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Two new polydentate ligands, 1‐(6‐hydroxymethyl‐2‐pyridyl)‐3‐(2‐pyridyl)‐propane‐1,3‐dione (6) and 1,3‐bis(6‐hydroxymethyl‐2‐pyridyl)‐propane‐1, 3‐dione (8), have been synthesized starting from 2,6‐pyridinedicarboxylic acid by conventional esterification, reduction, and condensation reactions. They were further converted to two new polydentate ligands, 3‐(6‐hydroxymethyl‐2‐pyridyl)‐5‐(2‐pyridyl)‐1H‐pyrazole (7) and 3,5‐bis(6‐hydroxymethyl‐2‐pyridyl)‐1H‐pyrazole (9), by reaction with hydrazine hydrate. These four compounds were characterized by proton nuclear magnetic resonance (1H NMR), electrospray ionization‐mass spectrum (ESI‐MS), infrared spectrum (IR), and elemental analyses. The structure of 9 was also determined by X‐ray diffraction. 相似文献
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We study a class of compressible non‐Newtonian fluids in one space dimension. We prove, by using iterative method, the global time existence and uniqueness of strong solutions provided that the initial data satisfy a compatibility condition and the initial density is small in its H1‐norm. The main difficulty is due to the strong nonlinearity of the system and the initial vacuum. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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We study the following complex Ginzburg-Landau equation with cubic nonlinearity on for under initial and Dirichlet boundary conditions u(x,0)=h(x) for x∈Ω, u(x,t)=Q(x,t) on ∂Ω where h,Q are given smooth functions. Under suitable conditions, we prove the existence of a global solution in H1. Further, this solution approaches to the solution of the NLS limit under identical initial and boundary data as a,b→0+. 相似文献
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Khoshtariya DE Wei J Liu H Yue H Waldeck DH 《Journal of the American Chemical Society》2003,125(25):7704-7714
Using nanometer thick tunneling barriers with specifically attached cytochrome c, the electron-transfer rate constant was studied as a function of the SAM composition (alkane versus terthiophene), the omega-terminating group type (pyridine, imidazole, nitrile), and the solution viscosity. At large electrode-reactant separations, the pyridine terminated alkanethiols exhibit an exponential decline of the rate constant with increasing electron-transfer distance. At short separations, a plateau behavior, analogous to systems involving -COOH terminal groups to which cytochrome c can be attached electrostatically, is observed. The dependence of the rate constant in the plateau region on system properties is investigated. The rate constant is insensitive to the mode of attachment to the surface but displays a significant viscosity dependence, change with spacer composition (alkane versus terthiophene), and nature of the solvent (H(2)O versus D(2)O). Based on these findings and others, the conclusion is drawn that the charge-transfer rate constant at short distance is determined by polarization relaxation processes in the structure, rather than the electron tunneling probability or large-amplitude conformational rearrangement (gating). The transition in reaction mechanism with distance reflects a gradual transition between the tunneling and frictional mechanisms. This conclusion is consistent with data from a number of other sources as well. 相似文献
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多路节目复用器是各种数字电视传输系统的关键设备之一,自行设计复用系统专用芯片己成为我国数字电视系统需要解决的迫切问题。首先介绍了多路数字节目复用器中的对多路预处理传送流复用的原理,提出了一套基于FPGA(现场可编程门阵列)的复用器输入部分设计方案。通过实践验证,达到了设计要求。 相似文献