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41.
42.
Infinite Polyiodide Chains in the Pyrroloperylene–Iodine Complex: Insights into the Starch–Iodine and Perylene–Iodine Complexes
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Dr. Sheri Madhu Hayden A. Evans Dr. Vicky V. T. Doan‐Nguyen Dr. John G. Labram Dr. Guang Wu Prof. Dr. Michael L. Chabinyc Prof. Dr. Ram Seshadri Prof. Dr. Fred Wudl 《Angewandte Chemie (International ed. in English)》2016,55(28):8032-8035
We report the preparation and X‐ray crystallographic characterization of the first crystalline homoatomic polymer chain, which is part of a semiconducting pyrroloperylene–iodine complex. The crystal structure contains infinite polyiodide I∞δ?. Interestingly, the structure of iodine within the insoluble, blue starch–iodine complex has long remained elusive, but has been speculated as having infinite chains of iodine. Close similarities in the low‐wavenumber Raman spectra of the title compound and starch–iodine point to such infinite polyiodide chains in the latter as well. 相似文献
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Molecular imprinting is an attractive tool for the development of artificial recognition systems. Even non-covalent imprinting
provides universal interaction centers for sensoric applications. The coated chemical sensors have high stabilities under
harsh conditions in both the gas and liquid phases. With adequate efforts optical and mass-sensitive sensors (quartz crystal
microbalance, QCM, surface acoustic wave detector, SAW) are suitable for analysis down to the ppb (nL/L) range. PAHs, isomer
VOCs as well as complex oil mixtures are appropriate analytes.
Received: 4 November 1998 / Revised: 29 April 1999 / Accepted: 5 May 1999 相似文献
45.
Activation volumes for chromophore reorientation were measured for a series of guest–host polymeric materials, indicating a significant coupling between chromophore motion and the glassy α and β relaxation dynamics of the polymer host. The specific systems studied were formed by individually dissolving N,N-dimethyl-p-nitroaniline (DpNA), 4-(dimethylamino)-4′-nitrotolane (DMANT), 4-(diethylamino)-4′-nitrotolane (DEANT), and 1-((4-(dimethylamino)phenyl)ethynyl)-4-((4-nitrophenyl)ethynyl)benzene (DMAPEANT) in poly(methyl methacrylate) (PMMA), poly(ethyl methacrylate) (PEMA), and poly(isobutyl methacrylate) (PiBMA). In each of these systems, the isothermal, sub-Tg decay of the second-order optical susceptibility χ(2) was monitored as a function of pressure using second harmonic generation. In each system, the observed decay of χ(2) was represented by a stretched exponential equation from which the decay time τ0 and decay distribution width βKWW were determined. For each dopant molecule, the decrease in activation volume with the increasing size of the polymer host's alkyl side group and the pressure dependence of βKWW were indicative of partial coupling between chromophore rotation and the glassy β relaxation dynamics of the polymer host. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 1013–1024, 1998 相似文献
46.
Self-organized receptor layers are synthesized by molecular imprinting methods directly on pre-coated 10 MHz quartz-crystal microbalances (QCMs). The surface-imprinting is performed by three methods using amorphous, crystalline and solubilized trypsin, respectively, as templates. These attempts allowed us to compare imprinting results obtained with templating proteins in the dry state as well as in aqueous solution. All methods are generally applicable for surface imprinting of thin films. The biomimetic sensor layers allow selective enzyme enrichment on the imprinted electrode with detection limits as low as 100 ng ml(-1) and response times of a few minutes. Solution-based polymer imprinting with native trypsin as template resulted in the highest specific enzyme recognition, which even allowed us to distinguish denatured trypsin from the native form. 相似文献
47.
