储核心,着重在交替双平面存储方式的基础上通过编程实现了断电续存功能。经大量实测数据的科学分析表明,具有断电续存功能固态存储器的设计已成功实现,解决了瞬时断电后数据会被覆盖记录的问题,满足某型号飞行器的需要。     

Preparation of polyaniline grafted multiwalled carbon nanotubes and conductive application in polyetherimide

A methodology for improving antistatic property of polyetherimide (PEI) composite using polyaniline (PANI) grafted multi‐walled carbon nanotubes (MWNTs) as conductive medium was proposed. First, the MWNTs grafted with PANI (PANI‐g‐MWNTs) were prepared by in‐situ polymerization in an emulsion system. Subsequently, PANI‐g‐MWNTs were blended with PEI using N‐methyl‐2‐pyrrolidone as solvent. After removing the solvent, the PEI/PANI‐g‐MWNT composite was prepared. As assisted conductive medium, the grafted PANI molecular chains on MWNT surface were dispersed in the PEI matrix to decrease the percolation value of the antistatic composites. The structure and morphology of PANI‐g‐MWNTs were characterized by Fourier transform infrared spectroscopy, transmission electron microscope, thermogravimetric analysis, and X‐ray powder diffraction, respectively. The dispersion of PANI‐g‐MWNTs in PEI matrix was studied by scanning electron microscope. The electrical performance was characterized by highly resistant meter. The volume resistivity of the conductivity percolation threshold was 1.781 × 10^?8 S/cm when the loading of PANI‐g‐MWNTs was 1.0 wt%. The conductivity of PANI‐g‐MWNTs/PEI composites was found to be higher than that of pristine MWNTs/PEI composite. Copyright © 2012 John Wiley & Sons, Ltd.     

二硫化锡纳米片阻变存储器的制备与性能

采用水热法合成了尺寸为50~100 nm的二硫化锡纳米片,并首次以二硫化锡作为阻变层材料的阻变存储器（Cu/PMMA/SnS₂/Ag,PMMA=聚甲基丙烯酸甲酯）,对其阻变性能进行了研究。结果表明： Cu/PMMA/SnS₂/Ag阻变存储器的开关比约10⁵,耐受性2.7×10³。在上述2项性能指标达到较优水平的同时,开态与关态电压分别仅约为0.28与-0.19 V。     

甲基绿褪色光度法测定琥乙红霉素

在pH 7.8的磷酸盐缓冲溶液中,琥乙红霉素和甲基绿在50℃下可以反应形成稳定的离子缔合物。冷却至室温后以水做参比测定体系的吸收光谱,发现琥乙红霉素溶液在550~670 nm几乎无吸收,甲基绿在此区域有强烈的吸收,甲基绿与琥乙红霉素生成的离子缔合物的吸光度与甲基绿相比有明显降低,最大褪色波长在634 nm附近,且吸光度变化ΔA与琥乙红霉素的浓度成正比。琥乙红霉素的质量浓度在0.0009~0.1530 mg/mL范围内服从Beer定律,线性回归方程为:A=-3.037ρ+0.0355,r=0.9995;对10.00 mL 5.0×10-3mg/mL琥乙红霉素测定6次,RSD=0.6%,在634 nm测得ε=6.19×104L·mol-1·cm-1。研究了琥乙红霉素-甲基绿反应体系的光谱特性、反应的影响因素、共存物质的影响,做了反应的条件优化实验,对所建立的方法进行了一些初步的分析应用。在实验基础上,建立了测定琥乙红霉素的褪色分光光度法,检出限为0.21μg/mL,可用于琥乙红霉素片中琥乙红霉素含量的测定。     

(英)硫酸氢钾高效催化一锅法合成5-未取代的3,4-二氢嘧啶-2(1H)-酮

无溶剂条件下,硫酸氢钾可有效催化芳香醛、苯乙酮衍生物和脲的三组分"一锅法"Biginelli反应来合成5-未取代的3,4-二氢嘧啶-2(1H)-酮。确定了优化反应条件。产品结构经IR、1H NMR、MS和元素分析进行表征。     

Performance of the Zero Forcing precoding MIMO broadcast systems with channel estimation errors

In this paper, the effect of channel estimation errors upon the Zero Forcing (ZF) precoding Multiple Input Multiple Output Broadcast (MIMO BC) systems was studied. Based on the two kinds of Gaussian estimation error models, the performance analysis is conducted under different power allocation strategies. Analysis and simulation show that if the covariance of channel estimation errors is independent of the received Signal to Noise Ratio (SNR), imperfect channel knowledge deteriorates the sum capacity and the Bit Error Rate (BER) performance severely. However, under the situation of orthogonal training and the Minimum Mean Square Error (MMSE) channel estimation, the sum ca- pacity and BER performance are consistent with those of the perfect Channel State Information (CSI) with only a performance degradation.     

光子晶体光纤拉制参数对包层气孔结构的影响

分析了光子晶体光纤(PCF)拉丝工艺参数对光纤毛细管及最终结构的影响,结果表明,通过调节温度、送料速度和拉制速度等参数可以在一定程度上调整最终的气孔结构,但难以拉制出结构完善的PCF.为此提出了惰性气体施压法,实验表明,通过调节施压量的同时结合上述参数的调节,可有效控制光纤的结构参数,拉制出横纵向均匀性良好的PCF.     

大功率光纤放大器分段泵浦方式下的理论分析

利用数值算法计算了掺镱双包层光纤放大器分段泵浦方式下的稳态速率方程组,分析比较了双端泵浦和多段泵浦方式下的最佳光纤长度,最高温度和效率,并采用遗传算法对分布泵浦功率的大小和每段光纤长度同时进行了优化。结果表明,通过优化,大功率分段泵浦光纤放大器获得了较为平坦的温度分布,与双端泵浦相比,大大降低了最高工作温度,斜率效率略有下降。