全文获取类型
收费全文 | 16033篇 |
免费 | 2630篇 |
国内免费 | 2537篇 |
专业分类
化学 | 8572篇 |
晶体学 | 246篇 |
力学 | 564篇 |
综合类 | 172篇 |
数学 | 1389篇 |
物理学 | 4559篇 |
无线电 | 5698篇 |
出版年
2024年 | 49篇 |
2023年 | 283篇 |
2022年 | 467篇 |
2021年 | 571篇 |
2020年 | 564篇 |
2019年 | 633篇 |
2018年 | 476篇 |
2017年 | 530篇 |
2016年 | 594篇 |
2015年 | 802篇 |
2014年 | 972篇 |
2013年 | 1210篇 |
2012年 | 1374篇 |
2011年 | 1323篇 |
2010年 | 1264篇 |
2009年 | 1232篇 |
2008年 | 1344篇 |
2007年 | 1272篇 |
2006年 | 1092篇 |
2005年 | 916篇 |
2004年 | 722篇 |
2003年 | 535篇 |
2002年 | 481篇 |
2001年 | 418篇 |
2000年 | 342篇 |
1999年 | 281篇 |
1998年 | 201篇 |
1997年 | 153篇 |
1996年 | 181篇 |
1995年 | 155篇 |
1994年 | 127篇 |
1993年 | 135篇 |
1992年 | 101篇 |
1991年 | 70篇 |
1990年 | 57篇 |
1989年 | 52篇 |
1988年 | 43篇 |
1987年 | 33篇 |
1986年 | 28篇 |
1985年 | 29篇 |
1984年 | 20篇 |
1983年 | 17篇 |
1982年 | 9篇 |
1981年 | 10篇 |
1980年 | 6篇 |
1979年 | 10篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1959年 | 2篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 359 毫秒
11.
Facile fabrication of fast recyclable and multiple self‐healing epoxy materials through diels‐alder adduct cross‐linker
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Xiao Kuang Guoming Liu Xia Dong Xianggui Liu Jianjun Xu Dujin Wang 《Journal of polymer science. Part A, Polymer chemistry》2015,53(18):2094-2103
A reversibly cross‐linked epoxy resin with efficient reprocessing and intrinsic self‐healing was prepared from a diamine Diels‐Alder (DA) adduct cross‐linker and a commercial epoxy oligomer. The newly synthesized diamine cross‐linker, comprising a DA adduct of furan and maleimide moieties, can cure epoxy monomer/oligomer with thermal reversibility. The reversible transition between cross‐linked state and linear architecture endows the cured epoxy with rapid recyclability and repeated healability. The reversibly cross‐linked epoxy fundamentally behaves as typical thermosets at ambient conditions yet can be fast reprocessed at elevated temperature like thermoplastics. As a potential reversible adhesive, the epoxy polymer with adhesive strength values about 3 MPa showed full recovery after repeated fracture‐thermal healing processes. The methodology explored in this contribution provides new insights in modification of conventional engineering plastics as functional materials. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2094–2103 相似文献
12.
Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface. 相似文献
13.
Video transmission over IEEE 802.11e wireless networks still shows poor performance for large bandwidth demand and frequently changed environments. Thus, several enhancements of IEEE 802.11e were proposed. On the other hand, big frames and simultaneous sending of adjacent frames always cause packet dropping for buffer overflow. In the past, we proposed an IEEE 802.11e enhancement named DFAA and a content aware mechanism to solve the above problems. The motivation of this paper is to find a proper way to integrate these two mechanisms. A DFAA enhancement (DFAA-E) is proposed to make up the insufficiency of content aware mechanism. Experiments results show that the combination of DFAA-E and content aware mechanism improves the video decoded quality greatly. And its performance can be further enhanced by selecting the suitable settings of certain parameters. 相似文献
14.
15.
In colloidal suspensions of silica, particles undergo constant collisions. By controlling various parameters, the repulsive barrier can be reduced, thereby substantially increasing the number of collision‐induced dimerization events. Xia and co‐workers report on p. 1627 that the dimers could be arrested and then permanently fixed by introducing a small amount of fresh tetraethylorthosilicate into the colloidal suspension, with monodisperse dimer yields of up to 50 %. This yield could be increased to 80 % by centrifugation in a density gradient medium. When fresh tetraethylorthosilicate is introduced into a colloidal suspension of silica spheres, it hydrolyzes and condenses in situ to arrest and fix the dimers resulting from constant collisions between the spheres. By optimizing the experimental parameters (including the length of aging time) and the diameter of the silica spheres, as well as the concentrations of counterions, water, and ammonia, it is possible to routinely produce monodisperse dimers with a yield as high as 50 %. When combined with centrifugation using a density gradient medium, the yield of such dimers could be further increased to 80 %. It is believed that this method will provide a simple and versatile approach to the high‐volume production of dimers from spherical colloids composed of different materials. These dimers may find widespread use in a range of applications such as fabrication of photonic crystals and fundamental studies related to colloidal science. 相似文献
16.
17.
18.
Image registration by "Super-curves" 总被引:4,自引:0,他引:4
Minghui Xia Bede Liu 《IEEE transactions on image processing》2004,13(5):720-732
We solve the 2-D affine image registration problem by curve matching and alignment. Our approach starts with a super-curve, which is formed by superimposing two affine related curves in one coordinate system. We use B-spline fusion technique to find a single B-spline approximation of the super-curve and a registration between the two curves simultaneously. This approach achieves superior accuracy and efficiency in curve matching and alignment. We then address the occlusion problem by finding partial match between the curves segmented using inflections and cusps, which are affine invariant. The combination of edge detection and curve alignment lead to accurate image registration. 相似文献
19.
精细功能陶瓷的若干发展趋势 总被引:5,自引:1,他引:4
概括了分析自90年代初以来精细功能陶瓷的发展趋势,提出了一些相关的研究领域。 相似文献
20.
ZHAO Shan-Rong CHEN Kai-Xian JIANG Hua-Liang WANG Qin-Mi JI Ru-YunShanghai Institute of Materia Medica Chinese Academy of Sciences Shanghai China 《中国化学》1997,15(1):84-89
We have used quantum mechanical method to study the transition states(TSs) of uridine phosphorolysis reaction. Comparing the four different reaction pathways and the five transition states obtained, we conclude that enzymatic uridine phosphorolysis takes place mainly according to acid-catalyzed SN2 mechanism. The proposed reaction pathway is consistent with many experimental results. 相似文献