首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5638篇
  免费   648篇
  国内免费   319篇
化学   3569篇
晶体学   72篇
力学   157篇
综合类   15篇
数学   418篇
物理学   1028篇
无线电   1346篇
  2023年   72篇
  2022年   88篇
  2021年   172篇
  2020年   165篇
  2019年   209篇
  2018年   145篇
  2017年   140篇
  2016年   245篇
  2015年   280篇
  2014年   341篇
  2013年   434篇
  2012年   488篇
  2011年   461篇
  2010年   322篇
  2009年   336篇
  2008年   387篇
  2007年   329篇
  2006年   282篇
  2005年   282篇
  2004年   208篇
  2003年   185篇
  2002年   192篇
  2001年   96篇
  2000年   75篇
  1999年   80篇
  1998年   65篇
  1997年   48篇
  1996年   32篇
  1995年   39篇
  1994年   33篇
  1993年   22篇
  1992年   22篇
  1991年   23篇
  1990年   17篇
  1989年   14篇
  1988年   8篇
  1987年   12篇
  1986年   7篇
  1985年   14篇
  1984年   12篇
  1983年   7篇
  1982年   7篇
  1980年   27篇
  1978年   25篇
  1977年   49篇
  1976年   19篇
  1975年   18篇
  1974年   11篇
  1973年   7篇
  1943年   10篇
排序方式: 共有6605条查询结果,搜索用时 187 毫秒
11.
孟炬  李纯 《信息技术》2006,30(6):149-150
标准化的目的是“获得最佳秩序和社会效益”,而最佳秩序是企业进行高效率生产和管理的前提条件。能够更及时准确的对企业的生产标准、技术标准、安全标准、管理标准进行监督和管理工作;有助于更好的督促企业在每个环节都建立起互相适应、配套的标准体系,使企业生产活动和经营管理活动井然有序,避免混乱;能够进一步加强对认证及认证咨询工作的质量,提高认证企业质量体系运行的有效性。为此我们提出了建设《哈尔滨市企业产品执行标准数据库管理系统》,对企业的产品执行标准进行登记注册管理,这将有助于组织、监督标准实施工作;有助于组织制订地方标准;推行采用国际标准和国外先进标准;有助于协调指导企业产品标准的制订并管理其备案;组织重要标准的宣传贯彻,监督检查重要标准的实施情况。  相似文献   
12.
我国上市公司资本结构决策的实证研究   总被引:4,自引:0,他引:4  
本在已有资本结构理论研究成果的基础上,对30家沪市上市公司的资本结构进行了实证研究,提出了在我国资本市场环境下优化企业资本结构的对策建议。  相似文献   
13.
消费电子和通信产业正见证着I/O解决方案从并行到高速串行的转变:能够降低成本、简化设计,并具备可延展性,满足全新带宽的要求。这类接口I/O技术的市场潜力巨大,包括移动电话、DVD-RW和高清晰度LCD电视机,而低功耗、低电磁干扰(EMI)和高数据吞吐量在这些应用中极为重要。因此,业界一直致力于设计和开发这些串行I/O,以低功耗提供高速的数据速  相似文献   
14.
A rapid DNA analysis has been developed based on a fluorescence intensity change of a molecular beacon in a PDMS microfluidic channel. Recently, we reported a new analytical method of DNA hybridization involving a PDMS microfluidic sensor using fluorescence energy transfer (FRET). However, there are some limitations in its application to real DNA samples because the target DNA must be labelled with a suitable fluorescent dye. To resolve this problem, we have developed a new DNA microfluidic sensor using a molecular beacon. By monitoring the change in the restored fluorescence intensity along the channel length, it is possible to rapidly detect any hybridization of the molecular beacon to the target DNA. In this case, the target DNA does not need to be labelled. Our experimental results demonstrate that this microfluidic sensor using a molecular beacon is a promising diagnostic tool for rapid DNA hybridization analysis.  相似文献   
15.
