Water‐Stable,Magnetic Silica–Cobalt/Cobalt Oxide–Silica Multishell Submicrometer Spheres

A method to produce monodisperse magnetic composite spheres with diameters from less than 100 nm to more than 1 μm in water solution is reported. The spheres consist of a dielectric silica core and a cobalt/cobalt oxide shell which can be protected from further oxidation with an outer shell of silica or, alternatively, they can be covered with the polymer polyvinylpyrrolidone as a stabilizer. The formation of a uniform magnetic shell proceeds with the adsorption of metallic cobalt seeds, produced by the reduction of cobalt chloride with sodium borohydride, on a self‐assembled layer of polyelectrolytes on the silica core. In the second step, an outer silica shell can be formed by the hydrolysis and condensation of (3‐aminopropyl)trimethoxysilane and tetraethoxysilane. The double‐shell composite spheres show excellent sphericity, monodispersity, and a magnetic hysteresis loop at room temperature.     

采用模数转换技术提高脉冲激光测距的测时精度

针对脉冲激光测距中计数量化误差影响测时精度的问题,本文提出了采用模数转换技术提高测时精度的方法,并进行了可行性与精度分析,理论与实践结果均表明,该方法易于实现,能够容易地将计数量化误差减少若干个数量级。     

Monoesterification of styrene–maleic anhydride copolymers with alcohols in ethyl benzene: Catalysis and kinetics

A kinetic investigation on the monoesterification reaction of the maleic anhydride residue (MA) in styrene-maleic anhydride copolymers with aliphatic alcohols was carried out in ethyl benzene solution. By comparison to classic catalysts such as tributylamine (TBA) and pyridine, 4-dimethylaminopyridine (4DMAP) is by far the most effective catalyst for this reaction. While both general base and nucleophilic mechanisms contribute to the reaction catalyzed by TBA or pyridine, a nucleophilic mechanism prevails with 4DMAP. This reaction is reversible, and its chemical equilibrium constant decreases significantly with increasing temperature. Both kinetic and thermodynamic results showed that in the presence of 4DMAP, the forward and reverse reactions are second and first order, respectively. The existence of side reactions, reactivity of two styrene-maleic anhydride copolymers of different MA contents as well as two aliphatic alcohols of different lengths are also addressed. © 1993 John Wiley & Sons, Inc.     

An overall study of convergence conditions for algorithms in nonlinear programming

Since the point-to-set maps were introduced by Zangwill^[1] in the study of conceptual algorithms, various sufficient conditions for the algorithms to be of global convergence have been established. In this paper, the relations among all these conditions are illustrated by a unified approach; still more, unlike the sufficient conditions previously given in the literature, a new necessary condition is put forward at the end of the paper, so that it implies more applications.     

Modeling electromigration lifetime under bidirectional currentstress

Electromigration reliability of interconnect under bidirectional current stress has been studied in a wide frequency range (mHz to 200 MHz). Experimental results show that the AC lifetime rises with the stress current frequency. The current density exponent and the activation energy of AC lifetime are found to be twice that of DC lifetime. Pure AC current stress failure at extremely high current density is believed to result from thermal migration of metal at hot/cold transition points     

THE EXISTENCE THEOREM OF THE CONE-WEAK SUBDIFFERENTIAL OF SET-VALUED MAPPING

In this paper, the existence theorem of the cone-weak subdiflerential of set-valued mapping in locally convex topological vector space is proved.     

用迁移率和载流子浓度研究碲镉汞中的深能级

获得了一种研究碲镉汞深能级的方法。通过分析迁移率 载子浓度与温度的关系，可以得到关于深能级的重要依据。     

络合沉淀法制备BaTiO_3超细粉末

在分析ＢａＴｉＯ_３前驱体形成机理的基础上，提出了以草酸作为络合剂，用络合沉淀法制备超细ＢａＴｉＯ_３新工艺。用化学分析法测定产物Ｂａ／Ｔｉ比，用ＸＲＤ、ＴＥＭ、ＢＩ－９０激光散射粒度仪对产物的晶型、粒度及形貌进行表征。结果表明：采用该法合成的前驱体，微观组分确定，粒径小，粒度分布窄，近似球形，煅烧后为高纯超细ＢａＴｉＯ_３粉末。     

中国的三种非同步轨道卫星移动通信系统星座方案

本文介绍基于我国的三种非同步轨道卫星移动通信系统星座方案：低、中轨系统各有２４和１８颗星，轨道高度分别为１３２６和８０３５ｋｍ，两系统各以５°和３０°的仰角对我国的覆盖率为９９．７８％和９９．９６％；椭圆轨道系统１２颗星，近、远地点分别为４２７和２９０６ｋｍ，以７°和１５°仰角对我国北纬２０°以上地区覆盖率分别为９７．９０％和８９．６１％，若增加４颗中轨卫星，以１５°仰角对我国的覆盖率为９９．９９％。     

B－ISDN与现有网络互连的研究

本文主要围绕Ｂ－ＩＳＤＮ与现有各种网络（如ＰＳＰＤＮ、ＰＳＴＮ、ＬＡＮ等）的互连问题展开讨论，并针对不同的应用场合提出了相应的互连解决方案。