Controllably asymmetric beam splitting via gap-induced diffraction channel transition in dual-layer binary metagratings

In this work, we designed and studied a feasible dual-layer binary metagrating, which can realize controllable asymmetric transmission and beam splitting with nearly perfect performance. Owing to ingenious geometry configuration, only one meta-atom is required to design for the metagrating system. By simply controlling air gap between dual-layer metagratings, high-efficiency beam splitting can be well switched from asymmetric transmission to symmetric transmission. The working principle lies on gap-induced diffraction channel transition for incident waves from opposite directions. The asymmetric/symmetric transmission can work in a certain frequency band and a wide incident range. Compared with previous methods using acoustic metasurfaces, our approach has the advantages of simple design and tunable property and shows promise for applications in wavefront manipulation, noise control and one-way propagation.     

Blue electroluminescent materials based on indeno[1,2-a]arene derivatives for Organic Light-Emitting Diodes

Abstract

In this study, as a continuous effort for searching efficient blue-emitting materials, we designed and synthesized materials based on indeno[1,2-a]arene. OLED devices using these materials were fabricated in the following sequence; ITO (180?nm)/N,N'-diphenyl-N,N'-(2-napthyl)-(1,1'-phenyl)-4,4'-diamine (NPB) (50?nm)/emitting materials (30?nm)/4,7-diphenyl-1,10-phenanthroline (Bphen) (30?nm)/Liq/Al (2/100?nm). Particularly, a device using 7,7-dimethyl-7H-indeno[1,2-a]pyrene as emitter showed maximum values of luminous efficiency, power efficiency, and external quantum efficiency of 1.10?cd/A, 0.49?lm/W, 1.47% at 20?mA/cm², respectively with CIE (x,y) coordinates of (0.15, 0.08) at 6.0V.     

PCB插件孔散热焊盘设计对上锡影响

0引言 插件孔:即PCB通孔直插式元件与电路板连接的金属化孔(PTH),常规插件孔孔径公差要求为±0.075 mm,此类插件孔的孔需要焊接.也有一些要求为压接器件的插件孔,此类插件孔对孔径精度要求高,作用是直接将原件的引脚插进去,通过引脚与孔壁的接触导通电流,此类孔不需要焊接,常规压接插件孔孔径公差要求为±0.05 m...     

Analysis of Vicinal Water in Soft Contact Lenses Using a Combination of Infrared Absorption Spectroscopy and Multivariate Curve Resolution

In this paper, we propose a new spectroscopic method to explore the behavior of molecules near polymeric molecular networks of water-containing soft materials such as hydrogels. We demonstrate the analysis of hydrogen bonding states of water in the vicinity of hydrogels (soft contact lenses). In this method, we apply force to hydrated contact lenses to deform them and to modulate the ratio between the signals from bulk and vicinal regions. We then collect spectra at different forces. Finally, we extracted the spectra of the vicinal region using the multivariate curve resolution-alternating least square (MCR-ALS) method. We report the hydration states depending on the chemical structures of hydrogels constituting the contact lenses.     

Rate Coefficients and Kinetic Isotope Effects of Cl+XCl→XCl+Cl (X=H,D, Mu) Reactions from Ring Polymer Molecular Dynamics

The ring-polymer molecular dynamics (RPMD) was used to calculate the thermal rate coefficients and kinetic isotope effects of the heavy-light-heavy abstract reaction Cl+XCl\begin{document}$ \rightarrow $\end{document}XCl+Cl (X = H, D, Mu). For the Cl+HCl reaction, the excellent agreement between the RPMD and experimental values provides a strong proof for the accuracy of the RPMD theory. And the RPMD results are also consistent with results from other theoretical methods including improved-canonical-variational-theory and quantum dynamics. The most novel finding is that there is a double peak in Cl+MuCl reaction near the transition state, leaving a free energy well. It comes from the mode softening of the reaction system at the peak of the potential energy surface. Such an explicit free energy well suggests strongly there is an observable resonance. And for the Cl+DCl reaction, the RPMD rate coefficient again gives very accurate results compared with experimental values. The only exception is at the temperature of 312.5 K, results from RPMD and all other theoretical methods are close to each other but slightly lower than the experimental value, which indicates experimental or potential energy surface deficiency.     

基于扫描探针显微镜(SPM)的高密度信息存储

随着信息技术的飞速发展,高密度信息存储的研究成为国际上备受关注的研究领域。扫描探针显微技术（SPM）通过改变材料的光、电、磁等局域特性可以实现纳米尺度的信息存储,成为提高信息存储密度的最有效手段之一。本文从信息存储材料和技术角度综述了基于SPM的高密度信息存储最近的研究进展,并讨论了其将来的研究和发展方向。     

香豆素类荧光传感器

荧光传感器能够将分子识别的信息转换成荧光信号,荧光法在灵敏度、选择性和实时原位检测等方面优势突出。实时检测被分析物的水平已引起包括化学家、生物学家、临床生物化学家和环境学家的极大兴趣。以香豆素为基础的荧光传感器近年来已成为一个新兴的研究热点。本文综述了香豆素类荧光传感器在阳离子、阴离子、中性分子识别检测中的分子设计、作用机理和应用效果,展望了该领域的发展方向。     

Continuous-Variable Measurement-Device-Independent Quantum Key Distribution with One-Time Shot-Noise Unit Calibration

Imperfections in practical detectors,including limited detection efficiency,and inherent electronic noise,can seriously decrease the transmission distance of continuous-variable measurement-device-independent quantum key distribution systems.Owing to the difficulties inherent in realizing a high-efficiency fiber homodyne detector,challenges still exist in continuous-variable measurement-device-independent quantum key distribution system implementation.We offer an alternative approach in an attempt to solve these difficulties and improve the potential for system implementation.Here,a novel practical detector modeling method is utilized,which is combined with a one-time shot-noise-unit calibration method for the purpose of system realization.The new modeling method benefits greatly from taking advantage of one-time shot-noise-unit calibration methods,such as measuring electronic noise and shot noise directly to a novel shot-noise unit,so as to eliminate the statistical fluctuations found in previous methods;this makes the implementation of such systems simpler,and the calibration progress more accurate.We provide a simulation of the secret key rate versus distance with different parameters.In addition,the minimal detection efficiency required at each distance,as well as the contrast between the two methods,are also shown,so as to provide a reference in terms of system realization.     

痫愈胶囊质量标准研究

制定了痫愈胶囊(天麻、僵蚕、黄芪、党参)的质量标准。用显微鉴别法鉴别僵蚕,用薄层色谱法鉴别黄芪、党参,用高效液相色谱法测定天麻素含量。天麻素含量在0.1036~2.072μg范围内呈良好的线性关系,r=0.9997。平均回收率为98.80%,相对标准偏差为0.94%(n=5)。鉴别方法、定量方法可用于该制剂的质量控制。     

化学学科的现状及基础化学教育改革问题

1　化学学科现状简介　　自 1 80 2年道尔顿提出原子假说 ,1 81 1年阿佛加德罗又提出分子学说以来 ,化学一直在原子和分子学说的基础上发展着。 1 86 9年门捷列夫所发现的元素周期律及在此基础上构成的元素周期表 ,使化学从而成为一门有着严密体系的学科。由于当时对于原子和分子的结构理论还停留在假说的阶段 ,化学家的研究工作主要侧重于元素的发现、分析或分离组成复杂的样品的方法以及新化合物的合成 ,所以化学的传统定义中只强调合成和分析两个方面。这个传统在基础化学教育中至今仍然有着深刻的影响。 2 0世纪物理学家对原子结构及有…