全文获取类型
收费全文 | 195272篇 |
免费 | 971篇 |
国内免费 | 283篇 |
专业分类
化学 | 90233篇 |
晶体学 | 2642篇 |
力学 | 9412篇 |
综合类 | 8篇 |
数学 | 21001篇 |
物理学 | 58364篇 |
无线电 | 14866篇 |
出版年
2020年 | 2070篇 |
2019年 | 2595篇 |
2018年 | 3708篇 |
2017年 | 3814篇 |
2016年 | 4517篇 |
2015年 | 1986篇 |
2014年 | 3901篇 |
2013年 | 7513篇 |
2012年 | 5940篇 |
2011年 | 7050篇 |
2010年 | 5948篇 |
2009年 | 6218篇 |
2008年 | 6975篇 |
2007年 | 7052篇 |
2006年 | 6279篇 |
2005年 | 5619篇 |
2004年 | 5443篇 |
2003年 | 4973篇 |
2002年 | 5102篇 |
2001年 | 5531篇 |
2000年 | 4274篇 |
1999年 | 3338篇 |
1998年 | 3072篇 |
1997年 | 2900篇 |
1996年 | 2586篇 |
1995年 | 2365篇 |
1994年 | 2344篇 |
1993年 | 2342篇 |
1992年 | 2335篇 |
1991年 | 2643篇 |
1990年 | 2630篇 |
1989年 | 2652篇 |
1988年 | 2528篇 |
1987年 | 2447篇 |
1986年 | 2288篇 |
1985年 | 2825篇 |
1984年 | 2811篇 |
1983年 | 2431篇 |
1982年 | 2453篇 |
1981年 | 2368篇 |
1980年 | 2146篇 |
1979年 | 2461篇 |
1978年 | 2604篇 |
1977年 | 2695篇 |
1976年 | 2783篇 |
1975年 | 2594篇 |
1974年 | 2521篇 |
1973年 | 2687篇 |
1972年 | 2189篇 |
1971年 | 2005篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
71.
Mao‐Chuan Yuan Ping‐I Shih Chen‐Han Chien Ching‐Fong Shu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(14):2925-2937
We have synthesized a blue‐light‐emitting polyfluorene (PF) derivative ( PF‐CBZ‐OXD ) that presents bulky hole‐transporting carbazole and electron‐transporting oxadiazole pendent groups functionalized at the C‐9 positions of alternating fluorene units. The results from photoluminescence and electrochemical measurements indicate that both the side chains and the PF main chain retain their own electronic characteristics in the copolymer. An electroluminescent device incorporating this polymer as the emitting layer was turned on at 4.5 V; it exhibited a stable blue emission with a maximum external quantum efficiency of 1.1%. Moreover, we doped PF‐CBZ‐OXD and its analogue PF‐TPA‐OXD with a red‐light‐emitting iridium phosphor for use as components of phosphorescent red‐light emitters to investigate the effect of the host's HOMO energy level on the degree of charge trapping and on the electrophosphorescent efficiency. We found that spectral overlap and individual energy level matching between the host and guest were both crucial features affecting the performance of the electroluminescence devices. Atomic force microscopy measurements indicated that the dipolar nature of PF‐CBZ‐OXD , in contrast to the general nonpolarity of polydialkylfluorenes, provided a stabilizing environment that allowed homogeneous dispersion of the polar iridium triplet dopant. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2925–2937, 2007 相似文献
72.
L. A. Kosyachenko I. M. Rarenko E. F. Sklyarchuk I. I. German Sun Weiguo 《Semiconductors》2006,40(5):554-557
Photodiodes designed to be sensitive in the region 0.5–1.7 μm and obtained by vacuum magnetron sputtering of the ITO (SnO2 + In2O3) layer on the surface of the Hg3In2Te6 single crystal are studied. The electrical characteristics, measured at 265–333 K, indicate that the mechanism of charge
transport in the diodes under study is thermionic. The current-voltage characteristic and its temperature variations are described
quantitatively based on the energy diagram and the found parameters of the heterojunction.
Original Russian Text ? L.A. Kosyachenko, I.M. Rarenko, E.F. Sklyarchuk, I.I. German, Sun Weiguo, 2006, published in Fizika
i Tekhnika Poluprovodnikov, 2006, Vol. 40, No. 5, pp. 568–571. 相似文献
73.
M. M. Zverev N. A. Gamov D. V. Peregoudov V. B. Studionov E. V. Zdanova I. V. Sedova S. V. Gronin S. V. Sorokin S. V. Ivanov P. S. Kop’ev 《Semiconductors》2008,42(12):1440-1444
Emission characteristics of an electron-beam-pumped Cd(Zn)Se/ZnMgSSe semiconductor laser are studied. The laser’s active region consists of a set of ten equidistant ZnSe quantum wells containing fractional-monolayer CdSe quantum-dot inserts and a waveguide formed by a short-period superlattice with the net thickness of ~0.65 μm. Lasing occurs at room temperature at a wavelength of 542 nm. Pulsed power as high as 12 W per cavity face and an unprecedentedly high efficiency of ~8.5% are attained for the electron-beam energy of 23 keV. 相似文献
74.
