Cyclo- and cyclized diene polymers. XII. Cationic polymerization of isoprene

Polymerization of isoprene with Lewis acids in n-heptane is a process leading to a quasiequilibrium which is characterized by very low conversions. Polymerization rates in aromatic solvents are much higher due to extensive chain transfer with solvent with regeneration of the original active centers. The rate of monomer disappearance in benzene or toluene when aluminum bromide is the catalyst is second order with respect to monomer concentration. The reaction order with respect to the catalyst depends on the reaction conditions; at constant monomer concentration it is approximately one. Polymerization rates in halogenated solvents with the use of syringe techniques are much higher than those in aromatic solvents. Polymers obtained with various cationic catalysts ranged from oils to white powders having molecular weights up to more than 100,000 depending on reaction conditions. All polymers exhibited infrared spectra characteristic of cyclopolydienes, and the content of linear structures usually did not exceed 20%, irrespective of the nature of the catalyst or solvent. In solvents of higher polarity, such as o-dichlorobenzene, more linear structures were detected. Among residual linear forms the trans-1,4 addition was found to prevail. Residual unsaturation in polymers did not exceed 30%.     

AlEt3–metal soap catalysts for the polymerization of epoxides

Epoxides, propylene oxide in particular, were polymerized by a catalyst system consisting of AlEt₃–metal soap, to high molecular weight polyethers in high conversion. Carboxylic acid salts of Ti, V, Cr, Zr, Mo, Co, and Ni, transition metals of groups IV–VIII in the Periodic Table, were most preferable. Metal salts of stearic, octanoic, lauric and naphthenic acid were examined as catalyst components and proved to be very active for the polymerization of epoxides when used with an organoaluminum compound such as AlEt₃ or AlEt₂Cl. Copolymerization of propylene oxide and allyl glycidyl ether was successfully carried out with an AlEt₃–Zr octoate catalyst.     

Perturbation of fluorescence by nonspecific interactions between anionic poly(phenylenevinylene)s and proteins: implications for biosensors

The use of anionic water-soluble conjugated polymers (CPs) for sensing the presence of avidin by use of a biotin-modified fluorescence quencher was studied. The molecules involved in the study included poly[2-methoxy-5-(3'-propyloxysulfonate)-1,4-phenylenevinylene] with either lithium (Li+-MPS-PPV) or sodium (Na(+)-MPS-PPV) countercations, the well-defined oligomer pentasodium 1,4-bis(4'(2",4"-bis(butoxysulfonate)-styryl)-styryl)2-butoxysulfonate-5-methoxybenzene (5R5-), the quenchers N-methyl-4,4'-pyridylpyridinium iodide (mMV+) and [N-(biotinoyl)-N'-(acetyl 4,4'-pyridylpyridinium iodide)] ethylenediamine (BPP+), which contains a molecular recognition fragment (biotin) attached to a unit that accepts an electron from a CP excited state, and the proteins avidin, tau, BSA, and pepsin A. Fluorescence quenching experiments were examined in a variety of conditions. Experiments carried out in water and in ammonium carbonate buffer (which ensures avidin/biotin complexation) reveal that nonspecific interactions between the CP and the proteins cause substantial perturbations on the CP fluorescence. The overall findings are not consistent with a simple mechanism whereby avidin complexation of BPP+ leads to encapsulation of the quencher molecule and recovery of Li+-MPS-PPV fluorescence. Instead, we propose that binding of BPP+ to avidin results in the quenching unit attaching to a positively charged macromolecule. Electrostatic attraction to the negatively charged conjugated polymer results in closer proximity to the quencher. Therefore, more enhanced fluorescence quenching is observed.     