Silvio Dutz M.E. Hayden Allison Schaap Boris Stoeber Urs O. Häfeli 《Journal of magnetism and magnetic materials》2012
Magnetic microspheres (MMS) are useful tools for a variety of medical and pharmaceutical applications. Typically, commercially manufactured MMS exhibit broad size distributions. This polydispersity is problematic for many applications. Since the direct synthesis of monodisperse MMS is often fraught with technical challenges, there is considerable interest in and need associated with the development of techniques for size-dependent fractionation of MMS. In this study we demonstrated continuous size-dependent fractionation of sub-micron scale particles driven by secondary (Dean effect) flows in curved microfluidic channels. Our goal was to demonstrate that such techniques can be applied to MMS containing superparamagnetic nanoparticles. To achieve this goal, we developed and tested a microfluidic chip for continuous MMS fractionation. Our data address two key areas. First, the densities of MMS are typically in the range 1.5–2.5 g/cm3, and thus they tend be non-neutrally buoyant. Our data demonstrate that efficient size-dependent fractionation of MMS entrained in water (density 1 g/cm3) is possible and is not significantly influenced by the density mismatch. In this context we show that a mixture comprising two different monodisperse MMS components can be separated into its constituent parts with 100% and 88% success for the larger and smaller particles, respectively. Similarly, we show that a suspension of polydisperse MMS can be separated into streams containing particles with different mean diameters. Second, our data demonstrate that efficient size-dependent fractionation of MMS is not impeded by magnetic interactions between particles, even under application of homogeneous magnetic fields as large as 35 kA/m. The chip is thus suitable for the separation of different particle fractions in a continuous process and the size fractions can be chosen simply by adjusting the flow velocity of the carrier fluid. These facts open the door to size dependent fractionation of MMS. 相似文献
48.
Recent work has precisely characterized the achievable trade-offs between three key information processing tasks-classical communication (generation or consumption), quantum communication (generation or consumption), and shared entanglement (distribution or consumption), measured in bits, qubits, and ebits per channel use, respectively. Slices and corner points of this three-dimensional region reduce to well-known protocols for quantum channels. A trade-off coding technique can attain any point in the region and can outperform time sharing between the best-known protocols for accomplishing each information processing task by itself. Previously, the benefits of trade-off coding that had been found were too small to be of practical value (viz., for the dephasing and the universal cloning machine channels). In this Letter, we demonstrate that the associated performance gains are in fact remarkably high for several physically relevant bosonic channels that model free-space or fiber-optic links, thermal-noise channels, and amplifiers. We show that significant performance gains from trade-off coding also apply when trading photon-number resources between transmitting public and private classical information simultaneously over secret-key-assisted bosonic channels. 相似文献
49.
Ye F Wu C Jin Y Wang M Chan YH Yu J Sun W Hayden S Chiu DT 《Chemical communications (Cambridge, England)》2012,48(12):1778-1780
We demonstrate a new compact CN-PPV dot, which emits in the orange wavelength range with high brightness. The small particle size, high brightness, and the ability to highly specifically target subcellular structures make the CN-PPV dots promising probes for biological imaging and bioanalytical applications. 相似文献
50.
Taft R.C. Lage C.S. Hayden J.D. Kirsch H.C. Lin J.-H. Denning D.J. Shapiro F.B. Bockelman D.E. Camilleri N. 《Electron Devices, IEEE Transactions on》1995,42(7):1277-1286
We present the process development and device characterization of the Selectively Compensated Collector (SCC) BJT specifically designed for high-density deep-submicrometer BiCMOS SRAM technologies. This double-poly BJT takes advantage of the self-aligned polysilicon layers of the SRAM bit cell to obtain high performance without adding excessive process complexity. Furthermore, although an NPN device, the SCC BJT is formed in a lightly doped p-well in which the collector is formed with a single 370 keV phosphorus implant to minimize parasitic junction capacitances without the use of trench isolation or recessed oxides. The suitability of this bipolar structure outside of its original FSRAM intent is proven with its potential for bipolar logic and mixed-mode RF applications. ECL delays of 50 ps at 200 μA and a CML power-delay product of 4.5 fJ at 1.1 V supply were obtained. A 900 MHz noise figure as low as 0.54 dB at 0.5 mA with an associated gain of 14.7 dB was demonstrated as well as a dual modulus ÷4/5 prescaler operating up to 3.3 GHz for a switch current of 200 μA 相似文献