Nonlinear dynamical magnetosonic wave interactions and collisions in magnetized plasma

The one-dimensional nonlinear dynamical wave interactions in a system of quasineutral two-fluid plasma in a constant magnetic field are investigated.The existence of the travelling wave solutions is discussed.The modulation stability of linear waves and the modulation instability of weakly nonlinear waves are presented.Both suggest that the Korteweg-de Vries(KdV) system is modulationally stable.Besides,the wave interactions including the periodic wave interaction and the solitary wave interactio...     

椭圆形孔扩张弹性分析

圆孔扩张理论作为一种相对成熟的理论工具已经广泛运用于岩土工程中的各类问题,但是对于初始孔为椭圆孔的扩孔问题,圆孔扩张理论并不适用.基于保角变换的方法将原物理平面上初始椭圆孔洞的外部映射到像平面上的单位圆外部,将原物理平面上由于椭圆孔洞扩张所产生的位移边界条件转换到像平面上,利用平面复变弹性理论,得到初始椭圆形孔洞孔扩张的弹性解.将论文椭圆孔扩张的退化解与传统圆孔扩张的弹性解进行对比分析,验证椭圆孔扩张弹性解的正确性.续而,针对一算例详细分析了椭圆孔扩张的弹性力学特性.研究结果表明,椭圆孔的退化解与传统的圆孔扩张弹性解完全一致,椭圆孔在弹性扩张过程中长轴方向比短轴方向较难扩张,长轴方向需要的扩张压力比短轴方向的要大.此外,当扩张率a2/a1=0.11/0.1=1.1时,扩张的影响半径为10倍的孔径左右.     

基于遗传算法的三维电场传感器解耦标定方法研究

3维电场分量对传感器输出信号的耦合干扰是影响3维电场探测准确性的关键问题。为了减小耦合干扰,实现3维电场的准确测量,该文提出一种基于遗传算法的3维电场传感器解耦标定方法。区别于求逆矩阵运算的传统标定方法,该方法利用遗传算法并行全局搜索的特点,通过设置适应度函数和遗传算子获得最优化解耦标定矩阵,避免了复杂的矩阵求逆计算,减小了计算误差。该文设计了一种可实现传感器与电场矢量成任意夹角的测试标定装置,建立了电场理论值计算模型。对基于矩阵求逆计算和基于遗传算法的两种解耦标定方法进行了对比实验,实验结果表明,基于遗传算法的3维电场传感器解耦标定方法与传统标定方法相比,有效地消除了电场分量对传感器的耦合干扰,提高了标定精度,实现了3维电场的准确测量。     

Two birds one stone: β-fluoropyrrolyl-cysteine SNAr chemistry enabling functional porphyrin bioconjugation

Bioconjugation, a synthetic tool that endows small molecules with biocompatibility and target specificity through covalent attachment of a biomolecule, holds promise for next-generation diagnosis or therapy. Besides the establishment of chemical bonding, such chemical modification concurrently allows alteration of the physicochemical properties of small molecules, but this has been paid less attention in designing novel bioconjugates. Here, we report a “two birds one stone” methodology for irreversible porphyrin bioconjugation based on β-fluoropyrrolyl-cysteine S_NAr chemistry, in which the β-fluorine of porphyrin is selectively replaced by a cysteine in either peptides or proteins to generate novel β-peptidyl/proteic porphyrins. Notably, due to the distinct electronic nature between fluorine and sulfur, such replacement makes the Q band red-shift to the near-infrared region (NIR, >700 nm). This facilitates intersystem crossing (ISC) to enhance the triplet population and thus singlet oxygen production. This new methodology features water tolerance, a fast reaction time (15 min), good chemo-selectivity, and broad substrate scope, including various peptides and proteins under mild conditions. To demonstrate its potential, we applied porphyrin β-bioconjugates in several scenarios, including (1) cytosolic delivery of functional proteins, (2) metabolic glycan labeling, (3) caspase-3 detection, and (4) tumor-targeting phototheranostics.

This work demonstrates ‘two birds one stone’ β-fluoropyrrolyl-cysteine SNAr chemistry. This methodology not only achieves porphyrin peptide/protein conjugates but also induces attractive porphyrinic photophysical properties to facilitate promising biological applications.     

