Convergence rates for decentralized consistent location parameter estimation in the presence of Gaussian outliers

We consider a distributed system where sensors make location parameter estimates using their observations. A central processor collects the local estimates and declares a final estimate based on them. We present a simple study of the convergence properties of three structures where empirical mean and M-estimates are used in various combinations. It is shown that when occasional outliers exist, decentralized estimators that provide robustness at stages where data corruption occurs perform superiorly.     

两种高Tg非线性光学聚合物母体及掺杂,极化的研究

利用具有非线性光学活性的对硝基苯胺掺杂高玻璃化转变温度的聚芳醚砜(PES-C)和聚芳醚酮(PEK-C),得到了两种掺杂含量较高的掺杂型非线性光学聚合物体系。电晕极化表明较高的取向和较慢的松驰。     

Kinetics and Mechanism of the oxygenation of triphenylphosphine by bis(ethyl-L-cysteinato)dioxomolybdenum(VI)

Summary The kinetics of oxygen-transfer from [MoO₂(Et-L-cys)₂] to PPh₃ and the reaction between [Mo₂O₃(Et-L-cys)₄] and O₂ in benzene solution have been investigated using spectrophotometric techniques between 25 and 40°. The rate laws-d[Mo⁶⁺]/dt = k₁[Mo⁶⁺][PPh₃] with k₁ (at 35°) = 2.95×10^–4dm³mol^–1s^–1 and -d[Mo⁵⁺]/dt = 2k₃[Mo⁵⁺][O₂] with k₃ (at 35°) = 6.3×10^–2 dm³mol^–1s^–1 account for the kinetic data obtained with activation parameters (at 35°) of H = 46 kJ mol^–1, S = –153 JK^–1mol^–1, and H = 50.8 kJ mol^–1, S = –95 JK^–1 mol^–1 respectively.     

二阶非线性光学极化聚合物

本文综述了二阶非线性光学极化聚合物材料研究概况，包括器件对材料的要求、材料的研究进展及目前存在的问题。     

Synthesis and characterization of copper(II), nickel(II) and cobalt(II) complexes with novel thiourea derivatives

A novel series of thiourea derivatives, namely, N,N-diphenyl-N-(4-phenyl-benzoyl)thiourea (HL¹), N,N-diphenyl-N-(4-chloro-benzoyl)thiourea (HL²) and N,N-di-n-propyl-N-(4-chloro-benzoyl)thiourea (HL³), and its metal complexes has been prepared and characterised by elemental analysis, i.r. spectroscopy, ¹H-n.m.r. spectroscopy, mass spectrometry and single crystal X-ray diffraction. The ligand coordinates to Ni^II, Cu^II and Co^II in a bidentate manner yielding essentially neutral complexes of the type cis-[ML₂]. N.m.r. spectra and single crystal X-ray diffraction analysis revealed the presence of a distorted tetrahedral coordination ML₂ complex.     

(E/Z)‐Isomerization of 3′‐Epilutein

3′‐Epilutein (=(all‐E,3R,3′S,6′R)‐4′,5′‐didehydro‐5′,6′‐dihydro‐β,β‐carotene‐3,3′‐diol; 1 ), isolated from the flowers of Caltha palustris, was submitted to both thermal isomerization and I₂‐catalyzed photoisomerization. The structures of the main products (9Z)‐ 1 , (9′Z)‐ 1 , (13Z)‐ 1 , (13′Z)‐ 1 , (15Z)‐ 1 , and (9Z,9′Z)‐ 1 were determined based on UV/VIS, CD, ¹H‐NMR, and MS data.     

Synthesis of some new benzimidazole-5(6)-carboxylic acids

The title compounds, 1,2-dialkyl-benzimidazole-5(6)-carboxylic acids 34–45 were prepared at four steps; 1) preparation of mono amide derivatives 1–11 by the reaction of methyl 3,4-diaminobenzoate and substituted phenyl or phenoxyacetic acid chlorides; 2) preparation of the methyl benzimidazolecarboxyl-ates 12–22 , with zinc chloride and dry hydrogen chloride gas; 3) alkaline hydrolysis of the esters 23–33 ; and 4) substitution of the imidazole ring with benzyl or p-fluorobenzyl bromide, in alkali medium. 2-Aryl-benzimidazole-5(6)-carboxylic acids 50–53 were prepared via the oxidative condensation of 3,4-diaminobenzoic acid and aromatic aldehydes with cupric ion.     

Complete convergence and almost sure convergence of weighted sums of random variables

Letr>1. For eachn1, let {X _nk , –<k<} be a sequence of independent real random variables. We provide some very relaxed conditions which will guarantee for every >0. This result is used to establish some results on complete convergence for weighted sums of independent random variables. The main idea is that we devise an effetive way of combining a certain maximal inequality of Hoffmann-Jørgensen and rates of convergence in the Weak Law of Large Numbers to establish results on complete convergence of weighted sums of independent random variables. New results as well as simple new proofs of known ones illustrate the usefulness of our method in this context. We show further that this approach can be used in the study of almost sure convergence for weighted sums of independent random variables. Convergence rates in the almost sure convergence of some summability methods ofiid random variables are also established.     

TMS320C6000系列DSP PCI接口模块WDM驱动开发及高速数据传输方法

针对基于TMS320C6000系列DSP芯片内集成的PCI接口模块设计的PCI接收机数据采集卡,根据高速数据传输要求,设计并开发了NT/2000操作系统下的WDM驱动程序及应用程序。在中频数字接收系统中的应用验证了此软件系统的效率和可靠性。