Preparation and NMR studies of cobalt-containing diphosphine ligand chelated W, Ru, Au and Pd complexes: Suzuki cross-coupling reactions and carbonylation catalyzed by the Pd complex

Treatment of a cobalt-containing diphosphine ligand, [[mu-P,P-PPh2CH2PPh2]Co2(CO)4[mu-PPh2C[triple bond]CPPh2]] 1 with metal complexes W(CO)6, Ru3(CO)12, AuCl(tht)(tht = tetrahydrothiophene) and (COD)PdCl2(COD = 1,5-cycloctadiene) gave 1-chelated metal complexes [(1)W(CO)4], [(mu-1)Ru3(CO)10] 4, [(1)(AuCl)2] 5 and [(1)PdCl2] 6, respectively. All these compounds were characterized by spectroscopic means whereas 3, 4 and 6 were also studied by X-ray diffraction. These compounds display chelating and bridging modes of metal-phosphine complexation. Variable-temperature 1H and 31P NMR experiments were carried out for 3-6 and revealed that the fluxional behavior of each individual bridging dppm fragment was affected greatly by the bite angle of 1 in each metal complex. Suzuki cross-coupling reactions were satisfactorily catalyzed by under mild conditions. The reactions of aryl halides or iodothiophenes with chloroform and alkali in biphasic solution utilizing a catalytic amount of result into the formation of benzoic and thiophenic acids, respectively.     

Stabilization of a K+-(bis-Cage-Annulated 20-Crown-6) Complex by Bidentate Picrate

Bis-cage-annulated 18-crown-6 and 20-crown-6 macrocyclic ethers (i.e., 1 and 2, respectively) have been synthesized, and their alkali metal picrate extraction profiles have been determined. Host system 1 proved to be a significantly more avid alkali metal cation complexant than 2 and somewhat more avid than 18-crown-6. Both 1 and 18-crown-6 display modest selectivity toward K⁺ and Rb⁺. A stable host–guest complex was prepared by slow evaporation of a CH₂Cl₂–hexane solution of an equimolar mixture of 2 and potassium picrate. The X-ray crystal structure of this complex reveals that picrate anion functions as a bidentate ligand therein. The gas-phase interaction energy between the 2 K⁺ complex and picrate anion was calculated to be ca. –64.9 kcal mol^–1, thereby indicating that participation of picrate anion as an additional bidentate ligand results in significant stabilization of complex 10.     

Enhancement of chiral recognition by formation of a sandwiched complex in capillary electrophoresis

For chiral primary amino compounds not separable by cyclodextrins alone, chiral recognition was successfully achieved by the formation of a sandwiched complex of the non-chiral 18-crown-6, the chiral amine and cyclodextrin (CD) [18-crown-6+amino compound+CD]. The separation of 1-methyl-3-phenylpropylamine and 1,2,3,4-tetrahydro-1-naphthylamine racemates showed the special function of the non-chiral 18-crown-6 on chiral recognition. By formation of the sandwiched complex, the chiral center of 1-methyl-3-phenylpropylamine was successfully recognized, and resolution of 1,2,3,4-tetrahydro-1-naphthylamine dramatically increased. In these studies, the mobility differences of the enantiomers were evaluated as a function of the concentration of cyclodextrins with and without the 18-crown-6, and as a function of the concentration of the 18-crown-6. In addition, the separations by this method were compared to those by the chiral 18-crown-6 reagent.     

