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21.
Gijs Schaftenaar Elias Vlieg Gert Vriend 《Journal of computer-aided molecular design》2017,31(9):789-800
Since the first distribution of Molden in 1995 and the publication of the first article about this software in 2000 work on Molden has continued relentlessly. A few of the many improved or fully novel features such as improved and broadened support for quantum chemistry calculations, preparation of ligands for use in drug design related softwares, and working with proteins for the purpose of ligand docking. 相似文献
22.
Rutger J. I. Knoop Gijs J. M. Habraken Nicolas Gogibus Simone Steig Henning Menzel Cor E. Koning Andreas Heise 《Journal of polymer science. Part A, Polymer chemistry》2008,46(9):3068-3077
We have developed a metal free synthetic pathway to homopolypeptide rod‐coil block copolymers. The concept was proven for the synthesis of poly(benzyl‐L ‐glutamate‐b‐styrene). A dual initiator containing a primary amine and a nitroxide group was used in a macroinitiation approach with high initiation efficiency. Good control over the molecular weight in the ring opening polymerization of benzyl‐L ‐glutamate N‐carboxyanhydride was obtained in DMF at 0 °C yielding poly(benzyl‐L ‐glutamates) with low polydispersities around 1.1. The almost quantitative incorporation of the dual initiator was confirmed by MALDI‐ToF analysis. Macroinitiation of styrene by nitroxide‐mediated controlled radical polymerization yielded the block copolymer with high structural control. The diblock structure was confirmed by molecular weight increase upon macroinitiation by size exclusion chromatography and retention time comparison with homopolymers using gradient polymer elution chromatography. Both polymerizations were also successfully conducted in one pot without intermediate isolation owing to the high compatibility of both polymerization techniques. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3068–3077, 2008 相似文献
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The theoretical and experimental studies of the giant magnetoresistance effect in metallic magnetic multilayers with measuring current perpendicular to the interface planes are reviewed. Theoretical formalisms of electronic transport in the inhomogeneous electron gas are critically compared with emphasis on the perpendicular magnetoresistance in multilayers. The effects of interface roughness, potential steps at the interfaces, and realistic band structures are addressed. The experimental determination of the perpendicular resistance of metallic multilayers requires either low-resistance measurement techniques or microfabricated samples with enhanced resistances. The experimental methods known at present are discussed and, where possible, compared with each other. 相似文献
25.
Chaoqing Yang Karel Folens Gijs Du Laing Flavia Artizzu Rik Van Deun 《Advanced functional materials》2020,30(39)
Two of the most persistent challenges for the high‐end application of luminescent lanthanide (Ln) compounds are a low quantum yield and luminescence quenching caused by a liquid medium. In this work, a type of polymeric hydrogen‐bonded heptazine framework is developed incorporating trivalent europium ions (P‐HHF‐Eu) via a low‐cost and facile low‐temperature thermal condensation reaction. Structural characterization clearly reveals that the solid‐phase pyrolyzation reaction results in the formation of P‐HHF‐Eu. Using time‐resolved and steady state photoluminescence (PL) spectroscopies, the photophysics and photochemistry of P‐HHF‐Eu at different hydration degrees are investigated and the role of hydrogen bonding in the significant enhancement of the emission properties is demonstrated. Furthermore, the P‐HHF‐Eu particles suspended in polyvinyl alcohol hydrogel exhibit excellent luminescence stability with a high PL quantum yield of up to ≈46% and wavelength responsive color‐tunable emission, which holds potential for security applications. 相似文献
26.
Jawalekar AM Meeuwenoord N Cremers JS Overkleeft HS van der Marel GA Rutjes FP van Delft FL 《The Journal of organic chemistry》2008,73(1):287-290
A procedure is presented for copper(I)-catalyzed [3+2] cycloaddition of nucleosides and nucleotides in near-quantitative yield. Azido-alkyne cycloaddition was applied for the preparation of a range of adenosine dimers and derivatives with versatile functionality, as well as for the smooth condensation of two oligonucleotide strands. The described technology may find valuable application in the synthesis of oligonucleotide dimers and conjugates. 相似文献
27.
