国内智能电话机产品技术及生产

全新的智能型电话机,结合了先进的电脑技术和传统的电话技术,功能日趋多元化。本文介绍了国内智能电话机的技术水平、产品现状及生产厂家,并对其未来发展提出了观点。     

Uptake of transferrin-conjugated quantum dots in single living cells

We study the uptake and distribution of transferrin （Tf）-conjugated CdSe/CdS/ZnS quantum dots （QDs） in single living HeLa cells with both fluorescence confocal microscopy and three-dimensional （3D） reconstruction technique. By increasing the co-incubation time or the dosage of QDs-Tf, we find that the uptake of QDs-Tf bioconjugates in the cells increases correspondingly, but with different uptake rates. Additionally, the distribution of QDs-Tf, in single live HeLa cells is time dependent. To our knowledge, this is the first study on quantitatively analyzing the uptake and distribution of bioconjugated QDs in single living cells. Such QDs nanoplatform can be further modified for developing biomedical evaluation tool in cancer diagnosis and targeted drug delivery.     

Structure and catalytic properties of magnesia-supported copper salts of molybdovanadophosphoric acid

The structure and stability of magnesia-supported copper salts of molybdovanadophosphoric acid (Cu(2)PMo(11)VO(40)) were characterized by different techniques. The catalyst was prepared in ethanol by impregnation because this solvent does not hurt texture of the water-sensitive MgO and Cu(2)PMo(11)VO(40). The Keggin-type structure compound may be degraded partially to form oligomerized polyoxometalate when supported on MgO. However, the oligomers can rebuild as the Keggin structure again after thermal treatment in air or during the reaction. Meanwhile, the V atoms migrate out of the Keggin structure to form a lacunary structure, as observed by Fourier transform IR spectroscopy. Moreover, the presence of Cu(2+) as a countercation showed an affirmative influence on the migration of V atoms, and the active sites derived from the lacunary species generated after release of V from the Keggin anion. The electron paramagnetic resonance data imply that V(5+) autoreduces to V(4+) in the fresh catalyst, and during the catalytic reaction a large number of V(4+) ions are produced, which enhance the formation of O(2-) vacancies around the metal atoms. These oxygen vacancies may also improve the reoxidation function of the catalyst. This behavior is correlated to higher catalytic properties of this catalyst. The oxidative dehydrogenation of hexanol to hexanal was studied over this catalyst. After reaction at 553.2 K for 50 h, catalytic properties did not decrease and exhibited higher selectivity (>96.0%) toward hexanal.     

基于晶格动力学的纳米薄膜热特性研究

针对分子动力学模拟存在的缺点,提出了基于晶格动力学模拟纳米薄膜热特性的新方法,并用该方法模拟了各种不同厚度的硅和氩纳米薄膜的比热、熔化温度、热膨胀系数和热传导系数等热特性参数。计算结果表明纳米薄膜具有与宏观晶体不同的热特性,并且呈现随纳米薄膜厚度变化的尺寸效应:纳米薄膜越薄,则熔化温度越低、比热越大、面向热膨胀系数越大、法向热传导系数越小;当纳米薄膜厚度远小于相应的宏观晶体的声子平均自由程时,法向热传导系数远小于相应的宏观晶体的热传导系数,并与纳米薄膜厚度成正比。     

一种支持源代码级调试的全芯片仿真技术

源代码级调试对于嵌入式软件开发效率来说至关重要。传统的IC数字前端仿真平台在运行目标代码时,由于目标机是用硬件描述语言Verilog HDL描述的,因此无法进行源代码级调试,只能通过指令级调试或者查看输出波形来分析问题,然后再反向追溯源代码,开发效率低下。提出一种基于VPI技术的全芯片混合仿真方法,利用该方法可以实现目标机软件内核模型与片上复杂硬件外设模型相结合的混合仿真。由于使用了大量的硬件模型,因此该平台是功能完备的,又由于目标机是由软件实现的,因此该混合仿真平台可支持目标软件的源代码级调试。最后在一款工业级DSP的实际设计流程中的成功应用证明了提出方法的有效性。     

New figuring model based on surface slope profile for grazing‐incidence reflective optics

Surface slope profile is widely used in the metrology of grazing‐incidence reflective optics instead of surface height profile. Nevertheless, the theoretical and experimental model currently used in deterministic optical figuring processes is based on surface height, not on surface slope. This means that the raw slope profile data from metrology need to be converted to height profile to perform the current height‐based figuring processes. The inevitable measurement noise in the raw slope data will introduce significant cumulative error in the resultant height profiles. As a consequence, this conversion will degrade the determinism of the figuring processes, and will have an impact on the ultimate surface figuring results. To overcome this problem, an innovative figuring model is proposed, which directly uses the raw slope profile data instead of the usual height data as input for the deterministic process. In this paper, first the influence of the measurement noise on the resultant height profile is analyzed, and then a new model is presented; finally a demonstration experiment is carried out using a one‐dimensional ion beam figuring process to demonstrate the validity of our approach.     

