全文获取类型
收费全文 | 39936篇 |
免费 | 11727篇 |
国内免费 | 1391篇 |
专业分类
化学 | 40968篇 |
晶体学 | 324篇 |
力学 | 441篇 |
数学 | 1874篇 |
物理学 | 2325篇 |
无线电 | 7122篇 |
出版年
2023年 | 56篇 |
2022年 | 35篇 |
2021年 | 193篇 |
2020年 | 1778篇 |
2019年 | 3187篇 |
2018年 | 1448篇 |
2017年 | 1018篇 |
2016年 | 3947篇 |
2015年 | 4076篇 |
2014年 | 4011篇 |
2013年 | 4567篇 |
2012年 | 3358篇 |
2011年 | 2554篇 |
2010年 | 3151篇 |
2009年 | 3159篇 |
2008年 | 2636篇 |
2007年 | 1992篇 |
2006年 | 1616篇 |
2005年 | 1802篇 |
2004年 | 1574篇 |
2003年 | 1426篇 |
2002年 | 2094篇 |
2001年 | 1422篇 |
2000年 | 1336篇 |
1999年 | 386篇 |
1998年 | 59篇 |
1997年 | 51篇 |
1996年 | 15篇 |
1995年 | 9篇 |
1994年 | 11篇 |
1993年 | 10篇 |
1992年 | 6篇 |
1991年 | 3篇 |
1990年 | 11篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1987年 | 7篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 5篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1975年 | 1篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
991.
Inês Nunes Nuno Mesquita Sandra Cabo Verde Maria João Trigo Armando Ferreira Maria Manuela Carolino António Portugal Maria Luísa Botelho 《Radiation Physics and Chemistry》2012,81(12):1943-1946
Parchments are important documents that give testimony for History; therefore these materials should be respected and preserved. Considering incremental biodeterioration problems that have to be faced daily, the Archive of the University of Coimbra (AUC) is involved in different scientific projects in order to evaluate and determine new methods for document decontamination and preservation.The aim of this study was to evaluate gamma radiation effects on the colour and texture of the AUC parchment documents. The assessment of these effects was used to estimate the maximum gamma radiation dose (Dmax) that could guarantee parchment documents′ decontamination treatment, without significant alteration of their physical properties. Parchment samples were exposed to gamma radiation doses ranging from 10 to 30 kGy. The texture and colour of samples were assessed before and after the irradiation procedure, using a texture analyser and an electronic colorimeter. Hardness and springiness were determined based on texture spectra. Lightness (L?), Chroma (C), greenness vs. redness (a*) and yellowness vs. blueness (b*) values were obtained from colorimetric measures. Results indicate no significant effects of gamma radiation on the texture and colour of parchment for the studied doses. 相似文献
992.
Yao‐Cheng Shi Huan‐Ren Cheng Da‐Cong Cheng 《Acta Crystallographica. Section C, Structural Chemistry》2013,69(6):581-583
The title compound, hexadecacarbonylbis{μ3‐[(diphenylphosphanyl)methanediidyl]sulfanido}‐μ4‐disulfido(2−)‐hexairon(4 Fe—Fe), [Fe6(C13H10PS)2(S2)(CO)16], contains two inversion‐related [Fe3(Ph2PCS)(CO)8] subclusters linked by an equatorial disulfide bond [S—S = 2.1490 (9) Å]. Each Ph2PCS3− ligand is coordinated to a triiron core in a μ3‐κP:κ2C:κ2S fashion. 相似文献
993.