Optical-fiber-to-waveguide coupling using carbon-dioxide-laser-induced long-period fiber gratings

Optical fibers are expected to play a role in chip-level and board-level optical interconnects because of limitations on the bandwidth and level of integration of electrical interconnects. Therefore, methods are needed to couple optical fibers directly to waveguides on chips and on boards. We demonstrate optical-fiber-to-waveguide coupling using carbon-dioxide laser-induced long-period fiber gratings (LPFGs). Such gratings can be written in standard fiber and offer wavelength multiplexing-demultiplexing performance. The coupler fabrication process and the characterization apparatus are presented. The operation and the wavelength response of a LPFG-based optical-fiber-to-waveguide directional coupler are demonstrated.     

Electron waveguiding characteristics and ballistic current capacityof semiconductor quantum slabs

Semiconductor slab electron waveguides with and without spatially varying effective mass are analyzed using the single-band effective-mass equation. Starting with ballistic electron incidence on a potential energy/effective mass interface, expressions for the phase shift, the lateral shift, and the time delay upon total internal reflection are found. It is shown that heterostructure wells, homostructure voltage-induced wells, and heterostructure barriers can act as waveguides for ballistic electrons, and that the waveguiding is described by a single dispersion relation. The guided mode wave functions, dispersion curves, cutoffs, group velocity. effective mass, density of states, and ballistic guided current density are determined     

Nanostructure optical emitters based on quasibound electron energy levels

Given two energy states (levels) in a quantum well formed by two potential barriers of finite thickness, elementary quantum mechanics tells us that the lower energy state is more tightly bound than the upper state. This produces a longer spatial confinement lifetime in the lower state than in the upper state. This ratio of lifetimes is opposite to that needed for laser action between these states. Furthermore, the lifetime of the lower energy state must be significantly shorter than the electron scattering time for the upper state. These facts have blocked the development of lasers based on these transitions. However, in this paper we report experimental and analytical results on a versatile type of semiconductor heterostructure that overcomes these difficulties. Unlike previous devices, this structure relies on an optical transition between two states which are both above-barrier quasibound states in the ‘classical’ continuum. The oscillator strength is large and the operation of the device clearly demonstrates coherent electron wave behavior. Such structures could represent the basis for a new room-temperature infrared semiconductor laser.     

Board-level optical-to-electrical signal distribution at 10 gb/s

An opto/electrical prototype for on-board optical-to-electrical signal broadcasting operating at 10 Gb/s per channel over an interconnect distance of 10 cm is demonstrated. An improved 1/spl times/4 multimode interference (MMI) splitter at 1550 nm with linearly tapered output facet is heterogeneously integrated with four p-i-n photodetectors (PDs) on a silicon (Si) bench. The Si bench itself is hybrid integrated onto an FR-4 printed-circuit board with four receiver channels. A novel fabrication/integration approach demonstrates the simultaneous alignment between the four waveguides and the four PDs during the MMI fabrication process. The entire system is fully functional at 10 Gb/s.     

Loss measurement of plasmonic modes in planar metal-insulator-metal waveguides by an attenuated total reflection method

We report experimental excitation and characterization of surface plasmon modes in planar metal-insulator-metal (MIM) waveguides. Our approach is based on determining the width of the reflection angular spectrum in the attenuated total reflection (ATR) configuration. Owing to its transverse character, the ATR configuration provides a more straightforward and simpler way to determine the loss of plasmonic modes in MIM structures, compared to using tapered end couplers with multiple waveguide samples or scanning near-field optical microscopy. In this Letter, two waveguide structures with Au claddings and 50/200 nm SiO(2) cores are investigated. The propagation lengths measured at λ = 1.55 μm are 5.7 and 18 μm, respectively, in agreement with the theoretical predictions.     

Donor-Acceptor-Gleichgewichte bei der Copolymerisation. 44. Mitt. Copolymerisation von Styrol und α-Methylstyrol mit Acrylaten und (α-substituierten Acrylaten mit Al-Verbindungen

Ohne Zusammenfassung     

Digital processing capabilities using holographically recorded data pages in electro-optic crystals

Digital logic operations on holographically recorded binary data pages in electro-optic crystals as previously reported by others are summarized and extended. The basic logic operations available and processing capabilities are identified and discussed.