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121.
Electron spin relaxation times and rapid scan EPR imaging of pH‐sensitive amino‐substituted trityl radicals 下载免费PDF全文
Hanan B. Elajaili Joshua R. Biller Mark Tseitlin Ilirian Dhimitruka Valery V. Khramtsov Sandra S. Eaton Gareth R. Eaton 《Magnetic resonance in chemistry : MRC》2015,53(4):280-284
Carboxy‐substituted trityl (triarylmethyl) radicals are valuable in vivo probes because of their stability, narrow lines, and sensitivity of their spectroscopic properties to oxygen. Amino‐substituted trityl radicals have the potential to monitor pH in vivo, and the suitability for this application depends on spectral properties. Electron spin relaxation times T1 and T2 were measured at X‐band for the protonated and deprotonated forms of two amino‐substituted triarylmethyl radicals. Comparison with relaxation times for carboxy‐substituted triarylmethyl radicals shows that T1 exhibits little dependence on protonation or the nature of the substituent, which makes it useful for measuring O2 concentration, independent of pH. Insensitivity of T1 to changes in substituents is consistent with the assignment of the dominant contribution to spin lattice relaxation as a local mode that involves primarily atoms in the carbon and sulfur core. Values of T2 vary substantially with pH and the nature of the aryl group substituent, reflecting a range of dynamic processes. The narrow spectral widths for the amino‐substituted triarylmethyl radicals facilitate spectral‐spatial rapid scan electron paramagnetic resonance imaging, which was demonstrated with a phantom. The dependence of hyperfine splittings patterns on pH is revealed in spectral slices through the image. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
122.
Hanan Alatawi Anna Hogan Ibtihaj Albalawi Emma O'Sullivan-Carroll Samia Alsefri Yineng Wang Eric Moore 《Electrophoresis》2022,43(20):1944-1952
A simple, rapid method using CE and microchip electrophoresis with C4D has been developed for the separation of four nonsteroidal anti-inflammatory drugs (NSAIDs) in the environmental sample. The investigated compounds were ibuprofen (IB), ketoprofen (KET), acetylsalicylic acid (ASA), and diclofenac sodium (DIC). In the present study, we applied for the first time microchip electrophoresis with C4D detection to the separation and detection of ASA, IB, DIC, and KET in the wastewater matrix. Under optimum conditions, the four NSAIDs compounds could be well separated in less than 1 min in a BGE composed of 20 mM His/15 mM Tris, pH 8.6, 2 mM hydroxypropyl-beta-cyclodextrin, and 10% methanol (v/v) at a separation voltage of 1000–1200 V. The proposed method showed excellent repeatability, good sensitivity (LODs ranging between 0.156 and 0.6 mg/L), low cost, high sample throughputs, portable instrumentation for mobile deployment, and extremely lower reagent and sample consumption. The developed method was applied to the analysis of pharmaceuticals in wastewater samples with satisfactory recoveries ranging from 62.5% to 118%. 相似文献
123.
Mukhtiar Ahmed Muhammad Nazim Lakhan Altaf Hussain Shar Irum Zehra Abdul Hanan Irfan Ali Muhammad Ahsan Latif Kishore Chand Asif Ali Jun Wang 《印度化学会志》2022,99(1):100281
Active nanocomposites synthesized by the electrochemical approach play a vital role in energy generation, conversion, and storage technologies. Recently, scientists began to explore the use of earth-rich transition metal-based materials to replace precious metal-based catalysts. Transition metals (TMs) based nickel (Ni) and their pnictides compounds such as phosphides and selenides exhibit good activity for hydrogen evaluation reaction (HER) and the entire water electrolysis process. In this study, we first prepared Ni(OH)2 and grown its layer on Ni foam (NF) and treated it with selenide (Se) and phosphide (P) then nickel-based selenide-phosphide catalyst (Ni–P–Se) was prepared by simultaneous selenization and phosphidation process for the first time. The as-obtained composite was then analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM), elemental mapping and transmission electron microscope (TEM) means to study the composition, structure, and micro-morphology of materials. Furthermore, we also observed electrocatalytic water splitting activity using electrochemical cell. The results of electrochemical tests depicted that the selenization and phosphidation treatments significantly enhanced the electrocatalytic HER activity of the starting materials. The overpotentials required for Ni–P–Se to reach 10 ?mA ?cm?2 and 100 ?mA ?cm?2 were only 242 ?mV and 282 ?mV. The Tafel slope of Ni–P–Se is 151 ?mV dec?1, which is lower than that of nickel phosphide, selenide, and hydroxide indicating that selenide-phosphide enhances the HER reaction kinetics of the material, which in turn increases hydrogen output rate as compared with previous studies. 相似文献
124.
