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991.
D.G. Seapy S.S.H. Al-Mahmoodi N.M.M. Al-Belushi F.A.M. Al-Mjeni 《Journal of photochemistry and photobiology. A, Chemistry》1994,80(1-3):241-249
The relatives photoreactives of bridged-ring systems 1, 3, 5-X and 6-X (X ≡ Cl or Br) have been studied at 254 nm in acetic acid. The formation of photosolvolysis product was rationalized in terms of photoinduced intramolecular electron transfer (ET) processes. The relative ease of ET in these donor—bridge—acceptor model system was analyzed in terms of known ET variables including free-energy changes, orientation effects and ridigity effects. The observed relative photoreactivities agreed better with the calculated free-energy changes when relative rigidities of the electron acceptor termini were evaluated. In general, the more rigid system were more photoreactive. 相似文献
992.
993.
994.
995.
Conlon P.J. Tong Y.P. French P.M.W. Taylor J.R. Shestakov A.V. 《Electronics letters》1994,30(9):709-710
Sub-100 fs pulse generation from a Kerr lens modelocked Cr4+ :YAG laser has been demonstrated for the first time, yielding femtosecond pulses tunable from 1.49 to 1.56 μm with pulses as short as 90 fs obtained at 1.53 μm 相似文献
996.
Langanay J. Brindel P. Brun E. Provost J.G. Lesterlin D. Hamaide J.P. 《Electronics letters》1994,30(19):1599-1601
The variability of optical frequency modulation with electric field in an electro-optical phase section is analysed. When configured for maximum sensitivity, the electro-optical phase section was used to compensate for the chirp of the gain section: 48 ps and 8.5 GHz wide transform-limited pulses were obtained at 5 GHz 相似文献
997.
A general finite element approach to computing the modes of open-boundary waveguides is presented. This efficient and robust scheme applies equally to situations with real and complex propagation constants. By using a localised boundary impedance condition, the approach preserves the sparsity of the global matrices. A comparison with the well established infinite element technique and the analysis of a 2-D leaky optical structure are given as examples 相似文献
998.
999.
Since the early demonstrations of our concept of pulsed microwave catalysis in chemistry, we have witnessed the coming of age of the technique as an enabling technology in the industrial world, despite the inadequate understanding of the basic mechanisms of how microwaves interact with metallic surface sites and the subsequent energy transfer. We shall present here some very recent developments of the microwave-induced acoustic technique and its applications to a better understanding of the basic surface heating and energy transfer phenomena in pulsed microwave catalytic systems. 相似文献
1000.
H.-J. Kluge B. A. Bushaw G. Passler K. Wendt N. Trautmann 《Fresenius' Journal of Analytical Chemistry》1994,350(4-5):323-329
Resonance ionization spectroscopy (RIS) and its combination with mass spectrometry (RIMS) have grown to become powerful techniques, which offer high sensitivity as well as elemental and isotopic selectivity. The principles of RIS and RIMS are introduced; they primarily concern the analysis of the optical spectra for the choice of efficient excitation schemes and the suitable design of the experimental apparatus. Recent applications span from studies of short-lived isotopes at on-line mass separators to a wide variety of trace analysis applications for radioactive isotopes, which can range from measurements of solar neutrino flux to environmental assessment.On leave from Pacific Northwest Laboratory, Richland, USA 相似文献