Rapid-scan time-resolved FT-IR spectroelectrochemistry studies on the electrochemical redox process

The electron transfer to or from molecules containing multiple redox centers has been extensively investigated. Rapid scan time-resolved FT-IR-RAS spectroelectrochemistry was used to investigate the electron-transfer mechanism in this report. The electron transfer of two typical compounds, 1,4-benzoquinone and 1,4-bis(2-ferrocenylvinyl)benzene, was examined with this method. Although the two compounds show two-electron transfer in the redox process, 1,4-benzoquinone exhibits two single electron waves while 1,4-bis(2-ferrocenylvinyl)benzene exhibits a single wave in cyclic voltammetric experiments. The IR absorption of the intermediate, BQ*- and p-(Fc-CH=CH)+2-benzene, at 1506 and 1589 cm(-1), respectively, appeared and disappeared on the experimental time scale in the oxidation and reduction process was observed. In the oxidation process of the p-(Fc-CH=CH)2-benzene molecule, one Fc was oxidated to Fc+ first and the electron-withdrawing ability of Fc+ was stronger than that of Fc, which resulted in the D-pi-A structure and the band at 1589 cm(-1) becoming visible. Then as the oxidation continues, the other Fc was oxidated to Fc+ too, which resulted in the reforming of the symmetry of the benzene ring A-pi-A, so the band at 1589 cm(-1) disappeared. Similar phenomenon can be elucidated in the reduction process but the configuration type changed from A-pi-A to D-pi-A and finally to D-pi-D. Hence, not only 1,4-benzoquinone but also 1,4-bis(2-ferrocenylvinyl)benzene show two consecutive one-electron processes. In addition, it is observed that the existing time of the electrochemical reaction intermediate (BQ*- and p-(Fc-CH=CH)+2-benzene) is prolonged at low temperatures due to slow reaction kinetics.     

不用切口的示波极谱滴定法

利用示波极谱图上切口的出现或消失来指示滴定终点的示波极谱滴定法具有终点直观、操作简便、仪器简单和抗干扰能力强等优点,但此法要求试剂能在示波极谱图上产生敏锐的切口。在微铂电极和铂片电极上进行示波极谱氧化还原滴定时,人们往往看到在滴定终点整个示波图发生突然变化,这种变化包括整个示波图的骤然扩大或缩小以及示波图位置的骤然移动。这种整个示波图的变化如此突然、灵敏,完全可用来指示滴定终点。在这里并不要求试剂在示波极谱图上产生切口。     

基于MEMS的流动主动控制技术及其研究进展

MEMS技术与流动控制技术的结合, 使得流动主动控制技术的实际应用逐步成为现实, 极大地推动了流动主动控制技术的发展. 简述了流动主动控制技术的基本原理、关键技术, 以及应用MEMS技术实现流动主动控制的机理和途径. 介绍了几家国外研究机构近年来在流动主动控制技术领域基于MEMS技术的微传感、微控制和微执行技术及其集成技术的研究进展, 以及在三角翼前沿涡控制、减阻研究、发动机喷流控制、细长体背风面分离流控制等方面的应用情况.      

CuCl2-KCl-LaCl3/γ-Al2O3对乙烷氧氯化反应的催化性能

 以γ-Al2O3为载体,采用常规浸渍法制备了负载型CuCl2-KCl-LaCl3三组分催化剂,并研究了其对乙烷氧氯化反应的催化性能. 结果表明,该催化体系中乙烷的转化率较稳定,但随着反应时间的延长,氯乙烯的选择性和收率明显下降. XRD,N2吸附,TGA/DTA和XPS测试结果表明,随着反应的进行,催化剂中的活性物种Cu2+逐渐被还原成Cu+,并且积炭的产生使催化剂的比表面积和孔容积减小. 活性物种Cu2+的减少及比表面积的降低是催化剂失活的主要原因.