Preparation of samples for the α—Spectrometry of transplutonium elements

The electrolytic deposition of the hydroxides of rare earth and transplutonium elements on nickel holders from α-hydroxyisobutyrate solutions of 10⁻⁵ M to 5·10⁻¹ M concentrations has been investigated in the presence of ammonium chloride. It is shown that at total concentrations of ≥10⁻¹² M of rare earth and transplutonium elements, their electrodeposition proceeds with a 90% yield.     

Micromechanisms of failure in short-fiber-reinforced high-impact polystyrene under tensile loading

Injection-molded, short-glass-fiber-reinforced high-impact polystyrene was investigated under uniaxial tension with special attention to the effects of fiber and rubber concentration on fracture behavior. According to a fracture morphology study performed by polarized optical and scanning electron microscopy, crazes were consecutively initiated from rubber-styrene composite particles and from fiber ends. The rubber particles exhibited an intra-particle failure mode which resulted from the failure manner of the matrix becoming of a more brittle character with increasing fiber fraction. Fibers were surrounded by neigh boring growing crazes. Failure at the fiber-matrix interfaces proceeded with an increase in the number of crazes. With increasing concentration of the fibers, crazing at rubber particles appeared to be suppressed and crazing occurred more preferentially at the fiber ends, which accelerated a macroscopic fracture.Dedicated to Prof. H. H. Kausch on the occasion of his 60th birthday.     

Enhancing the enantioselectivity of lipase in transesterification by substrate matching: an enzyme memory based approach

The substrate matching strategy is described as a new approach for effectively enhancing the lipase enantioselectivity in organic solvent. In the lipase-catalyzed transesterifications of 3a-c, higher enantioselectivities have been achieved using 1a-c, respectively, as the structurally matched acyl donors.     

A modified medium access control algorithm for systems with iterative decoding

Efficient transmission methods for fading radio channels often require an iterative decoder. This is for example the case for systems using turbo codes. Receiver decoder iterations could potentially lead to a latency problem which impacts the performance of the medium access control protocol. In this paper, we present modifications based on the carrier sense multiple access with collision avoidance (CSMA/CA) medium access control (MAC) protocol to accommodate the increased latency in the iterative processing. One area of applications is wireless local area networks (WLANs) with high data rate. The simulation results performed in the IEEE 802.11a WLAN environment by replacing the 802:11a's convolutional coding with turbo coding demonstrate that the proposed algorithm provides a throughput gain over the conventional method.     

A miniature UWB planar monopole antenna with 5-GHz band-rejection filter and the time-domain characteristics

A planar monopole antenna with a staircase shape and small volume (25/spl times/26/spl times/1 mm/sup 3/) is proposed in this paper. With the use of a half-bowtie radiating element, the staircase-shape, and a modified ground plane structure, the proposed antenna has a very wide impedance bandwidth measured at about 11.6 GHz (2.9-14.5 GHz, bandwidth ratio about 1:5) below VSWR 2 including the WLAN band notched in the vicinity of 5 GHz. An omnidirectional radiation pattern is obtained. The group delay which is an indication of linearity between two proposed antennas is less than 1 ns. The electrical characteristics in terms of frequency and time domains and physical ones of the proposed antenna make it attractive for use in ultrawideband (UWB) systems.     

Optoelectronic and microwave transmission characteristics of indium solder bumps for low-temperature flip-chip applications

This paper describes low-temperature flip-chip bonding for both optical interconnect and microwave applications. Vertical-cavity surface-emitting laser (VCSEL) arrays were flip-chip bonded onto a fused silica substrate to investigate the optoelectronic characteristics. To achieve low-temperature flip-chip bonding, indium solder bumps were used, which had a low melting temperature of 156.7/spl deg/C. The current-voltage (I-V) and light-current (L-I) characteristics of the flip-chip bonded VCSEL arrays were improved by Ag coating on the indium bump. The I-V and L-I curves indicate that optical and electrical performances of Ag-coated indium bumps are superior to those of uncoated indium solder bumps. The microwave characteristics of the solder bumps were investigated by using a flip-chip-bonded coplanar waveguide (CPW) structure and by measuring the scattering parameter with an on-wafer probe station for the frequency range up to 40 GHz. The indium solder bumps, either with or without the Ag coating, provided good microwave characteristics and retained the original characteristic of the CPW signal lines without degradation of the insertion and return losses by the solder bumps.     

