Blind per tone equalization of multilevel signals using support vector machines for OFDM in wireless communication

We present an efficient support vector machine (SVM)-based blind per tone equalization for OFDM systems. Blind per tone equalization using constant modulus algorithm (CMA) and multi-modulus algorithm (MMA) are used as the comparison benchmark. The SVM-based cost function utilizes a CMA-like error function and the solution is obtained by means of an iterative re-weighted least squares algorithm (IRWLS). Moreover, like CMA, the error function allows to extend the method to multilevel modulations. In terms of bit error rate (BER), simulation experiments show that the blind per tone equalization using SVM performs better than blind per tone equalization using CMA and MMA.     

Internet connection with UMTS

Mobile telecommunication new services are based on data networks specially Internet. These services include http, telnet, ftp, Simple Mail Transfer Protocol, etc. Besides, we recognize a mobile network as a multiuser network. Transmission Control Protocol (TCP)/Internet Protocol which is sensitive to link congestion in wireline data links is also used in wireless networks. In order to improve the system performance, the TCP layer uses flow control and congestion control. Besides, radio link control (RLC) and medium access control sublayers have been introduced to compensate the deficiency of TCP layer in wireless environment. RLC has an important role in quality of service enhancement of the Universal Mobile Telecommunications System (UMTS). In this paper, we review the protocol stack of UMTS Terrestrial Radio Access Network which is based on Third-Generation Partnership Project. Then, we evaluate its layer 2 error control mechanisms and verify TCP over automatic repeat request error control mechanism and finally quality of service improvement results from it in fading channels.     

Aluminum-27 NMR Investigations of Aqueous and Methanolic Aluminosilicate Solutions

Aluminum-27 NMR spectroscopy was used to characterize aqueous and methanolic alkaline solutions of tetramethylammonium (TMA) aluminosilicates. Aluminosilicate solutions have been prepared with different concentrations of silicon [0.577–1.24% (w/w)], aluminum [0.0022–0.239% (w/w)], methanol [0.0–0.70% (w/w)] and H₂O [0.23–90% (w/w)]. All solutions contain the same ratio of Si/TMA = 1 and Si/Al molar ratios between 0.5 and 25.²⁷Al NMR spectra of TMA aluminosilicate solutions are characterized by a variety of aluminosilicate species such as q¹(Al1OSi), q²(Al2OSi), q³(Al3OSi) and q⁴(Al4OSi). Aluminum-27 NMR spectra of TMA aluminosilicate solutions indicate that considerable changes occurred by changing the Si/Al ratio. The distribution of aluminosilicate species was affected by the presence of the methanol and the method of mixing the silicate and aluminosilicate solutions. A methanolic aluminosilicate solution needs about twice the time required for an aqueous aluminosilicate solution to reach a steady state, i.e., the latter takes 36 h to reach steady state. Results with the same concentration of silicon and aluminum show that the formation and distribution of aluminosilicate species are strongly dependent on the solvent comprising the silicate and aluminate solutions.     

Free resolutions of parameter ideals for some rings with finite local cohomology

Let be a -dimensional local ring, with maximal ideal , containing a field and let be a system of parameters for . If and the local cohomology module is finitely generated, then there exists an integer such that the modules have the same Betti numbers, for all .

     

Rock Salt Ni/Co Oxides with Unusual Nanoscale‐Stabilized Composition as Water Splitting Electrocatalysts

The influence of nanoscale on the formation of metastable phases is an important aspect of nanostructuring that can lead to the discovery of unusual material compositions. Here, the synthesis, structural characterization, and electrochemical performance of Ni/Co mixed oxide nanocrystals in the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is reported and the influence of nanoscaling on their composition and solubility range is investigated. Using a solvothermal synthesis in tert ‐butanol ultrasmall crystalline and highly dispersible Ni _x Co_{1? x} O nanoparticles with rock salt type structure are obtained. The mixed oxides feature non‐equilibrium phases with unusual miscibility in the whole composition range, which is attributed to a stabilizing effect of the nanoscale combined with kinetic control of particle formation. Substitutional incorporation of Co and Ni atoms into the rock salt lattice has a remarkable effect on the formal potentials of NiO oxidation that shift continuously to lower values with increasing Co content. This can be related to a monotonic reduction of the work function of (001) and (111)‐oriented surfaces with an increase in Co content, as obtained from density functional theory (DFT+U) calculations. Furthermore, the electrocatalytic performance of the Ni _x Co_{1? x} O nanoparticles in water splitting changes significantly. OER activity continuously increases with increasing Ni contents, while HER activity shows an opposite trend, increasing for higher Co contents. The high electrocatalytic activity and tunable performance of the nonequilibrium Ni _x Co_{1? x} O nanoparticles in HER and OER demonstrate great potential in the design of electrocatalysts for overall water splitting.     

Voltammetric Determination of Isoproterenol using a Graphene Oxide Nano Sheets Paste Electrode

3-(4'-Amino-3'-hydroxy-biphenyl-4-yl)-acrylic acid, was synthesized and used to construct a modified-graphene oxide nano sheets paste electrode. The electro-oxidation of isoproterenol at the surface of the modified electrode was studied using cyclic voltammetry, chronoamperometry, and square wave voltammetry. Under the optimized conditions, the square wave voltammetric peak currents of isoproterenol increased linearly with isoproterenol concentrations in the range of 2.5 × 10^–8 to 2.0 × 10^–5 M and detection limit of 12 nM was obtained for isoproterenol. Finally this modified electrode was used for determination of isoproterenol in some real samples.     

Acoustic Detection of Phase Transitions at the Nanoscale

Materials near structural phase transitions find applications in a wide range of devices. Typically, phase transitions are determined macroscopically through measurements of relevant order parameters and related property coefficients. Here, a method for understanding electric field induced phase transitions in ferroelectrically active materials at the nanometer scale via acoustic detection with band‐excitation piezoresponse force microscopy (BE‐PFM) is introduced. Specifically, the field‐induced rhombohedral (R) to tetragonal (T) phase transition in single crystal 0.72PbMg_1/3Nb_2/3O₃‐0.28PbTiO₃ (PMN‐PT) is mapped. It is shown that due to sample heterogeneity, some regions are more prone to the R–T transition, and display signatures in the acquired piezoresponse loops, as well as pronounced softening in the elastic modulus (monitored via the resonant frequency and calibrated with models of cantilever dynamics) that occurs just prior to phase switching. Landau–Devonshire thermodynamic theory confirms the stability of the tetragonal phase under applied fields in PMN‐PT, while phase‐field modeling suggests that the transition evolves smoothly in the probed volume of the tip, both in agreement with the BE‐PFM results. These results confirm the validity and utility of utilizing acoustic changes at phase transitions to detect their onset in nanoscale probed volumes, allowing spatial mapping of their onset with unprecedented resolution.