Hydrodechlorination of chlorophenols over Pd catalysts supported on zeolite Y,MCM-41 and graphene

Hydrodechlorination (HDC) reaction of chlorophenols was carried out using Pd catalysts supported over zeolite Y, MCM-41 or graphene. Pd-MCM-41 and Pd-Y zeolite were prepared by impregnation and ion-exchange method, respectively. Pd-graphene (Pd-G) was prepared by hydrazine hydrate reduction of palladium ion dispersed on graphene oxide. The catalysts were characterized by several analytical tools such as X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDS). These catalysts were subjected to HDC reaction of chlorophenols, such as 4-chlorophenol (4-CP), 2,4-dichlorophenol (2,4-DCP), 2,6-dichlorophenol (2,6-DCP) and 3,4-dichlorophenol (3,4-DCP). The reaction rate of HDC of chlorophenols catalyzed by Pd catalysts with various solid bases, such as KF/Al₂O₃ (alumina), sodium acetate (NaOAc) and K₂CO₃ was compared. First, Pd-MCM-41 and Pd-Y catalysts were compared. 2,4- and 3,4-DCPs were completely decomposed within 6 h, in the case of Pd-MCM-41 with NaOAc. Using Pd-Y instead of Pd-MCM-41 with NaOAc, much faster decomposition was observed. Faster decomposition of 4-CP and DCPs was observed with NaOAc base than K₂CO₃ or KF/Al₂O₃ under the same condition. In the case of Pd-Y with KF/Al₂O₃, slower decomposition of 4-CP and DCPs was observed. These base effects were interpreted using the solubility of NaCl and KCl in alcohol and the basic sites of KF/Al₂O₃. Because the solubility of NaCl is known to be larger than KCl solubility in alcohol, byproduct NaCl could be easily dissolved and ionized in solvents. For Pd-Y with KF/Al₂O₃, the small pore size of Y zeolite can interfere with the diffusion of HCl to KF/Al₂O₃ basic site. Second, three catalysts, including Pd-graphene, were compared. 2,4-DCP was decomposed within 2 h using Pd-G with either K₂CO₃, NaOAc or KF/Al₂O₃. Pd-G catalyst showed the highest catalytic activity among Pd-G, Pd-MCM-41 and Pd-Y catalysts. The high activity and stability of the Pd-G could be attributed to the strong metal–support interaction with an electron-deficient site and a critical Pd particle size (ca. 3.5 nm) of Pd-G nanocatalyst with a stronger resistance to the deactivation and good affinity toward aromatic organic molecules, especially phenols. The progress of HDC reaction was monitored by gas chromatography with flame ionization detection (GC/FID), and a feasible degradation process could be explained by analyzing the degradation products such as phenol, cyclohexanone and cyclohexanol from resulting GC chromatograms. The effect of reaction temperature on HDC in Pd-G catalyst was also discussed. In conclusion, Pd-G is an efficient catalyst for decomposition of chlorophenols and can be applied to remediation of chlorophenol-contaminated water under mild conditions.     

Interfacial change on morphological transitions in styrene-isoprene diblock copolymer

The specific interfacial area (S/V) and interfacial thickness in each microstructure of styrene-isoprene diblock copolymer were estimated by analyzing the deviations from Porod’s law. The thermally induced phase transitions proceeded from lamellae (L) to hexagonally ordered cylinder (HEX), via hexagonally perforated layer (HPL) and gyroid (G). The S/V ratio increased stepwise at the order-order transition (OOT) from L to HEX, via HPL and G. The S/V data can be utilized for OOT determination.     

High-frequency SPICE model of anisotropic conductive film flip-chipinterconnections based on a genetic algorithm

This paper firstly reports on the high-frequency SPICE model of the ACF flip-chip interconnections up to 13 GHz. The extraction process is based on an optimization procedure, called a genetic algorithm, which is known as a robust optimization tool. The proposed equivalent circuit model of the ACF interconnection can readily be used in SPICE circuit simulations for signal integrity analysis of high-frequency packages. Two different ACF interconnections were studied using the Au-coated polymer ball and Ni-filled ball. The extracted models of the two ACFs were found strongly dependent on not only size and rigidity of the conducting balls, but also on their magnetic permeability     

Biological functionalization of the amine-terminated Si(100) surface by glycine

A peptide reaction of glycine on an amine-terminated Si(100) surface was investigated using C 1s, N 1s, O 1s, and Si 2p core-level spectroscopy, where the amine-terminated Si(100) surface was prepared using NH₃. In-situ thermal treatments at a mild temperature of 50 °C after the adsorption of glycine on a room-temperature amine-terminated Si(100) surface induced the peptide reaction between the carboxyl group of glycine and the amine group of the surface. This suggests that the amine-terminated Si(100) surface can be an excellent template for constructing a junction between a biomaterial and a Si surface using a dry process.     

