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21.
Summary The photogalvanic effect of ferrousbis-(acetylacetonate) (Fe(II)(acac)2) and ferrousbis-(trifluoroacetylacetonate) (Fe(II)(tfac)2) complexes in aqueous acetonitrile thionine dye solutions has been studied in a photogalvanic cell of 70 cm3 capacity with identical platinum electrodes (area: 0.25 cm2) using visible light (80 mW/cm2) at 25°C. The theoretical Sunlight Engineering Efficiency (SEE) was determined for both complexes and it was found that the best SEE was obtained when Fe(II)(tfac)2 was used at a concentration of 1.5×10–4 mol/dm3 with a thionine concentration of 1×10–4 mol/dm3 atpH=4 in 40% aqueous acetonitrile. Effects of incident light intensity and temperature on the photogalvanic performance and the action spectrum of the present system were also investigated. A mechanism of the photoredox reaction between the Fe(II)-complex and the dye molecule is proposed.
Der photogalvanische Effekt von Fe(II)--Diketonat/Thionin-Systemen in wäßrigem Acetonitril
Zusammenfassung Der photogalvanische Effekt von Eisen(II)-bis-(acetonylacetonat) (Fe(II)(acac)2) und Eisen(II)-bis-(trifluoracetylacetonat) (Fe(II)(tfac)2 in wäßriger acetonitrilischer Thioninlösung wurde in einer photogalvanischen Zelle (70 cm3) mit identischen Platinelektroden (Fläche: 0.25 cm2) mit sichtbarem Licht (80 mW/cm2) bei 25°C untersucht. Für beide Komplexe wurde die theoretische Sunlight Engineering Efficiency (SEE) bestimmt; der beste SEE-Wert wurde für Fe(II)(tfac)2 bei einer Konzentration von 1.5×10–4 mol/dm3 beipH=4 in 40%igem Acetonitril gefunden (Thioninkonzentration: 1.0×10–4 mol/dm3). Effekte, die durch Änderung der Lichtintensität und der Temperatur hervorgerufen werden, werden diskutiert. Ein Mechanismus für die Photoredoxreaktion zwischen dem Fe(II)-Komplex und dem Farbstoffmolekül wird vorgeschlagen.相似文献
22.
Clément Ghiazza Moussa Ndiaye Anfal Hamdi Anis Tlili Thierry Billard 《Tetrahedron》2018,74(45):6521-6526
Herein, the direct C-5 fluoroalkylselenolation of 8-aminoquinolines is described. The Pd-catalyzed reaction is performed with the in situ generated fluoroalkylselenyl chloride and various 8-aminoquinoline amides or sulfonamides. The desired products were formed in moderate to excellent yields. 相似文献
23.
Mahmoud Roushani Zahra Saedi Fatemeh Hamdi Hamid Reza Rajabi 《Journal of the Iranian Chemical Society》2018,15(10):2241-2249
In this study, a new Cr(III)-imprinted polymer (Cr(III)-IIP) is prepared from CrCl3·6H2O, methacrylic acid functional monomer, ethyleneglycoldimethacrylate cross-linking agent, 2,2?-azobisisobutyronitrile radical initiator and 2,2-(azanediylbis (ethane-2,1-diyl))bis(isoindoline-1,3-dione) ligand. To obtain the maximum adsorption capacity, the optimum condition was studied through pH, type and concentration of eluent, IIP weight, sample volume as well as the adsorption and desorption times. The Cr(III) ion content was determined via flame atomic absorption spectrometer. In optimum conditions, the adsorption capacity of the IIP for Cr(III) was obtained to be 74.65 mg g?1, using 50 mg of IIP and the initial pH solution of 3.0. Both the adsorption and desorption times for quantitative analyses of Cr(III) ions were 15 and 5 min; respectively. After elution of the adsorbed ions by 3 mL of 4 mol L?1 HNO3 aqueous solution, the established IIP-based SPE procedure provides a reasonable pre-concentration factor of 100. The IIP-based pre-concentration method provides a low detection limit of 1.7 µg L?1 with good repeatability (RSD?=?3.22%). Reusability studies confirmed that synthesis IIP is reusable and recoverable up to six cycles. According to the selectivity experiments, it was concluded that the prepared sorbent possesses more affinity toward Cr(III) ions than other ions such as Al3+, Pb2+, Cu2+, Mn2+, Fe2+, Zn2+, and Ni2+ ions. To evaluate the potential applicability of the proposed separation method, the pre-concentration and determination of trace amounts of Cr(III) were performed successfully in food samples with complex matrices, a bestial sample (i.e. cow liver) and an herbal product (i.e., broccoli) as real samples. 相似文献
24.
Ahmad S. Shawali Abdou O. Abdelhamid Hamdi M. Hassaneen Abdelfattah Shetta 《Journal of heterocyclic chemistry》1982,19(1):73-75
Diazotized anthranilic acid and its methyl ester react with substituted phenacyl thiocyanates 3 to give in both cases the corresponding thiadiazolo[2,3-b]quinazolines 7a-e . A mechanism is proposed and it is substantiated by alternate synthesis of 7a from the hydrazidoyl chlorides 9a,b and potassium thiocyanate. 相似文献
25.
