基于多尺度特征选择性融合的遥感图像检测算法北大核心CSCD

遥感图像的检测在监察自然环境、军事、国土安全等方面具有极其广阔的应用前景,而遥感图像具有背景复杂、目标面积小、特征提取困难等缺点,进行检测时容易产生小目标漏检问题。本文提出一种基于多尺度特征选择性融合的遥感图像检测算法。所提算法采用改进的Resnet50作为主干网络,将Resnet50第一个卷积替换成动态卷积,并将其ConvBlock模块中的卷积替换成金字塔卷积,提高特征提取能力。同时,为了避免遗漏底层信息,在动态卷积层后加入所提有效空间通道注意力机制模块。最后,选取基于上下文信息的不同尺度特征进行融合,提高了模型对目标物体的定位能力。实验结果表明,本文算法在保证速度的同时提高了对遥感图像的检测精度,在遥感图像公开数据集RSOD和NWPUVHR-10上平均精度均值(mean average precision,mAP)分别达到91.88%和90.23%,检测速度达到33 FPS。     

短波通信频率的选择技术研究与实现

短波通信技术具有传输距离远、灵活性强、机动性高、应用成本低等优势,在诸多领域都有着广泛的应用。短波通信主要时利用电离层与地面之间的反射实现通信功能,受到太阳辐射等多方面因素的影响,电离层具有不稳定性和变化的不规则性,短波通信的稳定性、可靠性和持久性也会受到较大的影,保证短波通信的质量,要结合通信需求和电离层变化的规律,选择合适的通信信道和通信频率。     

一种高动态低信噪比环境下基于多样本点串行快速傅里叶变换的信号捕获方法

高超音速技术是未来空间飞行器的发展趋势,同时对通信平台在超高动态、低信噪比环境下的快速捕获能力也提出了新的挑战.针对经典捕获算法受频偏影响的局限性,该文提出一种基于信号多样本点串行快速傅里叶变换的信号捕获算法(MS-FFT),所提算法通过串行执行多个样本点的FFT,采用非相干合并后的峰值搜索得到捕获结果,在不增加复杂度的条件下,避免了频偏对捕获性能的影响.通过对峰值信噪比(PSNR)理论公式的推导,证明了MS-FFT的频偏适应范围取决于采样率,随着数模转换器件采样能力的不断提升,具有比经典算法更大的频偏适应范围.最后,通过仿真验证了上述理论推导的正确性,证明了所提算法更加适合超高动态环境的应用场景.     

A Glivenko-Cantelli lemma and weak convergence for empirical processes of associated sequences

Summary With the help of an extension of Hoeffding's equality, we develop a way for estimating the covariance structures for empirical functions of associated sequences in terms of covariances of the original random variables. Based on these estimations, a Glivenko-Cantelli lemma for associated sequences and weak convergence for empirical processes of stationary associated sequences are obtained, all under the conditions on covariances of the original random variables.This research has been supported partially by a scholarship from the Faculty of Graduate Studies and Research of Carleton University, Ottawa, and by an NSERC Canada grant of M. Csörg     

A metallo-capped polyrotaxane containing calix[4]arenes and cyclodextrins and its highly selective binding for Ca2+

A water-soluble nanometer-scale metallocapped polyrotaxane has been prepared by the inclusion complexation of azo-calixarenes with metallo-bridged bis(beta-CD)s, displaying highly selective binding for Ca(2+).     

STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES

The photopolymerization of acrylonitrile (AN) initiated with phenyl hydrazine (PHZ) and its derivatives has been studied. The initiator exponent and monomer exponent were determined from the kinetic investigation to be 0.66th and 2.1th respectively and the overall activation energy was 33.4KJ/mol for the PHZ-AN system. Spectral analysis and other data indicate that a charge transfer complex between PHZ as a donor and AN as an aceeptor is formed. The initiation mechanism was proposed.     

Diastereoselective allylation of planar chiral substituted ferrocenecarboxaldehyde: an efficient entry to chiral ferrocenyl ligands

2,2′-Disubstituted ferrocenecarboxaldehydes are subjected to zinc-mediated allylation to form homoallylic ferrocenyl alcohols. The effects of ortho-substituted functional groups on facial selectivities of planar chiral aldehydes were studied and it was found that the corresponding homoallylic alcohols were obtained as single diastereomers in excellent yields.     

A new serratane-type triterpene from Lycopodium phlegmaria

A new serratane-type triterpene, lycophlegmarin (1), has been isolated from Lycopodium phlegmaria L. Four known related triterpenoids were also found from the title plant. The structure of the new compound was elucidated on the basis of detailed spectroscopic analysis and chemical method. Lycophlegmarin exhibited modest growth-inhibitory activity in vitro against human hepatoma cells BEL 7402.     

Intermolecular potential energy surface and spectra of He-HCl with generalization to other rare gas-hydrogen halide complexes

A two-dimensional (rigid monomer) intermolecular potential energy surface (PES) of the He-HCl complex has been obtained from ab initio calculations utilizing the symmetry-adapted perturbation theory (SAPT) and an spdfg basis set including midbond functions. The bond length in HCl was chosen to be equal to the expectation value in the ground vibrational state of isolated HCl. The rigid-monomer potential should be a very good approximation to the complete (three-dimensional) potential for H-Cl distances corresponding to the lowest vibrational levels of the monomer since the He-HCl interaction energy was found to be only weakly dependent on the HCl bond length in this region, at least as compared to systems such as Ar-HF. The calculated points were fitted using an analytic function with ab initio computed asymptotic coefficients. As expected, the complex is loosely bound, with the dispersion energy providing the majority of the attraction. Our SAPT PES agrees with the semiempirical PES of Willey et al. [J. Chem. Phys. 96, 898 (1992)], in finding that, atypically for rare gas-hydrogen halide complexes including the lighter halide atoms, the global minimum is on the Cl side (with intermonomer separation 3.35 A and depth of 32.8 cm(-1)), rather than on the H side, where there is only a local minimum (3.85 A, 30.8 cm(-1)). The ordering of the minima was confirmed by single-point calculations in larger basis sets and complete basis set extrapolations, and also using higher levels of theory. We show that the opposite findings in the recent calculations of Zhang and Shi [J. Mol. Struct: THEOCHEM 589, 89 (2002)] are due to the lack of midbond functions in their basis set. Despite the closeness in depth of the two linear minima, the existence of a relatively high barrier between them invalidates the assumption of isotropy, a feature of some literature potentials. The trends concerning the locations of minima within the family of rare gas-hydrogen halide complexes are rationalized in terms of the physical components of the intermolecular forces and related to monomer properties. The accuracy of the SAPT PES was tested by performing calculations of rovibrational levels. The transition frequencies obtained were found to be in excellent agreement (to within 0.02 cm(-1)) with the measurements of Lovejoy and Nesbitt [J. Chem. Phys. 93, 5387 (1990)]. The SAPT PES predicts a dissociation energy for the complex of 7.74 cm(-1) which is probably more accurate than the experimental value of 10.1+/-1.2 cm(-1). Our analysis of the ground-state rovibrational wave function shows that the He-HCl configuration is favored over the He-ClH configuration despite the ordering of minima. This is due to the greater volume of the well in the former case. We have also determined positions and widths of three low-lying resonance states through scattering calculations. These predictions are expected to be more accurate than values derived from experiment.