Organic Cation‐Dependent Degradation Mechanism of Organotin Halide Perovskites

The applications of organotin halide perovskites are limited because of their chemical instability under ambient conditions. Upon air exposure, Sn²⁺ can be rapidly oxidized to Sn⁴⁺, causing a large variation in the electronic properties. Here, the role of organic cations in degradation is investigated by comparing methylammonium tin iodide (MASnI₃) and formamidinium tin iodide (FASnI₃). Through chemical analyses and theoretical calculations, it is found that the organic cation strongly influences the oxidation of Sn²⁺ and the binding of H₂O molecules to the perovskite lattice. On the one hand, Sn²⁺ can be easily oxidized to Sn⁴⁺ in MASnI₃, and replacing MA with FA reduces the extent of Sn oxidation; on the other hand, FA forms a stronger hydrogen bond with H₂O than does MA, leading to partial expansion of the perovskite network. The two processes compete in determining the material's conductivity. It is noted that the oxidation is a difficult process to prevent, while the water effect can be largely suppressed by reducing the moisture level. As a result, FASnI₃‐based conductors and photovoltaic cells exhibit much better reproducibility as compared to MASnI₃‐based devices. This study sheds light on the development of stable Pb‐free perovskite optoelectronic devices through new material design.     

Progressive Linear Precoder Optimization for MIMO Packet Retransmissions Exploiting Channel Covariance Information

This work investigates the design of linear precoders for ARQ packet retransmissions in multi-input multi-output (MIMO) systems. We consider transmitter precoder design based on partial MIMO channel information in the form of their covariance feedback. Our objective is to maximize the ergodic mutual information provided by multiple (re)transmissions of a packet subject to transmission power constraint. We propose a set of near-optimal successive linear ARQ precoders for flat fading MIMO channels. This progressive linear ARQ precoder combines the appropriate power loading and the reverse-order pairing of singular values in the current retransmission with previous transmissions. This reverse-order pairing is a special feature unique to our sequential ARQ preceding approach with demonstrated performance gains.     

基于Kohonen网络的入侵检测方法

本文在自动聚类分析的基础上,根据入侵检测系统收到的网络数据包中的特征数据, 采用Kohonen神经网络方法,确定该数据的状态,判断结果与该数据的真实模式是否相一致。该方 法能实现对入侵检测系统中用户行为的模式识别,而且准确率高。     

NYAB晶体Cr~(4 ):YAG被动调Q的激光特性研究

采用氙灯泵浦,Ｃｒ４＋ＹＡＧ被动调Ｑ,实现了自倍频晶体ＮＹＡＢ调Ｑ激光运转,测量了Ｃｒ４＋ＹＡＧ不同小信号透过率及不同泵浦能量下绿激光单脉冲的输出能量、脉冲宽度、重复率,给出了描述ＮＹＡＢ晶体Ｃｒ４＋ＹＡＧ调Ｑ工作原理的耦合波方程组,数值求解该方程组所得的理论结果与实验值相符。     

QoS Performance Bounds and Efficient Connection Admission Control for Heterogeneous Services in Wireless Cellular Networks

Quality-of-Service (QoS) performance and connection admission control (CAC) for heterogeneous services in wireless multiple access networks are investigated. The heterogeneous services include constant bit rate (CBR), variable bit rate (VBR) and available bit rate (ABR) services. Multiple access control is handled by a polling-based scheme with non-preemptive priority. Tight delay variation (jitter) bounds for CBR connections and delay bounds for VBR connections are derived. A CAC scheme based on the derived bounds is developed. The CAC makes use of user mobility information to reserve an appropriate amount of system resources for potential handoff connections to achieve low handoff connection dropping rate (HCDR). Simulation results show that the proposed CAC scheme can achieve both low HCDR and high resource utilization.     

一氧化氮退火对高温氧化SiC/SiO2界面特性的影响研究

本文研究了高温（1300℃）氧化并在一氧化氮（NO）气体中进行氧化后退火方法对4H-SiC 金属-氧化物-半导体（MOS）电容的SiC/SiO2界面特性的影响,主要通过SiC MOS的电容-电压(C-V)特性详细讨论了NO退火时间和温度与SiO2/SiC界面特性的相互关系. 结果表明在NO气体中进行氧化后退火可明显降低界面态密度,并且界面态密度随着温度和时间的增加会进一步降低。 同时,与常规1200℃及以下氧化温度相比,1300℃下热生长的氧化层具有更低的界面态密度且显著缩短了氧化时间,节约了生产成本。     

移动互联网环境下的智能管道关键技术

重点论述了移动互联网环境下智能管道的网络架构和关键技术,指出"感知、控制、开放"的智能管道能力将成为运营商网络能力提升的主要技术发展方向,感知是智能管道的基础、控制是智能管道的核心、开放是智能管道差异化服务的主要手段。     

Hierarchical NiMn Layered Double Hydroxide/Carbon Nanotubes Architecture with Superb Energy Density for Flexible Supercapacitors

A hierarchical nanostructure composed of NiMn‐layered double hydroxide (NiMn‐LDH) microcrystals grafted on carbon nanotube (CNT) backbone is constructed by an in situ growth route, which exhibits superior supercapacitive performance. The resulting composite material (NiMn‐LDH/CNT) displays a three‐dimensional architecture with tunable Ni/Mn ratio, well‐defined core‐shell configuration, and enlarged surface area. An electrochemical investigation shows that the Ni₃Mn₁‐LDH/CNT electrode is rather active, which delivers a maximum specific capacitance of 2960 F g^–1 (at 1.5 A g^–1), excellent rate capability (79.5% retention at 30 A g^–1), and cyclic stability. Moreover, an all‐solid‐state asymmetric supercapacitor (SC) with good flexibility is fabricated by using the NiMn‐LDH/CNT film and reduced graphene oxide (RGO)/CNT film as the positive and negative electrode, respectively, exhibiting a wide cell voltage of 1.7 V and largely enhanced energy density up to 88.3 Wh kg^–1 (based on the total weight of the device). By virtue of the high‐capacity of pseudocapacitive hydroxides and desirable conductivity of carbon‐based materials, the monolithic design demonstrated in this work provides a promising approach for the development of flexible energy storage systems.     

激光等离子体空间分辨XUV光谱技术

本文描述了环面镜-掠入射光栅谱仪系统获得激光等离子体空间分辨XUV光谱的原理,系统结构参数和实验结果,并讨论了这种环面镜技术和交叉狭缝技术各自的优缺点。     

基于RoboCup3D仿真平台的双足机器人大脚球进攻策略设计

RoboCup3D仿真系统融合了人工智能、传感器、通信、智能控制等多门学科的相关技术.针对RoboCup3D仿真中双足机器人的踢球动作设计问题(如:踢球力度弱、摔倒等)提出了一种基于大脚球的进攻策略.采用大脚球的进攻策略可以有效的促使足球快速的踢进对方半场后方,在仿真比赛中极具攻击性.仿真结果验证了它的有效性和实用性.