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51.
An efficient palladium-catalyzed AAA reaction with a simple α-sulfonyl carbon anion as nucleophiles is presented for the first time. Allyl fluorides are used as superior precursors for the generation of π-allyl complexes that upon ionization liberate fluoride anions for activation of silylated nucleophiles. With the unique bidentate diamidophosphite ligand ligated palladium as catalyst, the in situ generated α-sulfonyl carbon anion was quickly captured by the allylic intermediates, affording a series of chiral homo-allylic sulfones with high efficiency and selectivity. This work provides a mild in situ desilylation strategy to reveal nucleophilic carbon centers that could be used to overcome the pKa limitation of “hard” nucleophiles in enantioselective transformations.A variety of “hard” α-sulfonyl carbanions of aryl, heteroaryl and alkyl sulfones were successfully employed as nucleophiles in palladium-catalyzed asymmetric allylic alkylation with excellent enantioselectivities. 相似文献
52.
The crosstalk and coupling of the external fields on orthogonal microstrip transmission lines in different layers have significant
effects on signal quality in MMIC and PCBs. In this paper the crosstalk is analyzed in detail using both full-wave and quasi-static
methods. The used full wave method is mixed potential integral equation method of moment (MPIEMoM). Because of the weak coupling between lines, the effect of the incident plane-wave is studied by applying transmission
line theory in a scattered voltage formulation uses quasi-TEM propagation model for each interconnection and the exact distribution
of the incident electric field within the layers. Afterward, by using the predetermined lumped circuit model of the cross-region,
the effect of coupling between two lines is calculated and then applied to terminal voltages in 1–20 GHz frequency range which
results in the final terminal voltages. 相似文献
53.
In this paper we introduce the concept of a weak solution for second order differential inclusions of the form u″(t) ∈ Au(t) + f(t), where A is a maximal monotone operator in a Hilbert space H. We prove existence and uniqueness of weak solutions to two point boundary value problems associated with such kind of equations. Furthermore, existence of (strong and weak) solutions to the equation above which are bounded on the positive half axis is proved under the optimal condition tf(t) ∈ L 1(0, ∞; H), thus solving a long-standing open problem (for details, see our comments in Section 3 of the paper). Our treatment regarding weak solutions is similar to the corresponding theory related to the first order differential inclusions of the form f(t) ∈ u′(t) + Au(t) which has already been well developed. 相似文献
54.
We propose a family of models called row–column interaction models (RCIMs) for two-way table responses. RCIMs apply some link function to a parameter (such as the cell mean) to equal a row effect plus a column effect plus an optional interaction modelled as a reduced-rank regression. What sets this work apart from others is that our framework incorporates a very wide range of statistical models, e.g., (1) log-link with Poisson counts is Goodman’s RC model, (2) identity-link with a double exponential distribution is median polish, (3) logit-link with Bernoulli responses is a Rasch model, (4) identity-link with normal errors is two-way ANOVA with one observation per cell but allowing semi-complex modelling of interactions of the form \(\mathbf{A}\mathbf{C}^T\) , (5) exponential-link with normal responses are quasi-variances. Proposed here also is a least significant difference plot augmentation of quasi-variances. Being a special case of RCIMs, quasi-variances are naturally extended from the \(M=1\) linear/additive predictor \(\eta \) case (within the exponential family) to the \(M>1\) case (vector generalized linear model families). A rank-1 Goodman’s RC model is also shown to estimate the site scores and optimums of an equal-tolerances Poisson unconstrained quadratic ordination. New functions within the VGAM R package are described with examples. Altogether, RCIMs facilitate the analysis of matrix responses of many data types, therefore are potentially useful to many areas of applied statistics. 相似文献
55.
Didik Prasetyoko Zainab Ramli Salasiah Endud Hadi Nur 《Reaction Kinetics and Catalysis Letters》2005,86(1):83-89
Summary Titanosilicalite-1 (TS-1) in combination with sulfated zirconia efficiently catalyzes the epoxidation of 1-octene with aqueous hydrogen peroxide. The presence of both octahedral zirconium and sulfate species in the catalysts enhances the epoxidation rates. 相似文献
56.
Nanomolar Determination of Methyldopa in the Presence of Large Amounts of Hydrochlorothiazide Using a Carbon Paste Electrode Modified with Graphene Oxide Nanosheets and 3‐(4′‐Amino‐3′‐hydroxy‐biphenyl‐4‐yl)‐acrylic Acid 下载免费PDF全文
A novel electrochemical sensor for sensitive detection of methyldopa at physiological pH was developed by the bulk modification of carbon paste electrode (CPE) with graphene oxide nanosheets and 3‐(4′‐amino‐3′‐hydroxy‐biphenyl‐4‐yl)‐acrylic acid (3,′AA). Applying square wave voltammetry (SWV), in phosphate buffer solution (PBS) of pH 7.0, the oxidation current increased linearly with two concentration intervals of methyldopa, one is 1.0×10?8–1.0×10?6 M and the other is 1.0×10?6–4.5×10?5 M. The detection limit (3σ) obtained by SWV was 9.0 nM. The modified electrode was successfully applied for simultaneous determination of methyldopa and hydrochlorothiazide. Finally, the proposed method was applied to the determination of methyldopa and hydrochlorothiazide in some real samples. 相似文献
57.