This Note deals with the boundary null-controllability of linear diffusion–reaction equations in a 2D bounded domain. We transform the determination of the sought HUM boundary control into the minimization of a continuous and strictly convex functional. In the case of a rectangular domain where the diffusion tensor is represented by a diagonal matrix, we establish a procedure based on the inner product method that uses a complete orthonormal family of Sturm–Liouville's eigenfunctions to express explicitly the sought control. 相似文献
26.
M. Hamdi R. Bennes D. Schuhmann P. Vanel 《Journal of Electroanalytical Chemistry》1980,108(2):255-270
The influence of the nature of the anion on the adsorption of the tetrabutylammonium cation from halide solutions at a mercury—solution interface has been studied. A series of measurements of the interfacial tension for such solutions also containing a non-adsorbable cation, have led to the evaluation of the adsorption of both the tetraalkylammonium cation and of the halide anion. The variation of global surface excesses of entropy and concentration with temperature have also been determined. The results obtained can be explained by the formation, at the surface of the electrode, of both paired and non-paired ions, the latter neutralizing the charge on the electrode. The role of hydrophobic forces whose importance has been recognized in the adsorption of neutral substances is stressed in the case of surfaceactive cations. 相似文献
27.
The problem addressed in this paper is the verification of numerical solutions of nonlinear dispersive wave equations such as Boussinesq-like system of equations. A practical verification tool for numerical results is to compare the numerical solution to an exact solution if available. In this work, we derive some exact solitary wave solutions and several invariants of motion for a wide range of Boussinesq-like equations using Maple software. The exact solitary wave solutions can be used to specify initial data for the incident waves in the Boussinesq numerical model and for the verification of the associated computed solution. The invariants of motions can be used as verification tools for the conservation properties of the numerical model. 相似文献
28.
Patrick Jenny Hamdi A. Tchelepi Seong H. Lee 《Journal of computational physics》2009,228(20):7497-7512
This paper addresses the convergence properties of implicit numerical solution algorithms for nonlinear hyperbolic transport problems. It is shown that the Newton–Raphson (NR) method converges for any time step size, if the flux function is convex, concave, or linear, which is, in general, the case for CFD problems. In some problems, e.g., multiphase flow in porous media, the nonlinear flux function is S-shaped (not uniformly convex or concave); as a result, a standard NR iteration can diverge for large time steps, even if an implicit discretization scheme is used to solve the nonlinear system of equations. In practice, when such convergence difficulties are encountered, the current time step is cut, previous iterations are discarded, a smaller time step size is tried, and the NR process is repeated. The criteria for time step cutting and selection are usually based on heuristics that limit the allowable change in the solution over a time step and/or NR iteration. Here, we propose a simple modification to the NR iteration scheme for conservation laws with S-shaped flux functions that converges for any time step size. The new scheme allows one to choose the time step size based on accuracy consideration only without worrying about the convergence behavior of the nonlinear solver. The proposed method can be implemented in an existing simulator, e.g., for CO2 sequestration or reservoir flow modeling, quite easily. The numerical analysis is confirmed with simulation studies using various test cases of nonlinear multiphase transport in porous media. The analysis and numerical experiments demonstrate that the modified scheme allows for the use of arbitrarily large time steps for this class of problems. 相似文献
29.
J. Gummel Y. Corvis J. Jestin J. M’Hamdi L. Barré 《The European physical journal. Special topics》2009,167(1):171-176
Presence of suspended particles such as asphaltene in crude oils
could significantly affect the production by means of deposition in porous
media especially near the well bore. We investigate this phenomenon using
the ability of Small Angle Neutron Scattering technique to probe directly
the asphaltene adsorption process in a porous medium at the nanometer length
scale under flow conditions. A device based on a quartz tube filled with SiC
particles constitute the porous medium in which an asphaltene solution in a
mixture of good (toluene)/bad (heptane) solvent is injected under
controlled flow. The contrast matching technique enables to match the porous
medium scattering contributions and to measure the signal of the deposit.
Such a device can be used for curves surface measurements on a setup
originally designed for bulk studies and permit thus the direct comparison
with measurements on flat surfaces (neutron reflectivity) and indirect
adsorption measurements (adsorption isotherm). We show here that asphaltene
in good solvent leads to a monolayer whereas addition of bad solvent results
in a multilayer growth which is consistent with the deposition behaviour
described in the literature. 相似文献
30.
Density functional calculations on XYYX and X2YY isomers of the X2Y2 species (X: H, Li, Na, F, Cl, Br, I; Y: O, S, Se, Te) show that the XYYX isomers are more stable than the X2YY forms except for X = F and Y = S and Te, for which the F2SS and F2TeTe isomers are slightly more stable. 相似文献