基于电阻型频率选择表面的超宽带紧耦合阵列

针对接地板严重影响紧耦合天线阵列(Tightly Coupled Array,TCA)阻抗带宽的问题,设计了一种基于电阻型频率选择表面(Resistive Frequency Selective Surface,RFSS)的多层结构超宽带TCA,分析了电阻膜方阻及单元间耦合对阻抗带宽的影响,并对其扫描及未扫描时的性能进行了仿真分析.结果表明:通过在天线阵列与接地板之间加载开口谐振环结构的RFSS,可减小接地板反射,抑制天线短路点,显著增加其阻抗带宽,其辐射性能在整个带宽内均较稳定;由于RFSS加入了损耗,天线阵列增益有所降低.该多层结构TCA具有带宽宽、体积小、易共形等特点,在超宽带小型化相控阵天线中有良好应用前景.     

Fluorination of Terminal Groups Promoting Electron Transfer in Small Molecular Acceptors of Bulk Heterojunction Films

The fluorination strategy is one of the most efficient and popular molecular modification methods to develop new materials for organic photovoltaic (OPV) cells. For OPV materials, it is a broad agreement that fluorination can reduce the energy level and change the morphology of active layers. To explore the effect of fluorination on small molecule acceptors, we selected two non-fullerene acceptors (NFA) based bulk heterojunction (BHJ) films, involving PM6:Y6 and PM6:Y5 as model systems. The electron mobilities of the PM6:Y5 and PM6:Y6 BHJ films are 5.76 × 10⁻⁷ cm²V⁻¹s⁻¹ and 5.02 × 10⁻⁵ cm²V⁻¹s⁻¹ from the space-charge-limited current (SCLC) measurements. Through molecular dynamics (MD) simulation, it is observed that halogen bonds can be formed between Y6 dimers, which can provide external channels for electron carrier transfer. Meanwhile, the “A-to-A” type J-aggregates are more likely to be generated between Y6 molecules, and the π–π stacking can be also enhanced, thus increasing the charge transfer rate and electron mobility between Y6 molecules.     

基于导弹尾焰特征谱的SVDD检测方法

现有天基红外导弹预警系统对目标的探测侧重于对红外图像的处理。从光谱维数据分析角度出发结合支持向量数据描述基本理论,提出了一种基于导弹尾焰特征谱的SVDD检测方法。应用小样本训练数据建立了单分类器,以11型导弹目标的红外辐射尾焰特征谱数据作为训练样本,比较了RBF 与 SSM 作为核函数的检测效果,应用交叉检验的方法确定宽度因子和相似临界因子的值,结果表明,在低信噪比红外图像中,基于SSM-Kernel的SVDD检测性能优于基于RBF-Kernel的检测性能。应用训练样本数据的辐射双峰所对应中心波长作为匹配模板进行识别,实验表明方法具有可行性。     

变分模态分解在爆破信号趋势项去除中的应用

爆破工程中,信号趋势项的准确去除对提高爆破振动信号分析的精度具有重要意义。针对经验模态分解（empirical mode decomposition,EMD）识别法存在的模态混叠和端头效应等缺陷,提出了基于变分模态分解（variational mode decomposition,VMD）去除信号趋势项的方法,即VMD法。叙述了VMD法识别爆破信号趋势项原理,并进行了仿真实验,结果表明：趋势项频率对分解效果的影响相对较小,当趋势项频率处于1～5 Hz之间时,频率对分解效果的影响基本保持不变;振幅对分解效果影响显著,且振幅越小,VMD法的分解效果越差。当趋势项振幅超过原始爆破信号最大振幅的1/3时,VMD法分解效果较好。最后,应用VMD法和EMD法对含有趋势项的实测爆破振动信号进行处理,认为相比于EMD法,VMD法处理后的信号基本一致且不存在端点效应,在爆破信号趋势项去除领域中具有更加广泛的适用性。

     

浅议梁的强度与刚度的关系1)

本文提出了梁的强刚比的定义,用无量纲的形式定量地表达了梁的强度与刚度之间的关系,以期充分发挥材料的潜力并促进材料力学的课堂教学。强刚比与载荷大小无关,其数值可以通过有限元方法或者通过梁的载荷试验来获得。结合工程实际,从设计和试验两个方面对梁的强刚比 及其影响因素进行了简要地探讨和分析。     

一种基于免疫系统的RBF网络在线训练方法

 针对径向基函数(RBF)网络和免疫系统的相似性,本文提出了一种基于免疫模型的RBF网络在线学习方法以解决动态问题.该方法借鉴了免疫系统动态调整以对抗不断入侵的抗原的机制,通过免疫初步覆盖、免疫交叉响应和疫苗注射等免疫操作,加速算法效率、提高算法精度和动态性能.通过以上操作使得RBF网络能够根据样本的变化迅速地调整网络结构与参数.计算机仿真研究表明,采用这种方法设计的RBF网络在动态环境下具有优良的精度和泛化能力.