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941.
The selective degradation of polyethylene crystals with fuming nitric acid has been used to prepare a C100 chain with terminal functional groups. After treating this product with concentrated sulphuric acid, it is shown by average molecular weight, titration and infra-red spectroscopy measurements that each molecule contains two carboxylic acid groups. This C100 dicarboxylic acid is chain extended with several low molecular weight difunctional coupling agents. Block copolymers of this acid and poly(propylene glycol) have been prepared. 相似文献
942.
Electrical Conductivity of Molten Strontium Chloride-Alkali Chloride Salt Mixtures The temperature and concentration dependence of the specific electrical conductivity is measured for binary fused mixtures SrCl2–MeCl (Me = Li, Na, K, Rb, Cs). Minima of the conductivity are found at the concentration x · 0.5 in the systems SrCl2–(KCl, RbCl, CsCl). 相似文献
943.
The polarographic behaviour of phenylhydrazonomesoxalonitrile (2) and ethyl phenylhydrazonomesoxalonitrile (3) as well as pK′ and pKa values are reported for a series of arylhydrazones of α-cyanoketones. 相似文献
944.
Frans H.A. Rummens 《Chemical physics letters》1975,31(3):596-598
The use of the Bayliss-McRae theory on the solvent induced electronic frequency shifts for NMR dispersion shifts is criticized. It is suggested that the NMR shifts should actually be proportional to the square of the Bayliss-McRae function. It is shown that the methane gas-to-liquid shifts in eleven halo-methanes as solvents are indeed proportional to this squared function; ?σm(CH4) = 9.62 (n22?1)2/(2n22+1)2 ppm, where n2 is the refractive index of the solvent. The relation between this solvent factor and several existing continuum models for NMR medium shifts is discussed. 相似文献
945.
A systematic study of the adsorption and interfacial behaviour of the adenine mono-nucleotides (5′-AMP, 3′-AMP, cyclic 3′,5′-AMP, 5′-ADP and 5′-ATP) and adenosine for comparison at the HMDE has been carried out at pH 3.4 to 3.5. Thus, the N(1) of the adenine moiety is protonated to a major extent.The adsorption was followed by single sweep voltammetry (measurement of the time integral of the reduction peak of the adsorbed adenine moiety) and by a.c. voltammetry (out-of-phase component of the a.c. response being proportional to the differential double layer capacity). In this paper the situation corresponding to a “dilute” adsorption layer existing at low bulk concentrations is studied for various degrees of coverage. The potential dependence of the coverage is of bell shaped type with an extended maximum region around the potential of electrocapillary maximum (Eecm) of the blank. For the same bulk concentration the coverage decreases in the series AMP, ADP, ATP, i.e. with increasing negative charge of the nucleotide, and at the same time the potential range of adsorption narrows. Among the monophosphates the coverage decreases in the series 3′-AMP, 5′-AMP, cyclic 3′,5′-AMP. The variations are connected with the varying charge of the mononucleotides and with the possibilities for interactions with adjacent molecules in the adsorption layer.At elevated bulk concentrations above a threshold value a substantial increase in coverage occurs around Eecm as due to strong interactions between the adsorbed base moieties a rather compact film is formed. 相似文献
946.
The types of ion occurring in the field desorption mass spectra of inorganic and organic salts are discussed. In contrast to general experience with field desorption mass spectrometry molecular ions are either absent or of low intensity. The energetically and kindetically favoured process of cluster formation, however, generates ions from which the molecular structure can be easily derved. Some specific aspects for the analyses of salts by field desrption mass spectrometry are outlined. 相似文献
947.
U. Wannagat F. Vielberg H. Voß K. Hensen W. Sarholz 《Monatshefte für Chemie / Chemical Monthly》1969,100(4):1127-1132
The enthalpies of formation of the addition compounds F4Si(py)2, Cl4Si(py)2, Br4Si(py)2 and I4Si(py)4 have been measured calorimetrically by two different ways (see table 1). It was not possible to confirm enthalpy data published in7, 8. The sequence SiF44~SiBr4>SiI4(?) is proposed for the acceptor power of the silicon tetrahalides towards pyridine. 相似文献
948.
H. Boller 《Monatshefte für Chemie / Chemical Monthly》1973,104(2):545-549
Zusammenfassung Es wird gezeigt, daß die Oktaederlücken des Re3B-Typs in obigen Systemen teilweise durch Sauerstoff aufgefüllt werden. Die Auffüllungsbereichex der Phasen Zr3CoO
x
, Zr3NiO
x
, Hf3CoO
x
und Hf3NiO
x
werden studiert.
Mit 2 Abbildungen 相似文献
On the filled upRe 3 B-type in the systems(Zr, Hf)–(Fe, Co, Ni)–O
It is shown that the octahedral voids of the Re3B-type are partially filled up by oxygen in the above systems. The homogenous ranges ofx of the phases Zr3CoO x , Zr3NiO x , Hf3CoO x , and Hf3NiO x are studied.
Mit 2 Abbildungen 相似文献
949.
Fischer indolization of ethyl pyruvate 2-methoxyphenylhydrazone (1) with p-toluene-sulfonic acid in benzene in the presence of an enolizable dicarbonyl or an indolic compound gave either an indole product having an active methine group at C6 or a novel type of 3,6′-biindole compound. Structures of the products were established by NMR spectra and chemical evidence. 相似文献
950.
An unambiguous synthesis of Cypridina etioluciferamine was accomplished in order to prove the structure of this important bioluminescent natural product. Several 2-aminopyrazine 1-oxides were synthesized in order to establish a spectroscopic method for determining the placement of substituents on the pyrazine nucleus of Cypridina etioluciferamine. Titanium tetrachloride was used to improve the yields of these compounds; for example, the yield of 2-amino-3-methyl-5-phenylpyrazine 1-oxide (19) from reaction of phenylglyoxal 1-oxime and α-aminopropionitrile was raised from 3% to 51% by the use of titanium tetrachloride. The pyrazine ring proton is found at τ 1·37 (DMSO-d6). The isomeric 2-amino-3-methyl-6-phenylpyrazine 1-oxide (22) was similarly prepared and its pyrazine ring proton is found at τ 2·18. This large difference (0·81 ppm) in chemical shift was used to determine whether a 2-aminopyrazine 1-oxide was 5- or 6- substituted. Prepared in an analogous fashion were 2-amino-5-(indol-3-yl)-3-methylpyrazine 1-oxide (23) and 2-amino-5-(indol-3-yl)-3-(3-phthalimidopropyl)pyrazine 1-oxide (16). The structures of these compounds were verified by NMR spectroscopy. By treatment with Raney nickel and hydrogen gas, then 100% hydrazine hydrate, 16 was converted to 2-amino-3-(3-aminopropyl)-5-indol-3-ylpyrazine (5), isolated as the dihydrochloride. This compound, with the indole moiety definitely placed at C-5, is identical with Cypridina etioluciferamine dihydrochloride (IR, UV, TLC). These results show that the structures of Cypridina etioluciferamine and luciferin are correct as published. 相似文献