An Enantioselective Assembly of Dihydropyranones through an NHC/LiCl‐Mediated in situ Activation of α,β‐Unsaturated Carboxylic Acids

A straightforward N‐heterocyclic carbene (NHC)/LiCl‐mediated synthesis of dihydropyranones from α,β‐unsaturated carboxylic acids and 1,3‐dicarbonyl compounds was realized through the in situ activation strategy. The key advantages of this protocol include ready availability and high stability of starting materials, good yields, and excellent enantioselectivity.     

Recovery and separation of erythromycin from industrial wastewater by imprinted magnetic nanoparticles that exploit β‐cyclodextrin as the functional monomer

A type of surface imprinting over magnetic Fe₃O₄ nanoparticles utilizing erythromycin‐A as a template for use in the separation and recovery of erythromycin was developed and investigated. As the intermolecular forces play a key role in the performance of imprinted materials, differential scanning calorimetry, and ¹H NMR spectroscopy was employed to evaluate the interactions between erythromycin and the functional monomer β‐cyclodextrin. To synthesize the surface imprinted polymers, magnetic Fe₃O₄ nanoparticles, the core materials, were modified with a free radical initiator to initialize polymerization in a “grafting from” manner. Then using acryloyl‐modified β‐cyclodextrin as the functional monomer and ethyleneglycol dimethacrylate as the cross‐linker, thin erythromycin‐imprinted films were fabricated by the radical‐induced graft copolymerization of monomers on the surface of the Fe₃O₄ nanoparticles. Selectivity experiments showed that the erythromycin‐A‐imprinted materials had recognition ability toward erythromycin derivatives. Finally, these magnetic molecularly imprinted particles were successfully used for the separation and enrichment of erythromycin from the mother liquor. The recovery, detected by high‐performance liquid chromatography and differential pulse voltammetry, approached 97%. The combination of the specific selectivity of the imprinted material and the magnetic separation provided a powerful tool that is simple, flexible, and selective for the separation and recovery of erythromycin.     

相对论夸克模型中底奇异介子的辐射衰变(英文)

系统地研究了相对论夸克模型框架下的底奇异介子的辐射衰变。给出了底奇异介子E1 和M1 辐射衰变分宽度。这些结果表明,大多数电偶极辐射衰变宽带能达到数个keV,大多数磁偶极辐射衰变宽度小于1 个keV,这为实验上通过辐射衰变寻找底奇异介子提供了理论依据。建设中的Belle II 上的实验可以进一步验证我们的结果。We systematically study the radiative transitions of bottom-strange mesons in the framework of the relativistic constituent quark model. The partial widths of the E1 and M1 decays are predicted. The results predict that most of E1 decay widths are several keV and most of M1 decay widths are less than 1 keV,which give a roadmap of searching for the higher bottom-strange mesons via radiative decays. The experimental searches by the forthcoming Belle II can in turn provide further tests to our result in the present work.     

阵列光开关驱动结构制作工艺的研究

采用KOH溶液湿法腐蚀制作阵列光开关的微反射镜上电极.腐蚀表面的不平整影响了光开关的驱动扭臂结构的制作.采用合理配比的HF,HNO3和CH3COOH腐蚀剂对制作的微反射镜阵列硅片进行抛光处理,抛光后微反射镜表面和腐蚀的(110)面均有较大的改善,并且抛光不影响器件的结构,最后制作出了均匀一致的光开关阵列扭臂驱动结构.     

光纤光栅传感解调系统的研究进展

光纤光栅传感以其强大的优越性受到了社会的广泛关注,波长编码信号解调是实现光纤光栅多参量、多点分布式传感网络的关键技术.综述了光纤光栅传感信号解调技术的研究进展,对几种较成熟的解调方法的工作机理、特点和性能作了重点分析,分别给出了典型的实验原理图,并对其应用前景作了展望.     

An efficient and chemoselective synthesis of N-substituted 2-aminopyridines via a microwave-assisted multicomponent reaction

A facile and selective synthesis of N-substituted 2-aminopyridines is accomplished via microwave-assisted multi-component reactions controlled by the basicity of amine and the nature of solvent. In addition, a possible mechanism accounting for the reaction was proposed.     

Synthesis of Furano[3,2-c]- and Pyrano[3,2-c]quinolines upon Imino Diels-Alder Reactions Initiated by Nitrosonium （NO^＋）

Efficient nitrosonium （NO＋）-initiated aza-Diels-Alder reactions of N-arylimines with 2,3-dihydrofuran or 3,4-dihydro-2H-pyran allowed access to furano[3,2-c]- or pyrano[3,2-c]quinolines. A mixture of cis and trans-quinoline isomers was obtained in various ratios and yields.     

半线性抛物型方程组解的整体存在性与爆破速率估计

研究了具有非线性热源的半线性抛物型方程组的齐次neumann问题解的爆破性质.利用上下解方法得到了解整体存在的条件与爆破条件,并利用FriedmannMcleod方法建立了爆破速率估计.     

利用FEL康普顿背散射实现对NSRL辐射波段的扩展

 针对NSRL同步辐射光源不能开展硬X射线领域实验研究的缺点,提出了利用FEL康普顿背散射产生高亮度极化的硬X射线,并利用FEL波长可调的特点来连续调节硬X射线的波长。同时还针对NSRL光源的参数,提出了一个初步可行的远红外FEL参数和背散射工作方式,并给出了理论结果。     

ICP-AES法测定萤石中的主次成分

萤石通过醋酸加热使ＣaＣＯ３溶解,再经过滤、沉淀、烘干,以碳酸钠、硼砂混合熔剂熔 融,酸学好以后,采用ＩＣＰ－ＡＥＳ法测定碳酸钙、氟化钙及二氧化硅、三氧化铁。此方法精密度好,回收率在９６．０％－１０１．４％之间。