Buckling of a stiff thin film on a compliant substrate in large deformation

A finite-deformation theory is developed to study the mechanics of thin buckled films on compliant substrates. Perturbation analysis is performed for this highly nonlinear system to obtain the analytical solution. The results agree well with experiments and finite element analysis in wavelength and amplitude. In particular, it is found that the wavelength depends on the strain. Based on the accurate wavelength and amplitude, the membrane and peak strains in thin films, and stretchability and compressibility of the system are also obtained analytically.     

Multi-layer thin films/substrate system subjected to non-uniform misfit strains

Current methodologies used for the inference of thin film stress through curvature measurement are strictly restricted to stress and curvature states that are assumed to remain uniform over the entire film/substrate system. These methodologies have recently been extended to a single layer of thin film deposited on a substrate subjected to the non-uniform misfit strain in the thin film. Such methodologies are further extended to multi-layer thin films deposited on a substrate in the present study. Each thin film may have its own non-uniform misfit strain. We derive relations between the stresses in each thin film and the change of system curvatures due to the deposition of each thin film. The interface shear stresses between the adjacent films and between the thin film and the substrate are also obtained from the system curvatures. This provides the basis for the experimental determination of thin film stresses in multi-layer thin films on a substrate.     

Closed-form solutions for a rectangular layer with central crack under anti-plane shear stress

We consider the problem of determining the stress distributionin a finite rectangular elastic layer containing a Griffithcrack which is opened by internal shear stress acting alongthe length of the crack. The mode III crack is assumed to belocated in the middle plane of the rectangular layer. The followingtwo problems are considered: (A) the central crack is perpendicularto the two fixed lateral surfaces and parallel to the othertwo stress-free surfaces; (B) all the lateral surfaces of therectangular layer are clamped and the central crack is parallelto the two lateral surfaces. By using Fourier transformations,we reduce the solution of each problem to the solution of dualintegral equations with sine kernels and a weight function whichare solved exactly. Finally, we derive closed-form expressionsfor the stress intensity factor at the tip of the crack andthe numerical values for the stress intensity factor at theedges of the cracks are presented in the form of tables.     

Combined supercritical-fluid chromatography/mass spectrometry in the analysis of diuron in plasma using on-line phase-system switching

On-line sample pretreatment by means of the phase-system switching approach is an interesting technique for the analysis of aqueous samples, e.g., plasma, by means of supercritical-fluid chromatography. In order to analyse plasma samples the following analytical procedure is used. The plasma sample is injected on to a short precolumn, which is washed with water and subsequently dried with nitrogen. Next, the solutes are desorbed with the supercritical mobile phase, analysed with packed-column supercritical-fluid chromatography and detected with either a UV detector or a mass spectrometer, equipped with a moving-belt interface. The herbicide diuron is selected as a test compound to study the feasibility of this approach. Using a selective detector the procedure is sufficiently sensitive to detect diuron in plasma, but not appropriate to detect the diuron metabolites in a post-mortem plasma sample. These have been identified with liquid chromatography/mass spectrometry. The detection limit of diuron in plasma using the procedure described is about 30 ng/mL.     

Characterization of thermal diffusion in polymer solutions by thermal field-flow fractionation: Dependence on polymer and solvent parameters

The thermal diffusion coefficient D_T has been obtained for 17 polymer-solvent combinations, each of them spanning a range of polymer molecular weights, using thermal field-flow fractionation. The polymers examined include polystyrene, poly(alpha-methyl)styrene, polymethylmethacrylate, and polysioprene. The solvents include benzene, toluene, ethylbenzene, tetrahydrofuran, methylethylketone, ethylacetate, and cyclohexane. Although D_T was confirmed as essentially independent of polymer molecular weight, it was found to vary substantially with the chemical composition of polymer and solvent. The results were used to evaluate several thermal diffusion theories; the agreement with theory was generally found to be unsatisfactory. Attempts were then made to correlate the measured thermal diffusion coefficients with various physicochemical parameters of the polymers and solvent. A good correlation was found in which D_T increases with the thermal conductivity difference of the polymer and solvent and varies inversely with the activation energy of viscous flow of the solvent.     

Vibrations of a magnet levitated over a flat superconductor

Based on a dipole-dipole interaction model, we discuss the levitation force and related vibration problems to understand the effects of flux pinning in type-II superconductors, and the applications of levitation in superconducting systems.     

45 GHz self-pulsation with narrow linewidth in quantum dot Fabry-Perot semiconductor lasers at 1.5 /spl mu/m

Self-pulsation at 45 GHz repetition frequency has been demonstrated in 1.5 /spl mu/m monolithic single-section quantum dot Fabry-Perot semiconductor lasers without saturable absorber. The mode-beating exhibits a narrow linewidth below 100 kHz, demonstrating high phase correlation between these modes. Such modelocked lasers open ways to low timing-jitter components for clock recovery or millimetre-wave generation in wireless transmission applications.     

A slotted post-wall waveguide array with interdigital structure for 45/spl deg/ linear and dual polarization

This work proposes a dual-polarized planar antenna; two post-wall slotted waveguide arrays with orthogonal 45/spl deg/ linearly-polarized waves interdigitally share the aperture on a single layer substrate. Uniform excitation of the two-dimensional slot array is confirmed by experiment in the 25 GHz band. The isolation between two slot arrays is also investigated in terms of the relative displacement along the radiation waveguide axis in the interdigital structure. The isolation is 33.0 dB when the relative shift of slot position between the two arrays is -0.5/spl lambda//sub g/, while it is only 12.8 dB when there is no shift. The cross-polarization level in the far field is -25.2 dB for a -0.5/spl lambda//sub g/ shift, which is almost equal to that of the isolated single polarization array. It is degraded down to -9.6 dB when there is no shift.     

A stochastically optimized adaptive procedure for the location of MAS auxiliary monopoles: the case of electromagnetic scattering by dielectric cylinders

A genetically optimized technique that fully automates the potentially laborious allocation of the auxiliary monopoles for the method of auxiliary sources (MAS) is presented for the problem of electromagnetic (EM) scattering by isotropic dielectric cylinders with various cross sections. The proposed technique uses as input information not only the geometry of the scatterer but also the exciting field and the material properties of the cylinders are implicitly taking part in the optimization procedure. The resulting auxiliary surfaces, where the simulating monopoles are situated, are appropriately adapted to the original boundary surface and the MAS modeling is greatly facilitated. In addition, certain considerations are taken into account in order to avoid undesirable numerical dependencies between the fictitious monopoles. Finally, the accuracy of the numerical method combined with overdetermined systems of equations is examined for isotropic cylinders of various geometries and dielectric characteristics.     

Rotational spectra of isotopic species of SO2F2: experimental and ab initio structures

The rotational spectra of ³⁴SO₂F₂ and S¹⁸O¹⁶OF₂ have been measured in their ground vibrational state between 9 and 110 GHz. Accurate rotational constants have been derived. Various experimental structures including the average structure have been determined. The ab initio structure has been calculated at the CCSD(T) level of theory. The different structures are compared and the best equilibrium structure is the ab initio structure: r_e(SO)=1.401 (3) Å, r_e(SF)=1.532 (3) Å, ∠_e(OSO)=124.91(20)°, ∠_e(FSF)=95.53 (20)°.