Pyridine‐2‐carboximidates [methyl ( 1a ), ethyl ( 1b ), isopropyl ( 1c ), cyclopentyl ( 1d ), cyclohexyl ( 1e ), n‐octyl ( 1f ), and benzyl ( 1g )] were prepared from the reaction of 2‐cyanopyridine with the corresponding alcohols. Cyclopentyl‐substituted 1d was found to be a highly effective ligand for copper‐catalyzed atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA). For example, the observed rate constant for a CuBr/ 1d catalytic system was found to be nearly twice as high as the cyclohexyl‐substituted CuBr/ 1e catalytic system [kobs = (1.19 vs 0.56) × 10?4 s?1). The effects of the solvents, temperature, catalyst/initiator, and solvent/monomer ratio on the ATRP of MMA were studied systematically for the CuBr/ 1d catalytic system. The optimum condition for the ATRP of MMA was found to be a 1:2:1:400 [CuBr]o/[ 1d ]o/[ethyl 2‐bromoisobutyrate]o/[MMA]o ratio at 60 °C in veratrole solution, which yielded well‐defined poly(MMA) with a narrow molecular weight distribution of 1.14. The catalytically active copper complex 2d was isolated from the reaction of CuBr with 1d . Narrow molecular weight distributions as low as 1.06 were achieved for the CuBr/ 1d catalytic system by employing 10% of the deactivator CuBr2. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2747–2755, 2004  相似文献   
16.
The diffraction efficiency and morphology of the transmission modes of holographic polymer dispersed liquid crystals were studied with respect to the molecular structure of poly(urethane acrylate) (PUA), the film (polymer/liquid crystal) and resin (oligomer/monomer) compositions, and the cell thickness. PUA, based on N‐vinylpyrrolidone and ethyl hexyl acrylate, with low‐molecular‐weight poly(propylene glycol) at a low oligomer content, showed high diffraction efficiency. The results were interpreted in terms of the monomer reactivity and polymer elasticity. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 613–620, 2004  相似文献   
17.
The desorption behavior of a surfactant in a linear low‐density polyethylene (LLDPE) blend at elevated temperatures of 50, 70, and 80 °C was studied with Fourier transform infrared spectroscopy. The composition of the LLDPE blend was 70:30 LLDPE/low‐density polyethylene. Three different specimens (II, III, and IV) were prepared with various compositions of a small molecular penetrant, sorbitan palmitate (SPAN‐40), and a migration controller, poly(ethylene acrylic acid) (EAA), in the LLDPE blend. The calculated diffusion coefficient (D) of SPAN‐40 in specimens II, III, and IV, between 50 and 80 °C, varied from 1.74 × 10?11 to 6.79 × 10?11 cm2/s, from 1.10 × 10?11 to 5.75 × 10?11 cm2/s, and from 0.58 × 10?11 to 4.75 × 10?11 cm2/s, respectively. In addition, the calculated activation energies (ED) of specimens II, III, and IV, from the plotting of ln D versus 1/T between 50 and 80 °C, were 42.9, 52.7, and 65.6 kJ/mol, respectively. These values were different from those obtained between 25 and 50 °C and were believed to have been influenced by the interference of Tinuvin (a UV stabilizer) at elevated temperatures higher than 50 °C. Although the desorption rate of SPAN‐40 increased with the temperature and decreased with the EAA content, the observed spectral behavior did not depend on the temperature and time. For all specimens stored over 50 °C, the peak at 1739 cm?1 decreased in a few days and subsequently increased with a peak shift toward 1730 cm?1. This arose from the carbonyl stretching vibration of Tinuvin, possibly because of oxidation or degradation at elevated temperatures. In addition, the incorporation of EAA into the LLDPE blend suppressed the desorption rate of SPAN‐40 and retarded the appearance of the 1730 cm?1 peak. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1114–1126, 2004  相似文献   
18.
19.
We experimentally demonstrate a simple and novel scheme for tunable real-repetition-rate multiplication, based on the combined use of fractional Talbot effect in a linearly tunable chirped fiber Bragg grating (FBG) and cross-phase modulation (XPM) effect in a nonlinear optical loop mirror (NOLM). By tuning the group-velocity dispersion of the chirped FBG fabricated with the S-bending method using a uniform FBG, we obtain high quality pulses at pseudorepetition rates of 20/spl sim/50 GHz from an original 8.5-ps 10-GHz soliton pulse train. We subsequently convert this pseudorate multiplication into a real-rate multiplication using XPM effect in an NOLM. A wavelength tuning is also achieved over a /spl sim/15-nm range.  相似文献   
20.
本文利用自制云雾室把微观粒子的运动转化为宏观现象,从而供实验观察和研究。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号