Synthesis of side‐chain liquid‐crystalline homopolymers and triblock copolymers with p‐methoxyazobenzene moieties and poly(ethylene glycol) as coil segments by atom transfer radical polymerization and their thermotropic phase behavior

A series of side‐chain liquid‐crystalline (LC) homopolymers of poly[6‐(4‐methoxy‐4′‐oxy‐azobenzene) hexyl methacrylate] with different degrees of polymerization were synthesized by atom transfer radical polymerization (ATRP), which were prepared with a wide range of number‐average molecular weights from 5.1 × 10³ to 20.6 × 10³ with narrow polydispersities of around 1.17. Thermal investigation showed that the homopolymers exhibit two mesophases, a smectic phase, and a nematic phase, and the phase‐transition temperatures of the homopolymers increase clearly with increasing molecular weights. A series of novel LC coil triblock copolymers with narrow polydispersities was synthesized by ATRP, and their thermotropic phase behavior was investigated with differential scanning calorimetry and polarized optical microscopy. The LC coil triblocks were designed to have an LC conformation of poly[6‐(4‐methoxy‐4′‐oxy‐azobenzene) hexyl methacrylate] with a wide range of molecular weights from 3.5 × 10³ to 1.7 × 10⁴ and the coil conformation of poly(ethylene glycol) (PEG) (number‐average molecular weight: 6000 or 12,000) segment. Their characterization was investigated with ¹H NMR, Fourier transform infrared spectra, and gel permeation chromatography. Triblock copolymers exhibited a crystalline phase, a smectic phase, and a nematic phase. The phase‐transition temperatures from the smectic to nematic phase and from the nematic to isotropic phase increased, and the crystallization of PEG depressed with increasing molecular weight of the LC block. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2854–2864, 2003     

数学建模与素质教育

面对二十一世纪知识经济的挑战 ,我国高等教育模式应由应试教育 ,专业教育向素质教育转变 ,培养学生自主意识 ,效率意识 ,竞争意识 ,创新意识和民主意识 ,即高校教育应重视大学生的创新能力、实践能力和创业精神 ,普遍提高大学生的人文素质和科学素质 .本文拟就提高大学生素质的有效层面 ,对开展数学建模教学与实践进行深入分析 ,以窥探数学建模与素质教育之关系 .在深入把握数学建模教学与实践内涵的同时 ,分析得出这种以不打扰现行正常秩序的教育是提高大学生素质的有效途径之一     

Bandwidth renegotiation for VBR video over ATM networks

A scheme for delivery or variable bit-rate (VBR) video over asynchronous transfer mode (ATM) networks where bandwidth can be renegotiated during the duration of a call between the video source and the network is considered. Renegotiation can be initiated by either the video source or the network. The video bandwidth requirement is characterized by a usage parameter control (UPC) consisting, in general, of peak rate, burst length, and sustained rate. A baseline design is outlined where rate-control adjusts the source's rate while a new UPC is requested from the network. When granted, the new UPC allows the source to maintain its target quantization and delay requirements. Rate control epochs may be extended when the network blocks UPC requests or sets a lower UPC value to temporally deal with congestion. Simulation results are presented for VBR MPEG video. The results show that with a moderate renegotiation rate the scheme tracks the bandwidth requirements of the source. As a result, the video quality and bandwidth efficiency can be maintained     

PFC控制技术的一种改进方案

文章首先指出了目前ＰＦＣ所用控制技术的缺陷，然后提出了一各改进方案，并从理论分析和仿真验证的角度证明了改进方案的可行性和先进性。     

人造导星技术及导星用激光系统

论述了自适应光学系统对人造导星的需要;简单介绍了两类激光导星;重点描述了销激光导星的产生机理及可用于销激光导星的一些激光系统.     

超声跟踪法制作误差对器件性能的影响及补偿

研究发现快模入射超声跟踪氧化碲器件的布喇格损耗频响对于参数误差十分敏感,因而制作误差可能对器件性能有较大影响。本文系统研究了这种影响及其补偿方法,结果表明,当相邻两换能片之间中心距S有5%的误差和声偏置角丫_0有10%的误差时,通过调整入射角θ_1可作出完全的补偿。     

An isolated ZVS/ZCS flyback converter using the leakage inductanceof the coupled inductor

This paper describes a simple and effective way to modify an existing hard-switched flyback power converter into a circuit with zero-voltage switching (ZVS) and zero-current switching (ZCS). The key improvement is to turn the unattractive features of the coupled inductor leakage inductance and snubber capacitor into attractive ones. The coupled inductor leakage inductance and snubber are used to form a quasi-resonant circuit to facilitate ZVS/ZCS of all power devices. The operating principles of the power converter and experimental results are presented     

硼预淀积对自组织生长Ge量子点尺寸分布的影响

研究了以不同B2H6流量预淀积硼对UHV/CVD自组织生长Ge量子点尺寸分布的影响。在适当的生长条件下,得到了尺寸分布很窄的均匀Ge量子点,用AFM对量子点的形貌进行观察,Ge量子点尺寸的涨落小于±3%,量子点的水平尺寸和高度分别为60nm和10nm,密度为8×109cm-2。实验结果表明,通过预淀积硼表面处理,可以得到尺寸分布很窄的量子点,以满足量子点光电器件方面应用的要求。     

离子注入机的国内外现状

本文简要介绍了离子注入和器件的关系,概述了离子注入机的发展现状和趋势,初步探讨了我国离子注入机不能形成产业的原因。     

Rejection of narrowband interference in DS spread spectrum systemsemploying minimum redundant nonlinear filters

A new nonlinear filter structure, the minimum redundant nonlinear filter (MRNF), for combating narrowband interference in direct sequence spread spectrum systems is proposed. Analytical expressions for the signal-to-noise ratio improvement factors are derived under the condition of single tone interference. The results show that the MRNF provides significantly better performance than the minimum redundant transversal filter