Zhenhui Qi Dr. Changzhu Wu Dr. Paula Malo de Molina Han Sun Andrea Schulz Prof. Christian Griesinger Prof. Michael Gradzielski Prof. Rainer Haag Prof. Marion B. Ansorge‐Schumacher Prof. Christoph A. Schalley 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(31):10150-10159
A new and versatile, crown ether appended, chiral supergelator has been designed and synthesized based on the bis‐urea motif. The introduction of a stereogenic center improved its gelation ability significantly relative to its achiral analogue. This low‐molecular‐weight gelator forms supramolecular gels in a variety of organic solvents. It is sensitive to multiple chemical stimuli and the sol–gel phase transitions can be reversibly triggered by host–guest interactions. The gel can be used to trap enzymes and release them on demand by chemical stimuli. It stabilizes the microparticles in Pickering emulsions so that enzyme‐catalyzed organic reactions can take place in the polar phase inside the microparticles, the organic reactants diffusing through the biphasic interface from the surrounding organic phase. Because of the higher interface area between the organic and polar phases, enzyme activity is enhanced in comparison with simple biphasic systems. 相似文献
994.
995.
Markus Follmann Nils Griebenow Michael G. Hahn Ingo Hartung Franz‐Josef Mais Joachim Mittendorf Martina Schfer Hartmut Schirok Johannes‐Peter Stasch Friederike Stoll Alexander Straub Peter Jeschke Ralf Nauen Michael Edmund Beck Hans‐Wilhelm Engels Hans‐Georg Pirkl Reinhard Albers Rolf W. Albach Jens Krause Andreas Hoffmann Holger Casselmann Jeff Dormish 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2013,125(36):9503-9503
996.
Synthesis and Rearrangement of P‐Nitroxyl‐Substituted PIII and PV Phosphanes: A Combined Experimental and Theoretical Case Study
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Tobias Heurich Dr. Zheng‐Wang Qu Dr. Senada Nožinović Dr. Gregor Schnakenburg Dr. Hideto Matsuoka Prof. Dr. Stefan Grimme Prof. Dr. Olav Schiemann Prof. Dr. Rainer Streubel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(29):10102-10110
Low‐temperature generation of P‐nitroxyl phosphane 2 (Ph2POTEMP), which was obtained by the reaction of Ph2PH ( 1 ) with two equivalents of TEMPO, is presented. Upon warming, phosphane 2 decomposed to give P‐nitroxyl phosphane P‐oxide 3 (Ph2P(O)OTEMP) as one of the final products. This facile synthetic protocol also enabled access to P‐sulfide and P‐borane derivatives 7 and 13 , respectively, by using Ph2P(S)H ( 6 ) or Ph2P(BH3)H ( 11 ) and TEMPO. Phosphane sulfide 7 revealed a rearrangement to phosphane oxide 8 (Ph2P(O)STEMP) in CDCl3 at ambient temperature, whereas in THF, thermal decomposition of sulfide 7 yielded salt 10 ([TEMP‐H2][Ph2P(S)O]). As well as EPR and detailed NMR kinetic studies, indepth theoretical studies provided an insight into the reaction pathways and spin‐density distributions of the reactive intermediates. 相似文献
997.
998.
Synthesis of Some New Thiazole,Oxazole, Pyrimidine and Pyridazine Derivatives from 2‐cyano‐N‐octadecyl‐acetamide as Antimicrobial and Surface Active Agents
下载免费PDF全文
![点击此处可从《Journal of heterocyclic chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The motivation behind the present work is to synthesize some nonionic surfactants containing heterocyclic nucleus with intermediate fatty compounds for improving their surfactants properties. 2‐Cyano‐N‐octadecylacetamide was utilized as key intermediate for the synthesis of some new thiazole, pyrazole, oxazole, pyrimidine, 1,3‐dithiolane, thiophene, coumarin, oxazine and pyridazine derivatives. The newly synthesized compounds undergo propoxylation using propylene oxide to afford nonionic surface active agents. The antimicrobial and surface activities were evaluated and characterized through investigations of their spreading behavior in monolayer on water. 相似文献
999.
1000.
Identification and formation mechanism of individual degradation products in lithium‐ion batteries studied by liquid chromatography/electrospray ionization mass spectrometry and atmospheric solid analysis probe mass spectrometry
下载免费PDF全文
![点击此处可从《Rapid communications in mass spectrometry : RCM》网站下载免费的PDF全文](/ch/ext_images/free.gif)