Study on deactivation and regeneration of Pd/Al2O3 catalyst in hydrogen peroxide production by the anthraquinone process

Deactivated palladium catalysts in the hydrogenation of anthraquinione were regenerated with ethanol, nitric acid, hydrogen peroxide, boiling water and steam, respectively. The deactivated and regenerated catalysts were characterized by XPS, ICP, TG, FTIR, TPD, XRD, etc., and studied in the hydrogenation of anthraquinone. The results showed that the main cause of catalyst deactivation is the coverage of the active component by deposits. The treatments by hydrogen peroxide and boiling water can effectively regenerate the deactivated catalysts. This revised version was published online in August 2006 with corrections to the Cover Date.     

高斯光束计算平板波导自由传输区远场分布及其修正

对近轴近似条件下求解亥姆霍兹方程得到的高斯光束显式传播公式做了分析，同时，基于基尔霍夫衍射理论，在菲涅耳近似的条件下给出了相应的高斯光束在远场的传播公式，在此基础上，对近轴近似条件做出了定量分析，给出了这个近似条件引入的误差，提出了一种计算高斯光束远场分布的修正方法，并采用有限差分-光束传播方法(FD-BPM)来检验各种方法的准确性。把这种修正方法应用到平面光集成波导器件，如阵列波导光栅(AWG)、蚀刻衍射光栅(EDG)等器件的设计和模拟中，可以大大降低工作的复杂性，同时可以得到精确的结果。     

An Improved Synthesis of Retinoic Acid from β-Ionone

A convenient and large-scale preparation of retinoic acid 1 from β-ionone in five steps with 38% overall yield is described.The key steps are the epoxidization of 2 with a new methylated agent and the condensation 4 with tetraethyl methylenediphophonate in one-pot procedure to prepare 6.     

Chemical compositions and optical properties of HfOxNy thin films at different substrate temperatures

High-k HfO_xN_y thin films have been grown by radio frequency (rf) reactive sputtering of metal Hf target in N₂/Ar/O₂ ambient at different substrate temperatures. The chemical compositions of the films have been investigated as a function of substrate temperature by X-ray photoelectron spectroscopy (XPS). XPS measurements showed that nitrogen concentration increases with an increase in substrate temperature. Room-temperature spectroscopic ellipsometry (SE) with photon energy 0.75–6.5 eV was used to investigate the optical properties of the films. SE results demonstrated that refractive index n increases with an increase in substrate temperature. Based on TL parameters which were obtained from the best fit results used in a simulation of the measured spectra, meanwhile, we conclude that the energy band gap (E_g) decreases with an increase in substrate temperature.     

高阻值Cd1-xZnxTe晶体的生长及其性能测试

通过适当的工艺措施，采用Bridgman法生长了直径为30mm的X射线及γ射线探测器级的Cd.9Zn0．1Te晶锭．测试结果表明：该晶锭结晶质量良好，位错密度低，成分均匀，杂质含量低，红外透过率和电阻率都十分接近本征Cd.9Zn0．1Te的值．并从晶体的生长特性、缺陷和杂质的角度，分析了生长高性能晶体的条件，研究了生长Cdl-xZnxTe晶体的x值与缺陷和杂质浓度之间的关系．     

DVB数据广播中对象轮播技术的研究与实现

依据数字电视系统中数据广播规范对数字电视系统的增值业务——数据广播进行论述，着重对对象轮播的数据封装和传输规范进行分析，提出在终端设备上采取对象轮播技术实现数据广播业务的方法和思路，同时总结了对象轮播的特点及存在的问题。     

H.323同步控制实现研究

提出并实现了一种H.323多媒体通信系统音视频同步控制算法,算法以正常语音播放为基准,利用H.263码流语法信息,通过调整视频播放帧率实现媒体间同步, 不增加通信冗余度。实际测试结果表明,算法有效地提高了多媒体通信系统音视频媒体同步性能和多媒体的感知服务质量,并已应用于实际多媒体通信系统。     

浮栅技术及其应用

介绍了浮栅技术的基本原理及应用情况。井对2种应用了浮栅技术的典型器件-浮栅MOS晶体管和神MOS晶体管做了详细介绍，分析了他们的基本结构和工作原理，以及建立浮栅MOS晶体管的等效模型，并说明了他们的应用情况及存在的不足。     

ADSL MODEM 远程管理方案浅析

阐述了ADSLMODEM远程管理的意义及应遵循的原则，并对远程管理的方案作了简要阐述，最后比较分析了不同方案的优缺点。     

Dreamweaver UltraDev环境下实现数据库的动态链接

简要论述了如何在Dreamweaver UltraDev环境下实现对已有的Access或Excel数据库的动态链接的操作。在Dreamweaver UltraDev环境下，实现对企业、事业单位原有Access或Excel数据库的动态链接，可以在很短的时间内开发出符合单位实际情况的信息管理系统，并且可以使这类已经创建好的数据信息，不加任何修改地与外部进行交流，实现资源共享。将此系统以主页的形式链入Internet，可以实现开放式管理体系。