超细均分散稀土化合物胶粒的生长动力学

研究了尿素体系中超细均分散碳酸钕/碱式碳酸钇胶粒形成时, 粒子的尺寸随,以并运用Nielsen的时间因子分析法(Chronomal Analysis)表征了两种胶粒的生长机理, 获得了相应的速率常数。实验表明, 两种胶粒的生长(<40min)主要遵循表面反应控制的一级多核层增长机理。时间的变化规律     

Effects of Langmuir-Blodgett Film as Hole Transport Layer on Organic Electroluminescent Device Performance

Three types of organic electroluminescence(EL) cells with organic material FY as the EL-emitting layer and a copper phthalocyanine (CuPc) as the hole transport layer which were sandwiched between indium/tinoxde(ITO) and aluminum electrode have been fabricated by vacuum-vapor and Langmuir-Blodgett (LB) deposition:(a) ITO/FY/Al;(b)ITO/CuPc/FY/Al;(c) ITO/CuPc(LB)/FY/Al. It was found for the first time that the cell with the LB film as the hole transport layer has the highest luminescent intensity at the same bias-voltage. These results are attributed to the order orientation of the CuPc molecule in the layer of LB film.     

14β-甲磺酰氧基对映-贝壳杉二萜重排反应

本文研究了一类具有15-C与16-C单键的14β-甲磺酰氧基对映-贝壳杉烷(烯)(6,7和8)在Zn-EtOH体系中的重排反应, 它们均能重排成6, 7, 5, 5并环系统的化合物3, 12, 13a和13b。8重排时生成一个8-OEt化合物, 为这类化合物重排时经过阳离子中间体提供了一个证据。     

Properties of Above-Barrier Electronic States in Multi-Barrier structures

In the present work we report the detailed study of the above-barrier electronic states in the multi-barher structures by using the transfer matrix technique. The energy levels and the corresponding wavefunctions are calculated by solving the Schrodinger equation directly. Andy tical analysis is presented confirming the formation of sub band structure, similar to that determined by Kronig-Penney model. Each subband contains N energy states with N being the number of periods in the structure. Furthermore, our calculations demonstrate that in each subband there is one energy state whose wavefunction is always localized in the barrier regions, while others remain partly localized in general. These localized states satisfy the constructive condition k_bb = nπ in consistence with experiments, where kb is the wave vector in the barrier region, b is the barrier width, and n is an integer.     

Effect of Strong Electron-Phonon Interactions on an Interface Polaron

The present work deals with an electron interacting strongly with both bulk longitudinal optical (LO) phonons and interface (IF) optical phonons in which we adopt and generalize the Tokuda's variational method for studying the interface polaron properties in polar crystals at zero temperature, In our approach, we can reduce the Hamiltollian equation of the system to a pair of integro-differential equations in two variational parameters of the electron wavefunction from which we can calculate various physical properties of an interface polaron including the ground state energy, average numbers of interacting phonons, the average distance from the interface and the anisotropic effective masses of the interface polaron. Numerical results are obtained explicitly for LiF crystal interfaced with NaF crystal as well as other similar systems with varying physical constants, which show the typical trends of variations for the effects of strong electron-phonon interactions on different physical properties of an interface polaron.     

相似分析/质谱法鉴别二十种脂肪族双烯-1-醇及乙酸酯

本文报道了二十个脂肪族双烯-1-醇和乙酸酯EI-质谱的特征, 并提出了相似分析法鉴别这些共轭双烯、孤立双烯的双键位置及几何异构体的质谱。     

异苯橡胶环化反应动力学研究及产物微细结构表征

本文采用红外光谱法研究了前无报导的聚异苯橡胶环化反应动力学,测定了标题反应的动力学参数:反应级数n=1;活化能E_a=53.2kJ·mol^-1;指前因子A=2.24×10⁶min^-1,确立了该反应速率常数k_T与s反应温度T之间的函数关系为:Ln(k_T/min^-1)=14.62-6.40×10³K/T并采用核磁共振法分析了标题反应的产物环化异苯橡胶的微细结构,提出了标题反应的可能机理,并对活化能及指前因子进行了分析讨论。     

用衰减全反射红外二向色性表征聚环氧乙烷薄膜的表面取向

应用衰减全反射二向色性表征聚合物的表面取向,可不必测定样品的折光率使大多数实验简化.以聚环氧乙烷为例.用衰减全反射偏振红外光谱测定了它的表面二向色性比和计算了相应的取向函数.     

哌嗪-苯胺二环氧系感光性高分子的研究 Ⅰ.合成及其感光性

用哌嗪和N,N-二环氧丙基苯胺(苯胺二环氧)通过线型加成聚合反应,得到一种新型高分子。这种高分子与有机多卤化物所组成的感光体系,在近紫外光(300—400nm)的照射下,发色的同时交联固化。最低固化光量为78mJ·cm^-2。发色吸收峰初始为660nm,随曝光量增大,吸收增大,峰值向650nm俯移。所得蓝绿色图像可用稀酸显影。硫杂蒽酮类化合物是这些体系很有效的增感剂。     

THE RESPONSE OF A 3×3 BGO DETECTOR ARRAY TO 0.5—21MeV PHOTONS

An array of 9 BGO crystals of 20×20×200mm³ equipped with photomultiplier readout was assembled and tested. Radioactive γ and neutron sources, (p,γ) reactions by low energy protons from Van de Graaff accelerator and (n,γ) reactions by thermal neutrons from nuclear reactor were employed to produce photons in the energy range from 0.5 to 21MeV. The energy response of the array is shown to be linear over the whole range. Data on the energy resolution follow an E^1/2 dependence at low energies, and deviate from it at 4.43MeV and higher energies. Results from the lateral energy deposition of showers were compared with the predictions of the Monte Carlo simulation and found to be in good agreement. Our study demonstrates the feasibility of calibration and monitoring of BGO electromagnetic calorimeter by means of radioactive sources and low energy (p,γ) reactions.