Activation volumes associated with chromophore reorientation in corona poled guest–host and side-chain polymers

The decay of the second-order optical susceptibility χ⁽²⁾ as a function of temperature and pressure has been studied in a variety of corona poled guest–host and side-chain polymeric materials using second harmonic generation (SHG). The specific systems studied include the side-chain copolymer poly(disperse red 1 methacrylate-co-methyl methacrylate) (DR1-MMA) as well as the series of guest–host materials formed by individually dissolving the dyes Disperse Red 1 (DR1), Disperse Orange 3 (DO3), and N,N dimethyl-p-nitroaniline (DpNA) in poly(methyl methacrylate) (PMMA), polycarbonate (PC), and polystyrene (PS). In each of these systems, the observed relaxation of χ⁽²⁾ can be represented by a Kohlrausch-Williams-Watts stretched exponential, from which the decay time τ and decay distribution width β are determined. For pressures up to approximately 1000 atm, the natural log of the pressure shift factor is seen to vary linearly with applied pressure, yielding the activation volume for rotational reorientation of the chromophores in each system. The activation volumes are loosely correlated with dopant size in a given polymer host, but are not the same for a given dopant in different hosts. Modeling the chromophores as rotating cylinders, we show that the measured activation volumes do not correspond to the average volume swept out by the dye molecules as they reorient. On the other hand, the activation volumes for each of the three dyes dissolved in PS are seen to be in agreement with the measured activation volumes for the molecular motions associated with volume recovery in neat PS. Moreover, the activation volumes for DR1 and DpNA dissolved in PS are seen to correlate with the proposed couplings between the rotational reorientation of DR1 and the α-relaxation dynamics of PS and the slight decoupling of DpNA from the α-transition motion of PS. This correlation suggests a possible relationship between the activation volumes for chromophore reorientation and the size of the components of the host polymer or the volume swept through by the polymer components during structural reconfiguration. We demonstrate that assuming activation volumes for chromophore reorientation to be related to the size or motion of the polymer host constituents yields a consistent interpretation of the observed trends in the measured activation volumes. © 1995 John Wiley & Sons, Inc.     

Application of a two-layer planarization process to VLSI intermetaldielectric and trench isolation processes

The application of a novel planarization process using a sacrificial fill layer of photoresist is presented. The process is shown to solve the planarization problems encountered in both intermetal dielectric for a 1.2 μm 256 K SRAM technology and trench isolation for a0.8-μm 1M SRAM technology. The process is a simple extension of the standard dielectric etch-back scheme. A discussion of how to precisely quantify circuit planarization using well-known techniques is also presented. This information can then be adapted for statistical quality control purposes     

Calibration methods for time domain network analysis

Accurate calibration techniques for the characterization of general one- and two-port networks using time domain reflection/transmission (TDR/T) measurements are presented. Simple one-port open-short-match corrections formulated by W.M. Scott and G.S. Smith (1986) are generalized for three arbitrary known loads and extended to the two-port case. Known, general frequency-domain techniques are shown to be directly applicable to the time-domain measurements, including the use of redundancy to reduce the number of required calibration standards. A time-domain thru-match-short method similar to the TRL method of G.F. Engen and C.A. Hoer (1979) is presented. Examples of the measured results for typical one- and two-port devices are included and compared with vector network analyzer measurement results to validate the time domain network analysis algorithms     

A high-performance 0.5-μm BiCMOS technology for fast 4-Mb SRAMs

A high-performance 0.5-μm BiCMOS technology has been developed. Three layers of polysilicon are used to achieve a compact four-transistor SRAM bit cell size of less than 20 μm² by creating self-aligned bit-sense and V_ss contacts. A WSi_x polycide emitter n-p-n transistor with an emitter area of 0.8×2.4 μm² provides a peak cutoff frequency (f_T) of 14 GHz with a collector-emitter breakdown voltage (BV_CFO) of 6.5 V. A selectively ion-implanted collector (SIC) is used to compensate the base channeling tail in order to increase f_T and knee current without significantly affecting collector-substrate capacitance. ECL gate delays as fast as 105 ps can be obtained with this process     

C(6)N(7)-cyclized purines

By reaction of 6-[N-(2-hydroxyethyl)-N-methyl]aminopurine ( 2a ) and of the corresponding 3-hydroxypropyl derivative 2b with thionyl chloride a bridge to N(1) is formed yielding 5 and 6 , respectively, whereas from 6-[N-(4-hydroxybutyl)-N-methyl]aminopurine ( 2c ) the 4-chlorobutyl compound 4 is obtained, which cyclizes in alkaline medium to the C(6)-N(7) bridged compound 7 . A related cyclization to 11a–11f is observed when 6-chloropurines are reacted with 3-alkyl-1,3-oxazolidines or 3-methyl-1,3-thiazolidine.     

Analyses of tetracyline antibiotics by reversed-phase high-performance liquid chromatography

Summary A high-performance liquid chromatographic (HPLC) separation was developed that is generally applicable to nine commercially important tetracyline antibiotics. The general method uses an isocratic system and mobile phase consisting of 0.001MEDTA, pH 6.6, and methanol and a Vydac C₁₈ reversed-phase column. Quantitation of the particular tetracyline in some commercial preparations is accomplished by adjusting the mobile phase composition. Quantitative assays were developed for small amounts of 4-epitetracycline in tetracycline (TC) preparations, demeclocycline in minocycline preparations and TC in chlortetracycline (chlor-TC) preparations. A fast HPLC assay for potency was also developed for chlor-TC and minocycline in these commercial preparations.