全文获取类型
收费全文 | 256篇 |
免费 | 71篇 |
国内免费 | 9篇 |
专业分类
化学 | 160篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 32篇 |
物理学 | 117篇 |
无线电 | 25篇 |
出版年
2023年 | 5篇 |
2022年 | 6篇 |
2021年 | 9篇 |
2020年 | 13篇 |
2019年 | 9篇 |
2018年 | 9篇 |
2017年 | 5篇 |
2016年 | 11篇 |
2015年 | 6篇 |
2014年 | 9篇 |
2013年 | 19篇 |
2012年 | 26篇 |
2011年 | 23篇 |
2010年 | 11篇 |
2009年 | 8篇 |
2008年 | 12篇 |
2007年 | 10篇 |
2006年 | 12篇 |
2005年 | 9篇 |
2004年 | 3篇 |
2003年 | 4篇 |
2001年 | 6篇 |
2000年 | 2篇 |
1996年 | 3篇 |
1994年 | 2篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1982年 | 9篇 |
1978年 | 4篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1966年 | 2篇 |
1965年 | 10篇 |
1964年 | 7篇 |
1963年 | 5篇 |
1961年 | 3篇 |
1960年 | 1篇 |
1959年 | 14篇 |
1958年 | 5篇 |
1956年 | 1篇 |
1955年 | 5篇 |
1954年 | 2篇 |
排序方式: 共有336条查询结果,搜索用时 15 毫秒
51.
Sho Ikeda Ryo Shintani 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(17):5790-5794
A new mode of polymerization, rhodium‐catalyzed stitching polymerization, has been developed for the synthesis of π‐conjugated polymers with bridged repeating units from nonconjugated 1,5‐hexadiynes containing both terminal and internal alkyne moieties as monomers. The polymerization proceeded smoothly with a high degree of stitching efficiency under mild conditions, and 1,5,9‐decatriyne and 1,5,9,13‐tetradecatetrayne monomers could also be employed. The present polymerization strategy would be particularly beneficial for the synthesis of polymers consisting of a repeating unit that is difficult to prepare as a stable monomer because it does not require the use of a preformed bridged π‐conjugated monomer. 相似文献
52.
Fujiwara Masahide Hirosawa Koki Nonose Naoko Nishida Sho Furuta Naoki 《Accreditation and quality assurance》2019,24(5):329-339
Accreditation and Quality Assurance - The goal of this study was to evaluate the uncertainty of elemental analytical methods that use laser ablation in liquid (LAL) as a pretreatment. After LAL... 相似文献
53.
Direct Estimation of the Surface Location of Immobilized Functional Groups for Concerted Catalysis Using a Probe Molecule 下载免费PDF全文
Hiroto Noda Dr. Ken Motokura Prof. Dr. Yusuke Wakabayashi Kaori Sasaki Dr. Hiroo Tajiri Dr. Akimitsu Miyaji Dr. Sho Yamaguchi Prof. Dr. Toshihide Baba 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(15):5113-5117
The location of active sites during concerted catalysis by a metal complex and tertiary amine on a SiO2 surface is discussed based on the interaction between the functionalized SiO2 surface and a probe molecule, p‐formyl phenylboronic acid. The interactions of the probe molecule with the surface functionalities, diamine ligand, and tertiary amine, were analyzed by FT‐IR and solid‐state 13C and 11B MAS NMR. For the catalyst exhibiting high 1,4‐addition activity, the diamine ligand and tertiary amine base exist in closer proximity than in the catalyst with low activity. 相似文献
54.
We show that the Smith normal form of a skew‐symmetric D ‐optimal design of order is determined by its order. Furthermore, we show that the Smith normal form of such a design can be written explicitly in terms of the order , thereby proving a recent conjecture of Armario. We apply our result to show that certain D ‐optimal designs of order are not equivalent to any skew‐symmetric D ‐optimal design. We also provide a correction to a result in the literature on the Smith normal form of D ‐optimal designs. 相似文献
55.