M. I. Mazurkov V. S. Dmitrenko S. N. Kropachev 《Radioelectronics and Communications Systems》2008,51(2):106-111
It is proposed a rule of total classes of composition systems of discrete frequency signals (CDF-signals) construction in extended Galois fields. It is carried out modeling and research a correlation properties of CDF-signals, and determined their practical attraction. 相似文献
75.
Effect of nickel coating on electrochemical performance of graphite anodes for lithium ion batteries
Among the different materials often studied and proposed as negative electrodes for lithium-ion batteries, graphite anodes
are the most used in commercial batteries. For this study, synthetic graphite was tested. During the first discharge 0.2 Li
ions were consumed for the formation of the SEI film and the capacity reaches about 387 mAh/g. But at the end of the first
charge only 72% of the initial charge was recovered (the reversible capacity is about 279 mAh/g). In order to improve this
performance we have deposited metallic nickel on graphite with the intention to obtain a homogeneous thin layer able to modify
the nature of the SEI film, to allow the diffusion of lithium ions through the protective layer, and also to increase the
performance of graphite electrodes. The results show a decrease of the irreversible capacity loss (16% instead of 28% for
pure graphite electrodes) as well as better cycleability for a nickel-deposited graphite electrode with only 11% weight ratio
of nickel. On the other hand, an increase of the nickel content decreases this performance. 相似文献
76.
M. V. Zyubin I. A. Rudnev V. A. Kashurnikov 《Journal of Experimental and Theoretical Physics》2003,96(6):1065-1077
A system of Abrikosov vortices in a quasi-two-dimensional HTSC plate is considered for various periodic lattices of pinning centers. The magnetization and equilibrium configurations of the vortex density for various values of external magnetic field and temperature are calculated using the Monte Carlo method. It is found that the interaction of the vortex system with the periodic lattice of pinning centers leads to the formation of various ordered vortex states through which the vortex system passes upon an increase or a decrease in the magnetic field. It is shown that ordered vortex states, as well as magnetic field screening processes, are responsible for the emergence of clearly manifested peaks on the magnetization curves. Extended pinning centers and the effect of multiple trapping of vortices on the behavior of magnetization are considered. Melting and crystallization of the vortex system under the periodic pinning conditions are investigated. It is found that the vortex system can crystallize upon heating in the case of periodic pinning. 相似文献
77.
The results of the analysis of variations in the radiative recombination coefficient with varying doping level and concentration of excess electron-hole pairs are reported. It is shown that, along with the effect of narrowing of the band gap calculated in the many-electron approximation, the effect of screening of the Coulomb interaction responsible for the decrease in the excition binding energy should be taken into account. Both effects produce similar trends and decrease the radiative recombination coefficient with increasing levels of doping or injection. The contributions of excitonic radiative recombination and band-to-band radiative recombination to the total radiative recombination coefficient are separated from each other. It is shown that, in the region of room temperature, both contributions are comparable, while at liquid-nitrogen temperature, the excitonic component dominates over the band-to-band component. The results obtained by refined calculations of the limiting value of the internal quantum yield of electroluminescence for the silicon diodes and p-i-n structures are presented. It is shown that the internal quantum yield of electroluminescence can be as high as 14%. However, this values sharply decreases with increasing surface recombination rate and decreasing lifetime of excess charge carriers in the bulk. 相似文献
78.
E. M. Zobov M. E. Zobov F. S. Gabibov I. K. Kamilov F. I. Manyakhin E. K. Naimi 《Semiconductors》2008,42(3):277-280
The results of the effect of ultrasonic treatment of ZnSe crystals on the structure of the energy spectrum of electronic states of centers with deep levels forming photoelectric and luminescent properties of this compound are presented. It is for the first time proved experimentally that the climb of edge dislocations under the effect of ultrasound leads to regrouping and generation of defects forming deep levels, which manifest themselves in phenomena of photosensitivity and radiative recombination. 相似文献
79.
Howard Anton and Robert C. Busby, John Wiley & Sons, Inc., 2002. 相似文献
80.
Guangchang Zhou Jibao He Issifu I. Harruna 《Journal of polymer science. Part A, Polymer chemistry》2007,45(18):4204-4210
Amphiphilic tris(2,2′‐bipyridine)ruthenium‐cored star‐shaped polymers consisting of one polystyrene block and two poly(N‐isopropylacrylamide) blocks were prepared by the “arm‐first” method in which RAFT polymerization and nonconvalent ligand–metal complexation were employed. The prepared amphiphilic star‐shaped metallopolymers are able to form micelles in water. The size and distribution of the micelles were studied by dynamic light scattering and transmission electron microscopy techniques. Preliminary studies indicate that the polymer concentration and the hydrophilic poly(N‐isopropylacrylamide) block length can affect the morphologies of the formed metal‐interfaced core–shell micelles in water. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4204–4210, 2007 相似文献