Mahdi Mirzaei Hossein Eshghi Mohammad Rahimizadeh Mehdi Bakavoli Maryam M. Matin Minoo Hosseinymehr Hadi Amiri Rudbari Giuseppe Bruno 《中国化学会会志》2015,62(12):1087-1096
A series of α‐aminophosphonates were synthesized through one‐pot condensation of aryl aldehydes, aryl amines and diethyl phosphite in the absence of any catalyst and organic solvents. All the synthesized α‐aminophosphonates were characterized by spectral and elemental analysis and in the case of compound 4j by X‐ray crystallography. Some of these new α‐aminophosphonate derivatives were found to have cytotoxic activity on the cancer cell line DU145 in vitro by the MTT method. 相似文献
58.
The Barzilai–Borwein (BB) gradient method has received many studies due to its simplicity and numerical efficiency. By incorporating a nonmonotone line search, Raydan (SIAM J Optim. 1997;7:26–33) has successfully extended the BB gradient method for solving general unconstrained optimization problems so that it is competitive with conjugate gradient methods. However, the numerical results reported by Raydan are poor for very ill-conditioned problems because the effect of the degree of nonmonotonicity may be noticeable. In this paper, we focus more on the nonmonotone line search technique used in the global Barzilai–Borwein (GBB) gradient method. We improve the performance of the GBB gradient method by proposing an adaptive nonmonotone line search based on the morphology of the objective function. We also prove the global convergence and the R-linear convergence rate of the proposed method under reasonable assumptions. Finally, we give some numerical experiments made on a set of unconstrained optimization test problems of the CUTEr collection. The results show the efficiency of the proposed method in the sense of the performance profile introduced (Math Program. 2002;91:201–213) by Dolan and Moré. 相似文献
59.
Hadi Minbashian Hojatolah Adibi Mehdi Dehghan 《Numerical Methods for Partial Differential Equations》2017,33(6):2062-2089
This article concerns with incorporating wavelet bases into existing streamline upwind Petrov‐Galerkin (SUPG) methods for the numerical solution of nonlinear hyperbolic conservation laws which are known to develop shock solutions. Here, we utilize an SUPG formulation using continuous Galerkin in space and discontinuous Galerkin in time. The main motivation for such a combination is that these methods have good stability properties thanks to adding diffusion in the direction of streamlines. But they are more expensive than explicit semidiscrete methods as they have to use space‐time formulations. Using wavelet bases we maintain the stability properties of SUPG methods while we reduce the cost of these methods significantly through natural adaptivity of wavelet expansions. In addition, wavelet bases have a hierarchical structure. We use this property to numerically investigate the hierarchical addition of an artificial diffusion for further stabilization in spirit of spectral diffusion. Furthermore, we add the hierarchical diffusion only in the vicinity of discontinuities using the feature of wavelet bases in detection of location of discontinuities. Also, we again use the last feature of the wavelet bases to perform a postprocessing using a denosing technique based on a minimization formulation to reduce Gibbs oscillations near discontinuities while keeping other regions intact. Finally, we show the performance of the proposed combination through some numerical examples including Burgers’, transport, and wave equations as well as systems of shallow water equations.© 2017 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 33: 2062–2089, 2017 相似文献
60.
In this paper, we address the problem of cooperation among vehicles in VANET using QoS-OLSR protocol in the presence of selfish nodes. QoS-OLSR is a proactive protocol that considers the Quality of Service (QoS) of the nodes while electing the cluster-heads and selecting the Multi-Point Relay (MPRs) nodes. Cluster-heads and MPRs might misbehave on the roads by over-speeding or under-speeding. Classical and generous Tit-for-Tats are proposed to analyze the interaction among vehicles. However, both strategies are not able to enforce the cooperation due the fact that they (1) count on individual watchdogs monitoring, (2) rely on the node-to-node cooperation decision, (3) and ignore the high mobility and packet collisions. Therefore, we propose a Dempster–Shafer based Tit-for-Tat strategy that is able to improve the decision and regulate the cooperation in the vehicular network. This is done by (1) launching a cooperative watchdogs monitoring, (2) correlating the observations of the different watchdogs using Dempster–Shafer theory, and (3) propagating the decisions among clusters. Thereafter, we compare the Dempster–Shafer based strategy with several strategies derived from the original Tit-for-Tat. Simulation results prove that the Dempster–Shafer based strategy is able to maintain the survivability of the vehicular network in the presence of high mobility and packet collisions with minimal time and overhead. 相似文献