Lefteris G Gortzis Homer Papadopoulos Theo A Roelofs Stefan Rakowsky Dimitris Karnabatidis Dimitris Siablis Constantinos Makropoulos George Nikiforidis Georgi Graschew 《IEEE transactions on information technology in biomedicine》2007,11(5):597-599
Collaboration is a key requirement in several contemporary interventional radiology procedures (IRPs). This work proposes a multicast hybrid satellite system capable of supporting advanced IRP collaboration, and evaluates its feasibility and applicability. Following a detailed IRP requirements study, we have developed a system which supports IRP collaboration through the employment of a hybrid satellite-terrestrial network, a prototype multicast version of wavelet based interactive communication system (WinVicos) application, and a partition aggregation and conditional coding (PACC) wavelet codec. A semistructured questionnaire was also used to receive evaluative feedback from collaborating participants. The departments of interventional radiology of University Hospital of Patras, Greece and of Charite Hospital of Berlin, Germany have been connected on the system. Eight interventional radiologists and a vascular surgeon participated periodically in three satellite-terrestrial "fully collaborative" IRPs (average time 90 min) of high complexity and in four terrestrial educational sessions with great success, evidenced by considerable improving the IRP outcomes (clinical and educational). In case of high complexity, where the simultaneous presence of remote interventional expert and/or surgeon is required, advanced collaboration among staff of geographically dispersed international centers is feasible via integration of existing networking and other technologies. 相似文献
28.
Low‐Noise Multispectral Photodetectors Made from All Solution‐Processed Inorganic Semiconductors 下载免费PDF全文
Jesse R. Manders Tzung‐Han Lai Yanbin An Weikai Xu Jaewoong Lee Do Young Kim Gijs Bosman Franky So 《Advanced functional materials》2014,24(45):7205-7210
Infrared, visible, and multispectral photodetectors are important components for sensing, security and electronics applications. Current fabrication of these devices is based on inorganic materials grown by epitaxial techniques which are not compatible with low‐cost large‐scale processing. Here, air‐stable multispectral solution‐processed inorganic double heterostructure photodetectors, using PbS quantum dots (QDs) as the photoactive layer, colloidal ZnO nanoparticles as the electron transport/hole blocking layer (ETL/HBL), and solution‐derived NiO as the hole transport/electron blocking layer (HTL/EBL) are reported. The resulting device has low dark current density of 20 nA cm‐2 with a noise equivalent power (NEP) on the order of tens of picowatts across the detection spectra and a specific detectivity (D*) value of 1.2 × 1012 cm Hz1/2 W‐1. These parameters are comparable to commercially available Si, Ge, and InGaAs photodetectors. The devices have a linear dynamic range (LDR) over 65 dB and a bandwidth over 35 kHz, which are sufficient for imaging applications. Finally, these solution‐processed inorganic devices have a long storage lifetime in air, even without encapsulation. 相似文献
29.
Acenaphthylene-1-13C (1) rearranges at high temperatures in a flow system to give acenaphthylene-5-13C (2) and acenaphthylene-4-13C (3) in a 1:1 ratio as the primary products. This apparent migration of a labeled carbon atom from the bridge to the most remote sites in the molecule can be understood in terms of a benzenoid ring contraction mechanism. 相似文献
30.
W. S. Christian Roelofs Willem H. Adriaans René A. J. Janssen Martijn Kemerink Dago M. de Leeuw 《Advanced functional materials》2013,23(33):4133-4139
Light emission from ambipolar organic field‐effect transistors (OFETs) is often observed when they are operated in the unipolar regime. This is unexpected, the light emission should be completely suppressed, because in the unipolar regime only one type of charge carrier is accumulated. Here, an electroluminescent diketopyrrolopyrrole copolymer is investigated. Local potential measurements by scanning Kelvin probe microscopy reveal a recombination position that is unstable in time due to the presence of injection barriers. The electroluminescence and electrical transport have been numerically analyzed. It is shown that the counterintuitive unipolar light emission is quantitatively explained by injection of minority carriers into deep tail states of the semiconductor. The density of the injected minority carriers is small. Hence they are relatively immobile and they recombine close the contact with accumulated majority carriers. The unipolar light output is characterized by a constant efficiency independent of gate bias. It is argued that light emission from OFETs predominantly originates from the unipolar regime when the charge transport is injection limited. 相似文献