Calibration of sample-time error in a two-channel time-interleaved analog-to-digital converter

Offset mismatch, gain mismatch, and sample-time error between time-interleaved channels limit the performance of time-interleaved analog-to-digital converters (ADCs). This paper focuses on the sample-time error. Techniques for correcting and detecting sample-time error in a two-channel ADC are described, and simulation results are presented.     

Vapourisation of ionic liquids

Eight common imidazolium based ionic liquids have been successfully evaporated in ultra-high vacuum, their vapours analysed by line of sight mass spectrometry and their heats (enthalpy) of vapourisation determined. They were found to evaporate as ion pairs, with heats of vapourisation which depend primarily on the coulombic interactions within the liquid phase and the gas phase ion pair. An electrostatic model is presented relating the heats of vapourisation to the molar volumes of the ionic liquids.     

UV-vis spectroscopic study of Co(II)/Co(III) oxidation in poly[M-protoporphyrins] films and their interaction with axial ligands

A bathochromic shift for both Soret and Q bands in the polyCo(III)PP were indicative of Co(III) oxidation state in film. The presence of an isosbestic point indicates a chemical equilibrium between polyCo(III)PP (band I) in polyCo(III)PP with water as axial neutral ligand (band II). Concentration levels of iodide of 10(-1) M showed irreversible broadening of Soret band with a maximum shift from 400 nm to 380 nm attributed to film reduction. The thiocyanate anion shows a remarkable effect on polyCo(III)PP spectra. The degree of configuration interaction for Q and B transitions is nearly constant in air and water for Ni(II)PP, Cu(II)PP and Zn(II)PP films. The poly[Co(III)-protoporphyrin IX] showed strong deviation from the pattern. This result indicates that the Co atom does not present a planar conformation in polyCo(III)PP which is consistent with the less packed structure of this film. The apparent diffusion coefficients (D') were calculated for electroactive species using the polyNi(II)PP chemically modified electrode, with an experiment short enough to avoid preconcentration. D' was compared with D (diffusion coefficient), obtained with the bare working electrode. Apparent diffusion coefficients (D') changed regularly with molecular volume indicating certain molecular sieving effect.     

Direct inelastic and trapping desorption scattering of N2 from polycrystalline W; elementary steps in the chemisorption of nitrogen

Scattering of N₂ from a clean polycrystalline W surface is studied with a time-of-flight molecular beam apparatus. The time-of-flight spectra are used to characterize the N₂-W energytransfer and condensation, allowing inferences to be made about the initial steps of N₂ chemisorption, thought to proceed via a molecular precursor state. The sticking coefficient on our sample for N₂ to chemisorb to an atomic nitrogen bound state was 0.5 ± 0.1 5 for a 600 K beam and a 450 K surface temperature. Unreacted N₂ scattered into direct and trapping-desorption channels. The direct channel is shown to be entirely inelastic with temperature independent differential energy accommodation coefficients that average 0.46 for normal and specular scattering at 45° incidence angle. The fraction of trapping-desorption scattering diminishes significantly with increasing surface and beam temperature. The observed decrease in sticking coefficient with increase in surface temperature is shown to be due to a diminution of the N₂ condensation coefficient as well as an increase in desorption of the N₂, recursor relative to its migration-chemisorption.     

A comparison of experiment and theory for sound propagation in variable area ducts

An experimental and analytical program has been carried out to evaluate sound suppression techniques in ducts that produce refraction effects due to axial velocity gradients. The analytical program employs a computer code based on the method of multiple scales to calculate the influence of axial variations due to slow changes in the cross-sectional area as well as transverse gradients due to the wall boundary layers. Detailed comparisons between the analytical predictions and the experimental measurements have been made. The circumferential variations of pressure amplitudes and phases at several axial positions have been examined in straight and variable area ducts, with hard walls and lined sections, and with and without a mean flow. Reasonable agreement between the theoretical and experimental results has been found.     

Scattering from partial bodies of revolution

The electromagnetic scattering from classes of partial bodies of revolution formed by the presence of perfectly electrically or magnetically conducting (PEC or PMC) planes is investigated. It is found that when the Galerkin technique is used with a harmonic circumferential expansion, there is a modal decoupling of the integral operators. The choice of these expansions is determined by the angle subtended by the intersecting planes and by whether these planes are PEC, PMC, or a combination of the two. In this analysis, the partial bodies can be either PEC or penetrable. Examples illustrating this formulation are given for conducting and dielectric hemispherical geometries and for a modified corner reflector. Measured and calculated data are compared for the case of a half-cylinder on a finite ground plane     

The quantum theory of second class constraints: Kinematics

Communicated by H. Araki     

High-spin negative parity states in 19F

Levels at 7.17, 8.29, 8.96 and 9.88 MeV in ¹⁹F have been assigned spin and parity $\text{11}\text{2}{}^{\mathrm{?}}$, $\text{13}\text{2}{}^{\mathrm{?}}$, $\text{11}\text{2}{}^{\mathrm{?}}$ and $\text{11}\text{2}{}^{\mathrm{?}}$, respectively, from resonance strength and γ-ray angular distribution measurements employing the ¹⁵N(α,γ) ¹⁹F reaction. An earlier assignment of $\text{11}\text{2}{}^{\mathrm{+}}$ to the 8.96 MeV level is incorrect. The measured properties of the $\text{11}\text{2}{}^{\mathrm{?}}$ states are compared with the results of both SU (3) shell model and cluster model calculations.     

A study of the (τ, α) reaction on 50Cr

The ⁵⁰Cr(τ, α)⁴⁹Cr reaction has been studied at E_τ = 16.0 MeV using the Tandem Van de Graaff accelerator and the multichannel magnetic spectrograph of the Nuclear Physics Laboratory, Oxford. Twenty-nine levels up to an excitation of ≈ 6.8 MeV have been observed, including a few analogues. The angular distributions have been analyzed in terms of the DWBA theory of direct reaction. The J^π limits and spectroscopic factors are obtained for various levels.