Cross-layer selective routing for cost and delay minimization in IEEE 802.11ac wireless mesh network
Lai I.-Wei Funabiki Nobuo Tajima Shigeto Al Mamun Md. Selim Fujita Sho 《Wireless Networks》2018,24(6):2191-2203
Wireless Networks - A Wireless Internet-access Mesh NETwork (WIMNET) provides scalable and reliable internet access through the deployment of multiple access points (APs) and gateways (GWs). In... 相似文献
56.
以三苯胺、咔唑、4,4′-二羧基联吡啶为原料,设计并合成了两个联吡啶铱(III)配合物Ir1和Ir2,其结构经1H NMR, 13C NMR和HR-MS(MALDI-TOF)表征。并利用紫外可见光谱(UV-Vis)、荧光发射光谱(Photoluminescence)和循环伏安法研究了化合物的光学和电学性质。结果表明:Ir1和Ir2的紫外可见光吸收波长分别位于456 nm 和448 nm,相应的发射波长分别为645 nm和678 nm,说明其均能利用可见光; Ir1和Ir2的HOMO电位为-5.125~-5.510 eV, LOMO电位为-2.880~-0.310 eV,满足作为光敏剂的基本条件。研究了化合物在可见光照射下光催化水分解产生氢气的效果。结果表明:Ir1和Ir2的氢气值TONs(turnover numbers)达到2 827和1 908。 相似文献
57.
Pressure-induced reentrant micellization of amphiphilic block copolymers in dilute aqueous solutions
Osaka N Miyazaki S Okabe S Endo H Sasai A Seno K Aoshima S Shibayama M 《The Journal of chemical physics》2007,127(9):094905
The pressure-induced structural changes of a block copolymer, poly(2-ethoxyethoxyethyl vinyl ether)-block-poly(2-hydroxyethyl vinyl ether) (pEOEOVE-b-pHOVE) in aqueous solutions, were studied by means of small-angle neutron scattering (SANS) and dynamic light scattering (DLS) from atmospheric pressure up to 400 MPa. pEOEOVE-b-pHOVE formed a spherical micellar structure above 40 degrees C due to poor solubility of pEOEOVE. Micellization phase diagram was determined by DLS, and a covex-upward pressure-temperature (P-T) phase diagram was obtained having a peak around (P,T)=(150 MPa,48 degrees C). The SANS curves at 50 degrees C were analyzed as a function of P. The micellar core size decreased by pressurizing at low P's (P相似文献
58.
In this paper, three hotly discussed problems, namely the neutrino bursts, the blue progenitor, and the mixing phenomenon, observed in SN1987A are summarized. But it is pointed that while all the observations on SN1987A do not favour a twice-banged scenario, we have found three historical cases from ancient Chinese documents that might be interpreted as twice- or even multi-explosions of a supernova. Finally in a one-dimensional simulation we demonstrate that an induced gravitational collapse b possible. 相似文献
59.
本文报道从变色马兜铃(Aristolochia versicolar)的块根中提取的一种新倍半萜内酯-银袋内酯乙的乙酰化物的晶体结构和分子结构.分子式为C~17H~22O~4,分子量290.4,晶体属单斜晶系,空间群为P2~1,a=0.9594(5),b=0.6626(6),c=1.2924(12)um,β=94.48(6)`,V=0.819(1)nm^3,Z=2,Dx=1,18g.cm^-^3,F(000)=266e,μ=0.77cm^-^1(MoKa).结构用直接法解出,经最小二乘法修正后1280个衍射点偏离因子为R=5.5%,Rw=5.2%.分子由椅型.椅型的1,5二烯十员环([2323]矩形)和共用两个相邻DunitzIII型碳C(4),C(5),一个Dunitz II型碳C(6)的五员内酯环组成.十员环与五员内酯环之间夹角为99.该分子骨架拓扑在迄今已知的倍半萜内酯中只与银袋内酯丙相似.所有非氢原子的键长和键角均在实验误差范围内接近理论值。 相似文献
60.
It is found that owing to the large energy difference in K-and L-shells of the daughter atom, 158Tb is not the best candidate for neutrino "balance". Instead, l57Tb can offer a better chance for. neutrino mass determination if the Q-value 55 far obtained is verified. If it is so,then the relevant atomic calculation with high precision is very necessary. It is shown that to include the radiative correction in the Hartree-Fock calculation is very important for such atoms as 157Gd and 157Tb. 相似文献