Reliability of 1300-nm spot-size converter integrated laser diodesfor low-cost optical modules in access networks

This paper discusses the degradation behaviors and reliability of spot-size converter integrated laser diodes fabricated using the full wafer process with dry etching and metal organic vapor phase epitaxy (MOVPE). Failure criteria applicable to actual access networks were determined based on the degradation behavior exhibited in several aging tests, and device lifetimes were then estimated. The far-field patterns and wide-temperature operation required for low-cost system application scarcely changed during degradation, even after a 150% increase in threshold current. Within this degradation range, the device life for system application is estimated to be more than 10⁵ h at 60°C and 10 mW     

Spot-size converted 1.3 μm laser with butt-jointed selectivelygrown vertically tapered waveguide

A 1.3 μm laser has been developed with a butt-jointed selectively grown spot-sire converter (SSC). The SSC vertically tapered waveguide and strained multiquantum well (MQW) active region are independently optimised. The laser was buried with semi-insulating InP to reduce optical loss in the SSC. A threshold current of 7 mA and an output power of >20 mW were obtained. Minimum coupling loss to a flat-end fibre of 1.06 dB was achieved. Long-term stability was also confirmed     

Adsorbed structures of 4,4'-bipyridine on Cu(111) in acid studied by STM and IR

The adsorption of 4,4'-bipyridine (BiPy) on Cu(111) has been investigated in 0.1 M HClO4 by cyclic voltammetry, electrochemical scanning tunneling microscopy (STM), and surface-enhanced infrared adsorption spectroscopy (SEIRAS). Cyclic voltammetry showed the double layer region extending from -0.2 to 0.26 V and a pair of redox waves superposing on hydrogen evolution wave at more negative potentials. Diprotonated BiPy, BiPyH2(2+), is adsorbed flat on the Cu(111) (1 x 1) surface and forms a well-ordered monolayer with a (3 x 4) symmetry in the double-layer potential region. At more negative potential, BiPyH2(2+) is reduced to its monocation radical, BiPyH2(*+), and forms another well-ordered structure in which the radicals are stacked in molecular rows with a face-to-face self-dimer as the building unit. The SEIRA spectra of both BiPyH2(2+) and BiPyH2(*+) are dominated by gerade modes which should be IR-inactive for the centrosymmetric species. The breakdown of the selection rule of IR absorption is ascribed to the vibronic coupling associated with charge transfer between BiPyH2(2+) and the surface and between the radicals.     

Purines. LI. Synthesis and biological activity of hypoxanthine 7-N-oxide and related compounds.

A detailed account is given of the first chemical synthesis of hypoxanthine 7-N-oxide (5), which started from coupling of 6-chloro-5-nitro-4(3H)-pyrimidinone (7) with N-(4-methoxybenzyl)phenacylamine, generated in situ from the hydrochloride (8), and proceeded through cyclization of the resulting phenacylaminopyrimidinone (9) and removal of the 4-methoxybenzyl group. The results of catalytic hydrogenolysis, methylation followed by catalytic hydrogenolysis, and rearrangement under acidic conditions of 5 supported the correctness of the assigned structure. An ultraviolet spectroscopic approach suggested that the neutral species of 5 exists in H2O mainly as the N(7)-OH tautomer (21). In the in vitro bioassay of antileukemic activity against murine L5178Y cells, 5 was weakly cytotoxic, with IC50 of 100 micrograms/ml. It did not show any antimicrobial activity even at 1000 micrograms/ml. None of the 9-(4-methoxybenzyl) (11) and O-methyl (12, 13, and 14) derivatives was found to be antileukemic or antimicrobial.     

New 1.5 ?m wavelength GaInAsp/InP distributed feedback laser

A new 1.5 ?m-wavelength GalnAsP/InP distributed feedback buried-heterostructure laser was fabricated by a three-step LPE growth process. The second-order corrugation grating was formed on the waveguide layer grown on the active layer. High differential quantum efficiency of 13%/facet was obtained. Single-longitudinal-mode operation in the temperature range from ?20°C to 55°C was obtained.     

1.6 µm wavelength GaInAsP/InP lasers prepared by two-phase solution technique

Reduction of the threshold current of GaInAsP lasers with an antimeltback layer was studied in the wavelength range1.50-1.65 mun. The two-phase solution growth technique was applied using a relatively low temperature and a slow cooling rate of 0.17°C/min to reduce the active layer thickness. The antimeltback layer with a bandgap wavelength of 1.35 μm resulted in a flat active layer and eliminated the melt-back problem completely. From experiments and calculations we found that both the carrier and the optical confinement of this structure, having an antimeltback layer, were almost the same as those for the conventional InP cladding structure. A threshold eurrent density as low as 1.2 kA/cm²and an active layer thickness of 0.20μm were obtained at these wavelengths. The lattice-match condition of low-temperature growth was studied. In the low-temperature growth, the longer wavelength lasers were grown with the same amount of InAs.J_{th}/dwas independent of the growth condition (T_{S}, T_{G}) and had a value of 5-6 kA/cm². μm.     

Internal Heating Effect and Enhancement of Drying of Ceramics by Microwave Heating with Dynamic Control

The effectiveness of internal heating for enhancing the drying of molded ceramics is evaluated by both modeling and experiments. In the theoretical analysis, three dimensional drying-induced strain–stress are modeled, and the numerical solutions show that the internal heating generates lower internal stress than continuous convective heating or intermittent convective heating. Microwave drying is examined experimentally to study the effect of internal heating on the drying behavior of a wet sample of a kaolin slab. The drying behavior is compared among three modes: microwave heating, hot air heating and radiation heating. The transient behavior of temperatures in microwave drying is quite different from conventional drying by external heating. In particular, the temperature of the slab drops once in the progress of drying. This phenomenon cannot be predicted adequately by a simple model of one-dimensional heat conduction and moisture diffusion accompanied with an internal heat generation rate given as a linear function of the moisture content. It should be noted that the temperature behavior takes place due to the combined interactions with internal evaporation of moisture by rise in internal vapor pressure and shift of impedance or interference in the applicator. Microwave heating with a constant power above 100 W results in sample breakage due to the internal vapor pressure. However, if the power is dynamically controlled so as to maintain the temperature less than the boiling point of water, the drying succeeds without any crack generation until completion with a significantly faster drying rate than drying in convective heating or in the oven.     

Adlayers of C60-C60 and C60-C70 fullerene dimers formed on au(111) in benzene solutions studied by STM and LEED

Scanning tunneling microscopy (STM) and low-energy electron diffraction were used to reveal the structures of ordered adlayers of [2+2]-type C60-C60 fullerene dimer (C120) and C60-C70 cross-dimer (C130) formed on Au(111) by immersingit in abenzene solution containing C120 or C130 molecules. High-resolution STM images clearly showed the packing arrangements and the electronic structures of C120 and C130 on the Au(111) surface in ultrahigh vacuum. The (2 square root3 x 4square root3)R30 degrees, (2square root3 x 5square root3)R30 degrees, and (7 x 7) structures were found for the C120 adlayer on the Au(111) surface, whereas C130 molecules were closely packed on the surface. Each C60 or C70 monomer cage was discerned in the STM image of a C130 molecule.