全文获取类型
收费全文 | 4822篇 |
免费 | 956篇 |
国内免费 | 1165篇 |
专业分类
化学 | 1978篇 |
晶体学 | 131篇 |
力学 | 152篇 |
综合类 | 96篇 |
数学 | 488篇 |
物理学 | 1632篇 |
无线电 | 2466篇 |
出版年
2024年 | 30篇 |
2023年 | 64篇 |
2022年 | 180篇 |
2021年 | 184篇 |
2020年 | 155篇 |
2019年 | 158篇 |
2018年 | 150篇 |
2017年 | 206篇 |
2016年 | 118篇 |
2015年 | 236篇 |
2014年 | 275篇 |
2013年 | 329篇 |
2012年 | 376篇 |
2011年 | 426篇 |
2010年 | 405篇 |
2009年 | 454篇 |
2008年 | 500篇 |
2007年 | 488篇 |
2006年 | 428篇 |
2005年 | 336篇 |
2004年 | 245篇 |
2003年 | 184篇 |
2002年 | 182篇 |
2001年 | 170篇 |
2000年 | 194篇 |
1999年 | 90篇 |
1998年 | 59篇 |
1997年 | 38篇 |
1996年 | 23篇 |
1995年 | 35篇 |
1994年 | 30篇 |
1993年 | 29篇 |
1992年 | 24篇 |
1991年 | 13篇 |
1990年 | 15篇 |
1989年 | 19篇 |
1988年 | 14篇 |
1987年 | 14篇 |
1986年 | 10篇 |
1985年 | 11篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 6篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1975年 | 3篇 |
1965年 | 3篇 |
排序方式: 共有6943条查询结果,搜索用时 15 毫秒
21.
HOU Jing-Min TIAN Li-Jun 《理论物理通讯》2005,44(6):1025-1036
The Green's functions and the correlation functions in spin-2 Bose-Einstein condensates at finite temperature are defined and the generalized Dyson-Beliaev equations are introduced. We discuss the spin conservation in z direction and decouple the Green's functions and the generalized Dyson-Beliaev equations according to different spin conservations in z direction. The anomalous vertex functions are introduced and the self-energies are separated into the proper self-energies and the improper self-energies. The generalized Dyson-Beliaev equations are decoupled according to separation of the self-energies. We calculate the Green's functions step by step in the Bogoliubov approximation and discuss the collective excitations in spin-2 Bose-Einstein condensates in the polar, ferromagnetic, and cyclic cases, respectively. 相似文献
22.
We propose a scheme for multiparty-controlled remote preparation of the two-particle state by using two non-maximally Greenberger-Horne-Zeilinger states as quantum channel. Our scheme consists of one sender and n remote receivers. It will be shown that the sender can help either one of the n receivers to remotely preparation the original state with the appropriate probability, and the sender Alice's two-particle projective measurement and the controllers' single-particle product meazurements are needed. We also obtained the probability of the successful remote state preparation. 相似文献
23.
通过把互感滤波器应用到ZVS-PWM移相变换器的输出端,详细分析了互感滤波器对全桥移相ZVS-PWM变换器的影响,并利用PSPICE软件对全桥移相ZVS-PWM变换器及其改进电路进行了仿真,分析了互感滤波器应用在ZVS-PWM中的二阶滤波模式,比较了互感滤波与L、C滤波的效果,通过仿真验证了理论分析的结果。 相似文献
24.
The optical transient and kinetics characterizations of the transients formed in the reaction of OH with benzotrifluoride (BTF) were performed by a laser flash photolysis technique. The results indicated that the formation of π‐type adduct of C6H5(OH)CF3 was the major reaction channel, and the δ‐type adduct of C6H5CF3OH formation was an additional minor process in the oxidation reaction of BTF attacked by OH radicals yielded from the photolysis of H2O2. Addition of OH to the CF3 group led to the fluoride ion elimination to yield α,α‐difluorophenylcarbinol (C6H5CF2OH). Trifluoromethylphenol (HOC6H4CF3) of meta‐, para‐ and ortho‐substituted isomers resulted from the addition of OH to the BTF aromatic ring. 相似文献
25.
在水热条件下,利用硫代羟基二乙酸配体[thiodiglycolic acid=H2tda]和TbCl3·nH2O合成了新型稀土配合物[Tb2(tda)3(H2O)2]。单晶结构表明,配合物是以共边多面体[Tb2O16]为基本单元构筑的二维结构,并通过弱相互作用拓展为三维超分子体系。中心原子铽与氧原子的配位数是8和9,分别形成了单帽反四棱柱和三帽三角棱柱构型的空间配位多面体。配体H2tda在配合物中存在两种配位模式:(a) 双“顺-顺桥式双齿、螯合桥式三齿”模式和(b) 双“螯合双齿、顺-反桥式双齿”模式。荧光光谱研究表明:该配合物在室温下呈现较强的绿色荧光发射。配合物属三斜晶系,空间群P1。 相似文献
26.
HOU Ying SHI Zhan YANG Ming LI Guang-hua FENG Shou-hua State key Laboratory of Inorganic Synthesis Preparative Chemistry College of Chemistry Jilin University Changchun P. R. China 《高等学校化学研究》2005,21(4):406-410
IntroductionThe syntheses of metal-organic coordination poly-mers have been attracting increasing attention owing tothe potential applications of their functional materials incatalysis,non-linear optics,magnetism sensors andmolecular recognition[1—7].Coordination polymers crys-tallized from polyaromatic acids and metal-ions are ofgreat interest for their polymeric structures and porousproperties[8—12].Their network topologies based on mo-lecular building blocks are usually controlled and mod… 相似文献
27.
在胺存在下,3,7-二硝基二苯并溴五环硫酸氢盐与二甲基亚砜反应生成2-溴-4,4'-二硝基-3'-二甲基锍-2'-联苯酚内盐(3).3的X射线晶体结构分析数据表明其分子具有内盐结构但酚氧负离子的负电荷是部分离域的,分子内两苯环所成的两面角为117.3°.3在熔解时发生重排及热分解分别生成2-溴-2'-甲氧基-3'-甲硫基-4,4'-二硝基联苯(6)及3,7-二硝基-4-甲硫基-二苯并呋喃(7).3与盐酸反应生成相应的锍盐(8). 相似文献
28.
The chemical compositions of silicate minerals, sulphide minerals and metal Fe-Ni in theQingzhen meteorite were measured by the microprobe analyses. Based upon these chemicalcompositions, the cosmochemical behaviour and characteristics of the existing forms of themajor elements in the Qinzhen meteorite have been discussed. These characteristics show thatunder the S-rich, O-poor, and strongly reducing conditions, the light metal elements, such asCa, Mg, K, Na may form sulphide, and metal Fe-Ni may contain Si and P. However, we con-sider that the light metal-sulphide can be stable in the lower mantle and there are some Siand P in the Fe-Ni core. Finally, an earth core-mantle model is established, where the Fe-Ni core contains some Si and P; the lower mantle is composed of Mg-rich silicate, SiO_2 andsulphide; the upper mantle, of silicate and oxide. 相似文献
29.
30.
在一般模糊测度空间上,针对可测模糊值函数序列给出了几乎处处收敛,几乎一致收敛和伪几乎一致收敛的概念,并在此基础上,进一步研究了这几种收敛的蕴涵关系,从而获得了模糊化的Egoroff定理,使模糊值函数序列的理论得到进一步丰富. 相似文献