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131.
S. K. Chen A. Serquis G. Serrano K. A. Yates M. G. Blamire D. Guthrie J. Cooper H. Wang S. Margadonna J. L. MacManus‐Driscoll 《Advanced functional materials》2008,18(1):113-120
By applying a combination of characterisation tools, changes in structural and superconducting properties with nominal Mg non‐stoichiometry in MgxB2 are found. The non‐stoichiometry produces enhanced in‐field critical current densities (Jc's) and upper critical field / irreversibility field (Hc2/Hirr(T)) values. Upper critical fields of ~ 21 T (4.2 K) were obtained in nominal Mg‐deficient samples compared to ~ 17 T (4.2 K) for near‐stoichiometric samples. 相似文献
132.
Sungyong Kim Lingxin Chen Sangyeop Lee Gi Hun Seong Jaebum Choo Eun Kyu Lee Chil-Hwan Oh Sanghoon Lee 《Analytical sciences》2007,23(4):401-405
A rapid DNA analysis has been developed based on a fluorescence intensity change of a molecular beacon in a PDMS microfluidic channel. Recently, we reported a new analytical method of DNA hybridization involving a PDMS microfluidic sensor using fluorescence energy transfer (FRET). However, there are some limitations in its application to real DNA samples because the target DNA must be labelled with a suitable fluorescent dye. To resolve this problem, we have developed a new DNA microfluidic sensor using a molecular beacon. By monitoring the change in the restored fluorescence intensity along the channel length, it is possible to rapidly detect any hybridization of the molecular beacon to the target DNA. In this case, the target DNA does not need to be labelled. Our experimental results demonstrate that this microfluidic sensor using a molecular beacon is a promising diagnostic tool for rapid DNA hybridization analysis. 相似文献
133.
Xinjiang Chen Goh Matsuo Bunsho Ohtani Kaoru Tsujii 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4891-4900
A racemic amphiphilic monomer, n‐dodecyl glyceryl itaconate (DGI), forms bilayer membranes in water in the presence of small amount of ionic cosurfactant and shows iridescent color. A chiral DGI, S‐DGI, also shows an iridescent property, but with a rather red shift in the color, which can be ascribed to the increased packing density of the monomer in the bilayer membranes. Chrial DGI has a more compact packing density than racemic one owing to closer distance between the monomer molecules; the conversion rate, however, is slower than that of racemic one when H2O2 is used as an initiator. When the initiator is changed to an amphiphilic one, 4‐(2‐hydroxyethoxy) phenyl‐(2‐hydroxy‐2‐propyl) ketone (Irgacure 2959), the chiral DGI shows even a little faster conversion rate than that of racemic one. The NMR chemical shift results of protons in benzene ring show that the molecules of Irgacure 2959 insert into the bilayer membranes. The molecular weights of the corresponding polymers prove that the initiation by H2O2 is restricted compared to that by Irgacure 2959. It is concluded that the decelerated polymerization behavior of chiral DGI initiated by H2O2 is a result of limited diffusion of the initiator into the lamellar bilayer structures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4891–4900, 2007 相似文献
134.
徐州地区采暖教室内CO2污染影响因素分析 总被引:1,自引:1,他引:0
在徐州市采暖季节期间,实测3所高校3栋教学楼典型教室的室内CO2浓度、室内人员密度、室外空气流速等参数,分析不同状态的教室、不同的人员密度和不同的室外空气流速对室内CO2浓度的影响,提出改善采暖教室内CO2浓度的措施。 相似文献
135.
Rhythmic growth of ring‐banded spherulites in blends of liquid crystalline methoxy‐poly(aryl ether ketone) (M‐PAEK) and poly(aryl ether ether ketone) (PEEK) has been investigated by means of differential scanning calorimetry (DSC), polarized light microscopy (PLM), and scanning electron microscopy (SEM) techniques. The measurements reveal that the formation of the rhythmically grown ring‐banded spherulites in the M‐PAEK/PEEK blends is strongly dependent on the blend composition. In the M‐PAEK‐rich blends, upon cooling, an unusual ring‐banded spherulite is formed, which is ascribed to structural discontinuity caused by a rhythmic radial growth. For the 50:50 M‐PAEK/PEEK blend, ring‐banded spherulites and individual PEEK spherulites coexist in the system. In the blends with PEEK as the predominant component, M‐PAEK is rejected into the boundary of PEEK spherulites. The cooling rate and crystallization temperature have great effect on the phase behavior, especially the ring‐banded spherulite formation in the blends. In addition, the effects of M‐PAEK phase transition rate and phase separation rate on banded spherulite formation is discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3011–3024, 2007 相似文献
136.
Gujie Qian S. Baccaro M. Falconieri Jiafang Bei A. Cecilia Guorong Chen 《Journal of Non》2008,354(40-41):4626-4629
Glasses in SiO2–ZnO–BaO system with the different ZnO/BaO ratio were studied. In some cases, BaF2 was introduced to substitute for BaO on the equal base. Photoluminescent spectra showed that ZnO in glass matrices behaved somewhat differently from ZnO crystals. Especially, the introduction of fluorine ions led to dramatic shift of UV emission band of glasses closer to that of ZnO crystals. Raman spectral analysis provided consistent results. In particular, Raman bands in the high frequency region are sensitive to effects of different ZnO/BaO or BaF2/BaO ratio on structure of glasses. 相似文献
137.
Chengzhi Qi Mingyang Wang Qihu Qian Jianjie Chen 《Moscow University Mechanics Bulletin》2008,63(5):113-121
The formation mechanisms for the structural hierarchy in geological media are discussed. It is shown that the formation of such a hierarchy is caused by certain external and internal circumstances. The first ones consist in the fact that, because of external actions, the Earth’s poles continuously execute the translational and rotational motions responsible for a regular structure of rock fracture and for the appearance of the scale factor √2. The second ones consist in the fact that, under the action of many random factors and because of external actions, during the formation of geological media there appear dissipative structures and, hence, some self-similar fractal structures are formed. 相似文献
138.
Anti-BZ-Structure in Effect Algebras 总被引:1,自引:0,他引:1
The definitions of sharply approximating effect algebras, anti-BZ-effect algebras, central approximating effect algebras, and S-anti-BZ-effect algebras are given, the relationships between sharply approximating effect algebras and anti-BZ-effect algebras, between central approximating effect algebras and anti-BZ-effect algebras are established, and the set of anti-BZ-sharp elements in S-anti-BZ-effect algebras is proved to be an orthomodular lattice. 相似文献
139.
140.
相对于传统的数字滤波器实现方法,符号的2次幂和(SPT)滤波器用移位寄存器替代乘法器,因而资源消耗少、速度快,更加适于专用集成电路(ASIC)设计.介绍了一种适用于宽带码分多址(WCDMA)前向信道中给定基带成形滤波器单位脉冲响应后设计SPT滤波器的方法.相对于传统的理想SPT系数优化方法,此方法更适于给定单位脉冲响应后SPT滤波器的设计,计算复杂度低;仿真结果显示,相对于更加简单的四舍五入方法,此算法在性能上又有可观的增益. 相似文献