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271.
We have performed molecular dynamics method to investigate the conformational stability of the homotetramer form of HexCoil-Ala (PDB Code 3S0R). The previous experiments showed that the chains tend to form tetramer structures. The system was simulated in explicit water model at several temperatures by using isobaric-isothermal ensemble to better understand the behaviour of each monomer and its tetramer form. It was observed that central residues of each monomer have highly helical percentages in comparison with the termini residues. As the temperature increased, these percentages decreased, and bend-like configurations came into being due to the fact that the C-and N-terminals of the monomer were getting closer. When free energy landscapes of HexCoil-Ala were calculated by using the distance between Leu-Zipper and Ala-Coil interface, it was seen that the assemblies of monomers were very strong. What's more, the average values obtained from them were very close to the native case between 300?K and 350?K. It was also observed that the direct salt bridge forming between the residues E8 with R25 in the other chains plays a significant role for keeping tetramer structure. Consequently, our results are in better agreement with the results of experimental observations. 相似文献
272.
Effects of inclination angle on natural convection heat transfer and fluid flow in a two-dimensional enclosure filled with Cu-nanofluid has been analyzed numerically. The performance of nanofluids is tested inside an enclosure by taking into account the solid particle dispersion. The angle of inclination is used as a control parameter for flow and heat transfer. It was varied from = 0° to = 120°. The governing equations are solved with finite-volume technique for the range of Rayleigh numbers as 103 Ra 105. It is found that the effect of nanoparticles concentration on Nusselt number is more pronounced at low volume fraction than at high volume fraction. Inclination angle can be a control parameter for nanofluid filled enclosure. Percentage of heat transfer enhancement using nanoparticles decreases for higher Rayleigh numbers. 相似文献
273.
274.
Miraç Ocak Tuğba Ak Ayşe Aktaş Nurhayat Özbek Osman Can Çağılcı Abidin Gümrükçüoğlu Halit Kantekin Ümmühan Ocak Hakan Alp 《Journal of fluorescence》2017,27(1):59-68
Four new Schiff base ligands carrying naphthalene groups were prepared from the reaction of 2,4-diamino-6-methyl-1,3,5-triazine and 2,4-diamino-6-undecyl-1,3,5-triazine with 2-hydroxy-1-naphthaldehyde. The influence of a series of metal ions including Cu2+, Co2+, Hg2+, Al3+, Cr3+, Fe3+, Pb2+, Ni2+, Cd2+, Zn2+, Mn2+, Ag+, Ba2+, Ca2+ and Mg2+ on the spectroscopic properties of the ligands was investigated by means of absorption and emission spectrometry. The results of spectrophotometric and spectrofluorimetric titrations disclosed the complexation stoichiometry and complex stability constant of the ligands with metal ions. A simple spectrofluorimetric method was developed using the Schiff base derived from 2,4-diamino-6-undecyl-1,3,5-triazine to determine Hg2+ ion. No cleanup or enrichment of the tap water sample was required. A modified standard addition method was used to eliminate matrix effect. The standard addition graph was linear between 0.2 and 2.6 mg/L in determination of Hg2+. Detection and quantification limits were 0.08 and 0.23 mg/L, respectively. The simple and cost-effective method can be applied to water samples. 相似文献
275.
Fält S Atatüre M Türeci HE Zhao Y Badolato A Imamoglu A 《Physical review letters》2008,100(10):106401
We have investigated few-body states in vertically stacked quantum dots. Because of a small interdot tunneling rate, the coupling in our system is in a previously unexplored regime where electron-hole exchange plays a prominent role. By tuning the gate bias, we are able to turn this coupling off and study a complementary regime where total electron spin is a good quantum number. The use of differential transmission allows us to obtain unambiguous signatures of the interplay between electron and hole-spin interactions. Small tunnel coupling also enables us to demonstrate all-optical charge sensing, where a conditional exciton energy shift in one dot identifies the charging state of the coupled partner. 相似文献
276.
Xuan Hoang Khoa Le Hakan F. Oztop Fatih Selimefendigil Mikhail A. Sheremet 《Entropy (Basel, Switzerland)》2022,24(4)
Heat transport augmentation in closed chambers can be achieved using nanofluids and extended heat transfer surfaces. This research is devoted to the computational analysis of natural convection energy transport and entropy emission within a closed region, with isothermal vertical borders and a heat-conducting solid fin placed on the hot border. Horizontal walls were assumed to be adiabatic. Control relations written using non-primitive variables with experimentally based correlations for nanofluid properties were computed by the finite difference technique. The impacts of the fin size, fin position, and nanoadditive concentration on energy transfer performance and entropy production were studied. It was found that location of the long fin near the bottom wall allowed for the intensification of convective heat transfer within the chamber. Moreover, this position was characterized by high entropy generation. Therefore, the minimization of the entropy generation can define the optimal location of the heat-conducting fin using the obtained results. An addition of nanoparticles reduced the heat transfer strength and minimized the entropy generation. 相似文献
277.
We investigate the effect of the literature suggested optimal values of the parameters of a dynamic decision‐making heuristic in the presence of semirationally managed supply chain echelons using a soft coded one‐to‐one version of The Beer Game as an experimental platform. According to the counterintuitive results obtained in this study, it is possible for a “rational manager” to obtain higher costs than the costs generated by a “semirational manager.” Thus, the results do not support the use of the well‐established decision parameter values for the echelon of concern if the other echelons' inventories are managed suboptimally. © 2015 Wiley Periodicals, Inc. Complexity 21: 190–199, 2016 相似文献
278.
279.
Erhan Demirel Hakan Durmaz Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2016,54(4):480-486
The aliphatic polyurethane with pendant alkyne, perfluorophenyl, and anthracene moieties (PU‐anthracene) was prepared from polycondensation of anthracene, alkyne, and perfluorophenyl functional‐diols with hexamethylenediisocyanate in the presence of dibutyltindilaurate (DBTL) in CH2Cl2 at room temperature for 10 days. Thereafter, the PU‐(anthracene‐co‐alkyne‐co‐perfluorophenyl) (Mn,GPC = 15,400 g/mol, Mw/Mn= 1.37, relative to PS standards) was sequentially clicked with benzyl azide, octylamine, and 4‐(2‐hydroxyethyl)?10‐oxa‐4‐azatricyclo[5.2.1.02,6]dec‐8‐ene‐3,5‐dione (adduct alcohol) via copper‐catalyzed azide‐alkyne cycloaddition, active ester substitution and Diels–Alder reactions, respectively, to finally yield PU‐(hydroxyl‐co‐benzyltriazole‐co‐octylamine). The PUs were characterized using 1H NMR, GPC, and DSC. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 480–486 相似文献
280.
We describe our studies on the synthesis of carotenoid glucosides and deoxyglucosides using the acetimidate method and the Ferrier rearrangement, respectively. In both cases the reaction conditions were optimized until the yields were superior to those of previously published glycosylations. 相似文献