一种防闩锁的多嵌入阱SCR ESD器件

针对高压BCD工艺使用SCR器件ESD保护时面临的高触发电压与低维持电压之间的矛盾,设计了一种多嵌入阱可控硅(MEWSCR)结构。相比于常规SCR结构,首先,通过移动阳极/阴极的N+/P+掺杂区引入辅助泄放器件,MEWSCR结构实现了二次触发,增加了维持电压;其次,通过在阳极P+区和阴极N+区下方分别嵌入N浅阱和P浅阱,增强非平衡载流子的SRH复合作用,降低SCR的再生反馈效应,提高了维持电流。基于0.18 μm BCD工艺,采用TCAD软件进行模拟。结果表明,新型MEWSCR器件的维持电压提升至23 V,维持电流提升1 A以上,满足ESD设计窗口要求。     

基于Pandora 观测的OMI 全球臭氧产品精度验证

臭氧是大气中一种重要的微量气体, 是影响对流层与平流层大气运动的重要成分之一, 臭氧的高精度探测 对于环境和气候具有重要的意义。OMI 传感器是目前具备探测全球臭氧含量的主要遥感传感器之一。利用地基 Pandora 观测网全球范围内44 个臭氧观测站点数据对OMI 卫星数据产品进行了精度验证。结果表明: OMI 臭氧产品 与Pandora 地基测量结果之间具有很好的线性相关性, 相关系数达到0.948, 但精度结果存在区域差异。在南半球地区, 相关系数为0.915; 在北半球低纬度地区, 其相关系数为0.932, 中纬度地区相关系数为0.948, 而在高纬度地区, 相关系 数达到了0.957。此外, 验证精度还与臭氧柱总量存在相关性, 在臭氧柱总量低于220 Du (对应臭氧空洞条件) 时, OMI 卫星产品存在高估现象, 高估约13%; 而在臭氧柱总量高于400 Du 时, OMI 的臭氧产品低于Pandora 地基测量结果, 且 随着臭氧柱总量增加, 低估情况也越严重, 在臭氧柱总量达到500 Du 时, OMI 臭氧产品低估约4%。     

改性浇铸尼龙的研究进展

立足于浇铸尼龙的反应机理,结合对其在实际应用中的改性要求,阐述了改性浇铸尼龙的研究进展.尤其以聚合物改性浇铸尼龙为重点,从改性的机理和相形态等方面详细地介绍了其的研究情况,总结了最新的工作以及将来的发展方向,为尼龙材料的更加广泛应用提供一定的参考.     

Two Novel Myrinsol Diterpenes from Euphorbia prolifera

Two novel diterpenes,Euphorprolitherin A(1) and Euphorprolitherin B(2), were isolated from the roots of Euphorbia prolifera. Their structures were elucidated on the basis of spectroscopic methods.     

甲基丙烯酸缩水甘油酯/苯乙烯固相接枝聚丙烯

以苯乙烯(St)为共单体，过氧化苯甲酰(BPO)为引发剂，采用固相接枝反应将甲基丙烯酸缩水甘油酯(GMA)接枝到聚丙烯(PP)大分子链上。研究了反应时间、单体用量、引发剂用量等因素对接枝率的影响。采用凝胶渗透色谱(GPE)测定了PP和接枝物PP-g-(GMA-St)的分子量和分子量分布。结果 表明固相接枝PP反应条件为[GMA／[St]=2，反应3．5h，加入GMA 10份，BPO 5份。St的加入有助于GMA与PP的接枝，同时在一定程度上抑制了PP的降解。     

Intrinsic Surface Reaction Constant in 1-pK Model of Mg-Fe Hydrotalcite-like Compounds

The relationship among intrinsic surface reaction constant (K) in 1-pK model, point of zero net charge (PZNC) and structural charge density (σst) for amphoteric solid with structural charges was established in order to investigate the effect of σst on pK. The theoretical analysis based on 1-pK model indicates that the independent PZNC of electrolyte concentration (c) exists for amphoteric solid with structural charges. A common intersection point (CIP) should appear on the acid-base titration curves at different c, and the pH at the CIP is pHPZNC. The pK can be expressed as pK=-pHPZNC log[(1 2αPZNC)/(1-2αPZNC)], where αPZNC≡σst/eNANs, in which e is the elementary charge, NA the Avogadro‘s constant and Ns the total density of surface sites. For solids without structural charges, pK=-pHPZNC. The pK values of hydrotalcite-like compounds (HTlc) with general formula of [Mg1-xFex(OH)2](Cl,OH)x were evaluated. With increasing x, the pK increases, which can be explained based on the affinity of metal cations for H^- or OH^- and the electrostatic interaction between charging surface and H^- or OH^-.     

一个新的噻二唑衍生物H2ADTZ与锰的二维聚合物的合成与晶体结构(英)

A new 1,3,4 thiadiazole-derivative ligand 2,5-(s-acetic acid) dimercapto-1,3,4 thiadiazole (H₂ADTZ) and its one-dimensional manganese polymer Mn(ADTZ)·4H₂O had been synthesized and structurally characterized by X-ray single crystal diffraction in this paper. The Mn(Ⅱ) ion is coordinated with a distorted octahedron by two oxygen atoms from neighboring two deprotonated ligands ADTZ^2- and other four oxygen atoms from four coordinated water molecules. The structural feature of the title compound is the formation of one-dimensional manganese chains polymer through the bridging of dioxygen O-O units. In the solid state structure of the complex, one-dimensional manganese chains are joined together by the weak intermolecular hydrogen bonds and vander Waals interactions forming a two-dimensional supramolecular compound. Furthermore, the UV spectra and electro-chemical properties of the title compound were also investigated. CCDC: 260532.     

The Synthesis of Gracillin and Dioscin：TWO Typical Representatives of Spirostanol Glycosides

Two spirostanol saponins(gracillin and dioscin)which have the typical sugar moieties were synthesized facilely by a general approach.