STUDY ON PREPARATION OF INORGANIC COMPOSITE MEMBRANE AND ITS PROPERTIES FOR HYDROGEN PERMEATION

IntroductionDevclopmcntoftcchniqucsforthcscparationofgascousmixturesisofgrcatimportancetochemicalindustries.Rccentadvanccsinceramicmaterialprocessinghavcstimulatedtheeffortstodcvclopccramicormctallicmcmbrancsforgasseparation.Suchmembraneswouldbesuitableforthescparationsathightemperatureatx`hichthcx`ellcstablishedorganicpol}mermcmbranescannotfunctionButmostcommercialceramicmembranesxvhichcanbcobtainedinmarkctaremicroporous(porediamcterfromO.ItoloPm)whereseparationmcchanismisgovcrncdbyKnudscnd…     

微量元素锌促进儿童生长发育临床研究

报道以微量元素锌治疗缺锌患儿１１８例并与１１４例作对照观察．结果发现，衡量生长发育与营养的敏感指标：身高、体重、血清白蛋白及血色素等参数，治疗组比对照组都显著提高（Ｐ值＜０．０１）．证明锌制剂对缺锌儿童有显著的促进生长发育及改善营养状态作用，作者并对锌的作用机理作了论述．     

BaLaB_9O_（16）中Ce~（3＋）敏化Dy~（3＋）发光的机理

在紫外光激发下，研究了ＢａＬａＢ９Ｏ（１６）中Ｄｙ（３＋）、Ｃｅ（３＋）的发光光谱、激发光谱、发光强度及荧光寿命随着组成变化的规律性．结果表明：Ｄｅ（３＋）对Ｄｙ（３＋）的发光有相当强的敏化作用，Ｃｅ（３＋）→Ｄｙ（３＋）的能量传递效率可高达９３％，能量传递的机理为电偶极－偶极相互作用的共振传递．根据３４９ｎｍ激发下Ｄｙ（３＋）发光强度与浓度的关系，证明了Ｄｙ（３＋）发光的自身浓度猝灭机理也为电偶极－偶极相互作用．     

聚碳酸酯合成工艺开发的新进展

本文从工艺开发的角度，简要评介了目前聚碳酸酯两大工业生产工艺，即光气化界面缩聚工艺和熔融酯交换缩聚工艺的研究开发新动向。     

CnB-的激光等离子体产生与质谱分析

Time-of-flight mass spectrum of C_nB~- has been recorded on a selfbuilt instrument with laser vaporization of tetraphenylboron sodium. By analysis of the com-position of the anions, it is found that number of the boron atoms in any of these ions equals to the number of the charges carried by the anion, and the sum of the numbers of the carbon and boron atoms in these species are always the odd numbers. The experimental results show that boron atom has a strong tendency to attract an electron so that those C_nB~- will have similar electronic structures as C_n, and carbon clusters with odd members are always more stable than their even neighbors.     

Bis(m-phenylene)-32-crown-10-based cryptands, powerful hosts for paraquat derivatives

Four new bis(m-phenylene)-32-crown-10-based cryptands with different third bridges were prepared. Their complexes with paraquat derivatives were studied by proton NMR spectroscopy, mass spectrometry, and X-ray analysis. It was found that these cryptands bind paraquat derivatives very strongly. Specifically, a diester cryptand with a pyridyl nitrogen atom located at a site occupied by either water or a PF(6) anion in analogous complexes exhibited the highest association constant K(a) = 5.0 x 10(6) M(-1) in acetone with paraquat, 9000 times greater than the crown ether system. X-ray structures of this and analogous complexes demonstrate that improved complexation with this host is a consequence of preorganization, adequate ring size for occupation by the guest, and the proper location of the pyridyl N-atom for binding to the beta-pyridinium hydrogens of the paraquat guests. This readily accessible cryptand is one of the most powerful hosts reported for paraquats.     

萃取分光光度法测定废烟末中的尼古丁

本文在ｐＨ４．５的乙酸－乙酸钠缓冲溶液中，使烟碱与甲基橙生成稳定的黄色络合物，然后用二氯甲烷萃取。于λｍａｘ＝４３５ｎｍ处测定有机相的吸光度，烟碱浓度在０－６５μｇ／５ｍＬ范围内符合比尔定律，摩尔吸光系数为９．８％１０＾３Ｌ．ｍｏｌ＾－＾１．ｃｍ＾－＾１。方法快速，简便，应用于烟草中烟碱的定量分析，其加标回收率在８１－１０９％之间，相对标准偏差小于４．１％。