Full software analysis and impedance matching of radio frequencyCMOS integrated circuits

We present a systematic analysis technique of complementary metal-oxide-semiconductor (CMOS) radio-frequency (RF) integrated circuits (ICs). A full simulation program with integrated circuit emphasis (SPICE) simulation of the whole chip including the package and the die, with the parameters extracted from purely software analysis, has been performed. It is shown that the RF impedance matching without S-parameter based techniques is possible and the measured results agree well with our SPICE-only software based technique     

Adhesion comparison of human bone marrow stem cells on a gradient wettable surface prepared by corona treatment

Corona discharge treatment was applied to modify the surface of polyethylene (PE). The wettability of PE surface was gradually increased by power increase of a corona treatment along the PE length, indicating that the hydrophilicity of PE surface increased gradually. The adhesion and proliferation behavior of human bone marrow stem cells (hBMSCs) on the gradient PE surface was evaluated. We found that hBMSCs were adhered to and proliferated on better highly hydrophilic than hydrophobic surfaces. The plot of proliferation rate vs. the water contact angles was parabolic. These results indicate that surface wettability plays an important role in the cell attachment and proliferation.     

Fabrication of quantum dot transistors incorporating a single self-assembled quantum dot

We report on the fabrication and the characterization of quantum dot transistors incorporating a single self-assembled quantum dot. The current–voltage characteristics exhibit clear staircase structures at room temperature. They are attributed to electron tunneling through the quantized energy levels of a single quantum dot.     

A novel hybrid silica wide-band amplifier covering S+C+L bands with 105-nm bandwidth

We report a novel hybrid optical amplifier covering S+C+L bands with 105-nm total bandwidth using a silica fiber. The principle of amplification is based on the stimulated radiative transition of Er-ions for C-band and on the stimulated Raman scattering for S- and L-band, respectively. In this letter, we analyze the amplification characteristics for two types of active fiber mediums through numerical simulation. One is a silica fiber configured with Er-doped cladding and Ge-doped core and the other is a medium consisting of Er-doped fiber and dispersion-compensating fiber. By optimizing parameters such as fiber length and pump power, we newly achieve wide-band amplification with 105-nm bandwidth showing a flat gain characteristic over the entire S+C+L bands.     

An Efficient Rerouting Scheme for MPLS-Based Recovery and Its Performance Evaluation

The path recovery in MPLS is the technique to reroute traffic around a failure or congestion in a LSP. Currently, there are two kinds of model for path recovery: rerouting and protection switching. The existing schemes based on rerouting model have the disadvantage of more difficulty in handling node failures or concurrent node faults. Similarly, the existing schemes based on protection switching model have some difficulty in solving problem such as resource utilization and protection of recovery path. This paper proposes an efficient rerouting scheme to establish a LSP along the least-cost recovery path of all possible alternative paths that can be found on a working path, which is calculated by the upstream LSR that has detected a failure. The proposed scheme can increase resource utilization, establish a recovery path relatively fast, support almost all failure types such as link failures, node failures, failures on both a working path and its recovery path, and concurrent faults. Through simulation, the performance of the proposed scheme is measured and compared with the existing schemes.     

Performance of Hybrid Laser Diodes Consisting of Silicon Slab and InP/InGaAsP Deep‐Ridge Waveguides

The fundamental transverse mode lasing of a hybrid laser diode is a prerequisite for efficient coupling to a single‐mode silicon waveguide, which is necessary for a wavelength‐division multiplexing silicon interconnection. We investigate the lasing mode profile for a hybrid laser diode consisting of silicon slab and InP/InGaAsP deep ridge waveguides. When the thickness of the top silicon is 220 nm, the fundamental transverse mode is lasing in spite of the wide waveguide width of 3.7µm. The threshold current is 40 mA, and the maximum output power is 5 mW under CW current operation. In the case of a thick top silicon layer (1 µm), the higher modes are lasing. There is no significant difference in the thermal resistance of the two devices.