Hanan Alatawi Anna Hogan Ibtihaj Albalawi Emma O'Sullivan-Carroll Yineng Wang Eric Moore 《Electrophoresis》2022,43(7-8):857-864
Paracetamol (PAC) is one of the most extensively used analgesics and antipyretic drugs to treat mild and moderate pain. P-aminophenol (PAP), the main hydrolytic degradation product of PAC, can be found in environmental water. Recently, CE has been developed for the detection of a wide variety of chemical substances. The purpose of this study is to develop a simple and fast method for the detection and separation of PAC and its main hydrolysis product PAP using CE and microchip electrophoresis with capacitively coupled contactless conductivity detection. The determination of these compounds using microchip electrophoresis with capacitively coupled contactless conductivity detection is being reported for the first time. The separation was run for all analytes using a BGE (20 mM β-alanine, pH 11) containing 14% (v/v) methanol. The RSDs obtained for migration time were less than 4%, and RSDs obtained for peak area were less than 7%. The detection limits (S/N = 3) that were achieved ranged from 0.3 to 0.6 mg/L without sample preconcentration. The presented method showed rapid analysis time (less than 1 min), high efficiency and precision, low cost, and a significant decrease in the consumption of reagents. The microchip system has proved to be an excellent analytical technique for fast and reliable environmental applications. 相似文献
125.
The dinuclear gold(I) amidinate complex [Au(2)(Me(2)-form)(2)], 1, (Me(2)-form = 2,6-Me(2)-formamidinate) reacts with Hg(CN)(2) to form a 2D structure, 1.2Hg(CN)(2).2THF. Each gold center interacts with two Hg(CN)(2) molecules. The Au...Au distance increases from 2.7 Angstroms in the starting dinuclear complex to 2.9 Angstroms in the adduct. The gold centers are connected to four nitrogen atoms with Au-N distances in the range 2.13-2.51 Angstroms. The cyanide stretch is shifted from 2192 cm(-1) in the Hg(CN)(2) to 2147 cm(-1) in the adduct. 相似文献
126.
Hanan Alyami 《School science and mathematics》2020,120(1):15-28
Empirical studies of angle, angle measure, and radian angle measure have primarily focused on documenting students' and teachers' conceptions. Representations of angle measure have the potential to inform and build on these conceptions. To gain insight into the concept of radian angle measure from a curricular perspective, I investigated the representations of radian angle measure in eight widely used U.S. high school mathematics textbooks. The data for this study are the 20 figures and the 8 definitions of radian angle measure in the textbooks. Inductive content analysis was used to identify the frequency of observable characteristics in the representations. Textbook figures of radian angle measure most frequently focus on a one-radian angle. Textbook figures also demonstrated radian angle measures in terms of π, in standard position, even when the Cartesian-coordinate plane was not in the figure. The frequently used characteristics of radian representations could inadvertently reinforce a qualitative concept of angle, instead of fostering the quantitative attributes of radian angle measure. Moving forward, analyzing conceptions that are evoked by the frequently used representations of radian angle measure could build a link between evidence from this study and studies of learning. 相似文献
127.
Samah Ben Atia Anis Messaoud Ridha Ben Abdennour 《Mathematical and Computer Modelling of Dynamical Systems: Methods, Tools and Applications in Engineering and Related Sciences》2018,24(1):26-43
In this paper, an online algorithm is proposed for the identification of unknown time-varying input delay in the case of discrete non-linear systems described by decoupled multimodel. This method relies on the minimization of a performance index based on the error between the real system and the partial internal models outputs. In addition, a decoupled internal multimodel control is proposed for the compensation of discrete non-linear systems with time-varying delay. This control scheme incorporates partial internal model controls. Each partial controller is associated to a specified operating zone of the non-linear system. The switching between these controllers is ensured by a supervisor that contains a set of local predictors. A simulation example is carried out to illustrate the significance of the proposed time-varying delay identification algorithm and the proposed internal multimodel control scheme. 相似文献
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130.
N. M. Ravindra Choong-Un Kim Anis Zribi Seung H. Kang 《Journal of Electronic Materials》2005,34(5):467-467