Parallel optical transmitter module using angled fibers and a V-grooved silicon optical bench for VCSEL array

We propose an advanced structure of optical subassembly (OSA) for packaging of the vertical-cavity surface-emitting laser (VCSEL) array, using (111) facet mirror of the V-groove ends formed in a silicon optical bench (SiOB) and angled fiber apertures. The feature of our OSA can provide a low optical crosstalk between neighboring channels, a low feedback reflection, and a large misalignment tolerance along the V-groove. We describe the optimized design of fiber angle, VCSEL position, and fiber position. The fabricated OSA structure consists of 12 channels of angled fiber array, 54.7/spl deg/ V-grooves, Au-coated mirrors on (111) end facet of the V-grooves, and flip-chip-bonded VCSEL array on a SiOB. In this structure, the beam emitted from the VCSEL is deflected at the 54.7/spl deg/ mirror of (111) end facet and propagated into the angled fiber. The angled fiber array was polished by 57/spl deg/. Fabricated OSAs showed a coupling efficiency of 30%-50% that is 25 times larger than that obtained from an OSA with a vertically flat fiber array. Our OSA showed large misalignment tolerance of about 90 /spl mu/m along the longitudinal direction in the V-groove. We fabricated a parallel optical transmitter module using the OSA and demonstrated 12 channels /spl times/2.5 Gb/s data transmission with a clear eye diagram.     

Discrete-time analysis of a CPCH access scheme in W-CDMA

Common packet channel (CPCH) access is an efficient approach to support packet data transmissions in a wideband code division multiple access (W-CDMA) system. Rather than using a continuous-time analysis approach, this paper presents a discrete-time analysis of the CPCH access scheme to fully characterize the complete CPCH operation process. Previous studies using the continuous-time analysis only models a portion of the CPCH process. We assume that a packet arrival process is Poisson distributed and the service time of each packet is geometrically distributed. The study focuses on examining the number of packet arrivals in each CPCH access slot. Performance is evaluated in terms of normalized throughput and it is observed that CPCH performs better when packet mean service time is larger. The performance results are also compared with previous studies using continuous-time analyses     

Bi-slotted tree based anti-collision protocols for fast tag identification in RFID systems

This paper is intended to present bi-slotted tree based RFID tag anti-collision protocols, bi-slotted query tree algorithm (BSQTA) and bi-slotted collision tracking tree algorithm (BSCTTA). Diminishing prefix overhead and iteration overhead is a significant issue to minimize the anti-collision cost. For fast tag identification, BSQTA and BSCTTA use time divided responses depending on whether the collided bit is `0' or `1' at each tag ID. According to the simulation results, BSQTA and BSCTTA require less time consumption for tag identification than the other tree based RFID tag anti-collision protocols     

Intramitochondrial co-assembly between ATP and nucleopeptides induces cancer cell apoptosis

Mitochondria are essential intracellular organelles involved in many cellular processes, especially adenosine triphosphate (ATP) production. Since cancer cells require high ATP levels for proliferation, ATP elimination can be a unique target for cancer growth inhibition. We describe a newly developed mitochondria-targeting nucleopeptide (MNP) that sequesters ATP by self-assembling with ATP inside mitochondria. MNP interacts strongly with ATP through electrostatic and hydrogen bonding interactions. MNP exhibits higher binding affinity for ATP (−637.5 kJ mol⁻¹) than for adenosine diphosphate (ADP) (−578.2 kJ mol⁻¹). To improve anticancer efficacy, the small-sized MNP/ADP complex formed large assemblies with ATP inside cancer cell mitochondria. ATP sequestration and formation of large assemblies of the MNP/ADP–ATP complex inside mitochondria caused physical stress by large structures and metabolic disorders in cancer cells, leading to apoptosis. This work illustrates a facile approach to developing cancer therapeutics that relies on molecular assemblies.

Mitochondria-targeting nucleopeptide (MNP) can sequester ATP by self-assembling with ATP. A small nanosized MNP/ADP complex forms a large assembly with ATP. Thus, intramitochondrial co-assembly causes stress by large structures and apoptosis.