Compressive sensing for ultra‐wideband channel estimation: on the sparsity assumption of ultra‐wideband channels

Due to the sparse structure of ultra‐wideband (UWB) multipath channels, there has been a considerable amount of interest in applying the compressive sensing (CS) theory to UWB channel estimation. The main consideration of the related studies is to propose different implementations of the CS theory for the estimation of UWB channels, which are assumed to be sparse. In this study, we investigate the suitability of standardized UWB channel models to be used with the CS theory. In other words, we question the sparsity assumption of realistic UWB multipath channels. For that, we particularly investigate the effects of IEEE 802.15.4a UWB channel models and the selection of channel resolution both on channel estimation and system performances from a practical implementation point of view. In addition, we compare the channel estimation performance with the Cramer‐Rao lower bound for various channel models and number of measurements. The study shows that although UWB channel models for residential environments (e.g., channel models CM1 and CM2) exhibit a sparse structure yielding a reasonable channel estimation performance, channel models for industrial environments (e.g., CM8) may not be treated as having a sparse structure due to multipaths arriving densely. Furthermore, it is shown that the sparsity increased by channel resolution can improve the channel estimation performance significantly at the expense of increased receiver processing. Copyright © 2013 John Wiley & Sons, Ltd.     

Histopathological evaluation of the effect of intranasal phototherapy on nasal mucosa in rabbits

Allergic rhinitis is a high-incidence allergic inflammation of the nasal airways that impacts quality of life. Of the numerous therapies used to treat allergic rhinitis, intranasal phototherapy has emerged as a promising new treatment modality for inflammatory airway disease. Phototherapy is widely used for the treatment of immune-mediated skin diseases because its profound immunosuppressive effect inhibits hypersensitivity reactions in the skin. Intranasal phototherapy using a combination of Ultraviolet-A (UVA) and Ultraviolet-B (UVB) plus Visible light (VIS) has been shown to suppress the clinical symptoms of allergic rhinitis, but limited data regarding its adverse effects on the nasal mucosa currently exists. In this study, we demonstrate that UV displays no harmful effects on the nasal mucosa cells of rabbits following 2 weeks of intranasal phototherapy.     

Market segmentation strategy in internet market

This paper presents a model to describe the competitive dynamics of web sites on the WWW market and analyze the stability of the model which is composed of one powerful site and two small sites. One of the most important results that emerge from this simple model is that strong competition among websites does not necessarily lead to the demise of the small website on the WWW market. From the stability analysis of the model, we obtain a series of conditions in which small sites can obtain competitive advantages by using the market segmentation strategy.     

基于耦合算法的三维复杂结构冲击动力学特性

光滑粒子流体动力学-有限元耦合算法（SPH-FEM）较好地结合了SPH和FEM的优势,近年来逐渐被引入冲击动力学相关问题研究中。然而早期的研究对象多为单一材料的简单结构,所取得的研究成果距离实际工程应用仍有一定差距。为此,在总结前人工作的基础上,对SPH-FEM耦合算法进行适当改进,通过引入复合材料损伤模型,对复合材料蒙皮结构飞行器舱段结构进行建模计算,分析其在爆炸冲击激励下的冲击动力学特性。将数值计算结果与试验结果进行对比分析,验证该算法和模型的有效性和准确性,初步实现SPH-FEM的工程实际应用。最后总结了复合材料蒙皮结构飞行器在爆炸冲击激励下的一系列结构动态响应规律,以期为航天飞行器结构设计与防护提供参考。     

Sulfone-Embedded Heterocyclic Narrowband Emitters with Strengthened Molecular Rigidity and Suppressed High-Frequency Vibronic Coupling

Sulfone-embedded heterocyclics are of great interest in organic light-emitting diodes (OLEDs), however, exploring highly efficient narrowband emitters based on sulfone-embedded heterocyclics remains challenging. Herein, five emitters with different sulfur valence state and molecular rigidity, namely tP, tCPD, 2tCPD, tPD and tPT, are thoroughly analysed. With restricted twisting of flexible peripheral phenyl by strengthening molecular rigidity, molecular emission spectra can be enormously narrowed. Further, introducing the sulfone group with bending vibration in low-frequency region that suppresses high-frequency vibration, sharp narrow full-widths at half-maximum of 28 and 25 nm are achieved for 2tCPD and tPD, respectively. Maximum external quantum efficiencies of 22.0 % and 27.1 % are successfully realized for 2tCPD- and tPD-based OLED devices. These results offer a novel design strategy for constructing narrowband emitters by introducing sulfone group into a rigid molecular framework.     

Single-Atom Catalysts for H2O2 Electrosynthesis via Two-Electron Oxygen Reduction Reaction

Oxygen reduction reaction via the two-electron route (2e⁻ ORR) provides a green method for the direct production of hydrogen peroxide (H₂O₂) along with in situ utilization. The effective catalysts with high ORR activity, 2e⁻ selectivity, and stability are essential for the application of this technology. Single-atom catalysts (SACs) have attracted intensively attention for H₂O₂ electrosynthesis owing to the unique geometric and electronic configurations. In this review, the mechanism and theoretical predictions for 2e⁻ ORR over SACs are first introduced. Then, the recent advances of various SACs for the electrosynthesis of H₂O₂ are documented. And the correlation between the central atom, coordination atoms, and coordination environment of SACs and the corresponding electrocatalytic ORR performance including activity, selectivity, and stability are emphatically analyzed and summarized. Finally, the major challenges and opportunities regarding the future design of SACs for the H₂O₂ production are pointed out.     

Ni Single Atoms on Hollow Nanosheet Assembled Carbon Flowers Optimizing Polysulfides Conversion for Li−S Batteries

The sluggish conversion kinetics and shuttling behavior of lithium polysulfides (LiPSs) seriously deteriorate the practical application of lithium–sulfur (Li–S) batteries. Herein, Ni single atoms on hollow carbon nanosheet-assembled flowers (Ni-NC) are synthesized via a facile pyrolysis-adsorption process to address these challenges. The as-designed Ni-NC with enhanced mesoporosity and accessible surface area can expose more catalytic sites and facilitate electron/ion transfer. These advantages enable the Ni-NC-modified separator to exhibit both enhanced confinement-catalysis ability and suppressed shuttling of LiPSs. Consequently, the Li−S battery with Ni-NC-modified separator shows an initial capacity of 1167 mAh g⁻¹ with a low capacity decay ratio (0.033% per cycle) over 700 cycles at 1 C. Even at the sulfur loading of 6.17 mg cm⁻², a high areal capacity of 5.17 mAh cm⁻² is realized at 0.1 C, together with superior cycling stability over 300 cycles. This work provides a facile catalyst design strategy for the development of high-performance Li−S batteries.