Synthesis, Structure and Biological Activities of Novel Triazole Compounds Containing N,N-Dialkyldithiocarbamate Moiety

Introduction As an important type of fungicides, triazole compounds are highly efficient, low poisonous and inward absorbent.1-3 At present, the studies on triazole derivatives are mainly concentrated on compounds with triazole as the only active group. The report of triazole compounds that contain both triazole group and other active group in a single molecule has rarely been found. Dialkyl-substituted dithiocarbamate salts have also shown interesting biological effects.4 N,N-Dialkyldithio-…     

Investigations on Preparation,Crystal Structure and Thermal Stability of Bis(O-ethylcarbonodithiolato-S,S′)(1,10-phenanthroline-N~1,N~(10))cobalt(II) Complex:[Co(Et-XA)_2·phen]·H_2O (XA=xanthate)

IntroductionTheincreasingcommercialvalueoftransitionmetalcomplexesofxanthateshasarousedconsiderableinterestintheirchemistry .Whiletheiranalyticalapplicationsarewellknown ,1theyarenowfindingextensiveuseinvulcan izationofrubber ,frothfloatationprocessforconcentrationofsulphideores ,asantioxidants ,lubricants ,2 ,3andhavebeenfoundtopossessfungicidalandinsecticidalactivi ties .4 Recently ,molecularrecognitionbetweenhostandguestmolecules ,inclusionphenomenaandnoncovalentmolecularinteractionarefunda…     

The influence of cetyltrimethyl ammonium bromide on electrochemical properties of thyroxine reduction at carbon nanotubes modified electrode

The effect of cetyltrimethyl ammonium bromide (CTAB) on the electrochemical behaviors of thyroxine at a glassy carbon electrode (GCE) modified with single-walled carbon nanotubes (SWNTs) was investigated. At the SWNTs film-coated GCE, a well-defined oxidation peak of thyroxine at 0.78 V was obtained, but the reduction peak of thyroxine was indiscernible. When trace CTAB was added to the working solution, the reduction current could be greatly enhanced and the oxidation current remained stable. The reaction mechanisms for the reduction of thyroxine were explored by chronocoulometry. Thyroxine might form particular ion complex with CTAB via the interaction between iodine atoms on thyroxine and bromide ions in CTAB, which made the concentration of thyroxine at the surface of the modified electrode increased and the electron transfer rate enhanced. The proper mechanisms for the enhanced reduction of thyroxine in the present of CTAB were explored by several electrochemical techniques including cycle voltammetry linear sweep voltammetry and others. It was concluded that the special interactions between the thyroxine CTAB and SWNTs resulted in the increase of the reduction peak current. All results indicated that two iodine atoms on the thyroxine and four electrons were involved the reduction process which was irreversible and two iodine ions produced. In this system, the sensitive reduction peak of thyroxine at 0.3 V was employed to determine thyroxine and a low detection limit of 2x10(-8) mol/L was obtained for 2 min accumulation at 0.9 V. The SWNTs coated GCE had good stability and reproducibility.     

Synthesis and Crystal Structure of 2-Chloromethyl-1H-benzimidazole Nitrate, [ClCH_2(C_7H_6N_2)]NO_3

1 INTRODUCTION Benzimidazole is an interesting heterocyclic compound because it is found in various naturally occurring drugs, such as omeprazole, astemizole and emedastine difumarate[1]. The efficacy of sub- stituted benzimidazoles in the treatment of parasitic infections is well known[2～4]. Substituted benzimid- azole moieties are established pharmacophores in parasitic chemotherapy. Bis(2-benzimidazole) and some substituted bis(benzimidazol-2-yl)alkanes have attracted much interest …     

Synthesis and Properties of Polyetherketones Containing Sulfide and Phthalazinone

High molecular weight copoly(ether ketone)s (PEK) based on 4-(4-hydroxyphenyl)-1-phthalazinone (DHPZ)/4,4′-thiobisphenol (TBP)/4,4′-diflourodiphenylketone (DFK) were prepared by nucleophilic substitution polycondensation. The copolymers were characterized by FT- and ^1H-NMR. Thermal properties and solubility of copolymers were studied.     

RZ-DPSK传输系统相位噪声的比较分析

建立了单信道40Gbit／s归零-差分相移键控码（RZ-DPSK）传输系统模型，详细地分析并比较了线性相位噪声和非线性相位噪声对系统性能的影响。结果表明，由放大器自发辐射（ASE）噪声带来的线性相位噪声对传输系统的性能影响最大，ASE与自相位调制（SPM）相互作用引起的Gordon-Mollenauer（G-M）相移次之，带内四波混频（IFWM）的影响最小。在最优输入功率的条件下，由ASE带来的线性相位噪声引起的系统差分相位Q值代价大于204dB，由G-M相移引起的系统差分相位Q值代价小于7．5dB。仿真结果表明，对于采用掺铒光纤放大器（EDFA）级联放大的单信道40Gbit／s RZ-DPSK传输系统，ASE噪声是限制系统无中继传输距离的最主要因素。     

基于海天线提取和混合灰度差的船舶检测方法

为了快速、准确检测海天背景下远距离水平观测的船舶目标,提出了一种基于海天线提取和混合灰度差的船舶检测方法.首先,利用边缘检测算法将图像分为天空、海天线和海面三个区域,并根据海天区域连接点,采用直线拟合方法确定海天线的直线参数;然后提取海天线区域作为目标感兴趣区域,并在去除海面杂波和噪声等干扰后利用混合灰度差水平投影和垂...     

基于PZT陶瓷谐振技术的光纤相位调制器研究

分析影响了基于压电陶瓷谐振换能器的光纤相位调节的主要参数,并根据参数研制出一种满足性能要求的压电陶瓷光纤相位调制器.结果表明,光纤伸长位移量与光纤直径、压电常数、工作电压及陶瓷直径有关,与压电陶瓷的厚度无关;压电陶瓷光纤相位调制器的具有工作频率高(100 kHz以上),驱动电压低(2～3 V),电容小,介电损耗小,自滤波谐振等特点.     

矩形波导窄边倾斜缝隙天线阵的设计

介绍了一种矩形波导窄边斜缝泰勒线阵设计的方法.简要阐述了矩形波导窄边缝隙天线阵列的相关理论,并使用HFSS软件对单个缝隙结构,无限阵列环境下缝隙单元的导纳参数进行数值仿真.然后按照仿真获得的等效谐振电导曲线,运用泰勒线元法综合求出非谐振式48元波导窄边缝隙线阵,并对整个线阵进行了仿真和实测.仿真和实测结果表明,该天线阵列具有低副瓣、宽带宽、高增益等特点,并且实测结果与仿真吻合良好.     

运用长周期光纤光栅实现EDFA的增益平坦化

针对Perilli公司生产的OP 980型掺铒光纤放大器 (EDFA)的增益谱不平坦特性 ,运用紫外写入的方法研制成使其增益平坦化的长周期光纤光栅增益平坦化器件 ,实现了该掺铒光纤放大器在 30nm范围内的增益谱波动小于± 0 4dB。