4,4’-二氯二苯酮合成二氮杂萘联苯酮结构聚醚砜酮的研究

以4-(4-羟基苯基)*2,3-二氮杂萘-1-酮(DHPZ)、4,4’-二氯二苯砜(DCS)和4,4’-二氯二苯酮(DCK)为原料,采用分步加料的方法,合成了系列高分子量的聚芳醚砜酮共聚物(PPESKs),其特性黏度在0.40 ～0.61dL/g之间,解决了由于DCK活性低不适合用于聚芳醚合成的问题.采用FTIR、示差...     

可紫外光交联氟代聚芳醚的合成及性能研究

以丙酮酸、苯甲醚为原料合成了1,1-双(4-甲氧基苯基)(BMPE)乙烯单体,并通过去甲基反应得到了含可交联基团的二酚单体1,1-双(4-羟基苯基)乙烯(BHPE),并且用核磁共振、飞行质谱及元素分析表征了单体的结构,DSC测试了单体的熔点.并将BHPE与全氟联苯(DFBP)在氟化钾和氢化钙的催化作用低温下进行缩聚反应,得到了一种可紫外辐照交联的氟代聚芳醚.通过核磁共振证明了所合成的单体以及聚合物的结构,凝胶渗透色谱(GPC)测定了聚合物的分子量.傅立叶变换红外光谱分析了聚合物紫外辐照下的交联反应.所合成的氟代聚芳醚在室温下可溶于氯仿、四氢呋喃等有机溶剂,紫外交联后不溶于任何有机溶剂.且合成的聚合物具有良好的热稳定性能(玻璃化转变温度为160℃,交联后的5%热失重为465℃).     

Quantum wavepacket ab initio molecular dynamics for extended systems

In this paper, we introduce a symmetry-adapted quantum nuclear propagation technique that utilizes distributed approximating functionals for quantum wavepacket dynamics in extended condensed-phase systems. The approach is developed with a goal for implementation in quantum-classical methods such as the recently developed quantum wavepacket ab intio molecular dynamics (QWAIMD) to facilitate the study of extended systems. The method has been numerically benchmarked for extended electronic systems as well as protonic conducting systems that benefit from quantum nuclear treatment. Vibrational properties are computed for the case of the protonic systems through use of a novel velocity-flux correlation function. The treatment is found to be numerically accurate and efficient.     

关于良定问题

本文应用有限理性模型M,对非线性问题的良定性进行了统一的研究,对最优化、多目标最优化、非合作博弈和广义博弈得到了一些新的良定性结果.     

金融系统数学模型的机理分析与控制

基于金融系统数学模型的基本知识,讨论了模型的稳定性、耗散性等,同时进行机理分析;通过对参数和初值的取值,讨论了模型的线性、加速、双周期函数的反馈控制.数值模拟证实其有效性.     

C-N bond cleavage of allylic amines via hydrogen bond activation with alcohol solvents in Pd-catalyzed allylic alkylation of carbonyl compounds

Hydrogen-bond-activated C-N bond cleavage of allylic amines was realized in Pd-catalyzed allylic alkylation to form the C-C bond product. The method could be expanded to a series of allylic amines and carbonyl compounds with excellent results. It provides a new and convenient access to C-C bond formation based on Pd-catalyzed allylic alkylation of allylic amines by using only inexpensive alcohol solvents.     

Spare node cooperative method for IEEE 802.11 networks

Most of the existing cooperation methods select relay node(s) mainly based on the channel state information, but do not consider whether the selected relay nodes work or not. If the selected relays are invalidated, the performance of cooperative communication will deteriorate. To resolve the above problem, this paper investigates cooperative communication in IEEE 802.11 networks, and proposes a novel Spare Cooperative Method (SCM). SCM chooses a spare cooperation node to enhance the reliability of communication, and uses an enhanced handshaking mechanism to coordinate the access of source nodes and cooperation nodes to the wireless channel. The performance of SCM is comprehensively analyzed in terms of outage probability and saturated throughput. The analysis shows that SCM improves the performance of IEEE 802.11.     

SQL触发器在气象局仪表计量检定系统中的应用

山东省气象局计量检定系统是基于ASP.NET开发的,而温度实验室和风速风向实验室都用Visual Basic开发了客户端,为了将计量检定处各实验室的仪表检定客户端融入计量检定系统,设计了SQL触发器,方便的解决了系统集成问题。     

热空穴应力下LDD nMOSFET中GIDL电流退化特性研究*

本文通过GIDL电流参数IDIFF对空穴应力下LDD nMOSFET中的GIDL电流退化进行了深入研究。IDIFF是在相同VDG下漏电压VD=1.4V和栅电压VG=-1.4V两种情形下的GIDL电流之差。空穴陷落在栅漏交叠区的氧化层中导致GIDL电流退化。这些陷落的空穴减小了上述两种对称的测试情形下的横向电场差ΔEX从而使得IDIFF表小。从GIDL电流中提取的IDIFF随着应力时间t的增加而减小。IDIFF的退化量ΔIDIFF,MAX与应力时间成幂指数关系：ΔIDIFF,MAX∝tm, m=0.3. 并用热电子应力实验验证了HHS实验中的相关物理机理。     

Silver nanocrystals with concave surfaces and their optical and surface-enhanced Raman scattering properties

Shaped and dimpled: Silver nanocrystals enclosed by concave surfaces and thus high-index facets have been prepared by simply controlling the growth habit of Ag cubic seeds. Four types of concave nanocrystals, including octahedron, cube, octapod, and trisoctahedron, were obtained (see picture).