热氧化磁控溅射金属锌膜合成一维ZnO纳米棒

利用退火热氧化射频磁控溅射金属锌膜的方法在Si(111)衬底上制备了一维Zn O纳米棒,同时用多种测试手段对样品的晶体结构、表面形貌和光学性能进行了研究.XRD,SEM和TEM的测试结果表明,Zn O纳米棒为单晶相六方纤锌矿结构,呈头簪状向外发散生长,直径在30～60 nm左右,其长度可达几μm.PL 谱测试结果表明:在波长为280 nm光的激发下,在372 nm处有强的近带边紫外光发射和516 nm处的较微弱深能级绿光发射.说明合成的一维Zn O纳米棒的结晶质量和光学性能优良     

Formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber blends: Effects of preparation method,composition, and thermal condition

The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007     

FHCF: A Simple and Efficient Scheduling Scheme for IEEE 802.11e Wireless LAN

The IEEE 802.11e medium access control (MAC) layer protocol is an emerging standard to support quality of service (QoS) in 802.11 wireless networks. Some recent work shows that the 802.11e hybrid coordination function (HCF) can improve significantly the QoS support in 802.11 networks. A simple HCF referenced scheduler has been proposed in the 802.11e which takes into account the QoS requirements of flows and allocates time to stations on the basis of the mean sending rate. As we show in this paper, this HCF referenced scheduling algorithm is only efficient and works well for flows with strict constant bit rate (CBR) characteristics. However, a lot of real-time applications, such as videoconferencing, have some variations in their packet sizes, sending rates or even have variable bit rate (VBR) characteristics. In this paper we propose FHCF, a simple and efficient scheduling algorithm for 802.11e that aims to be fair for both CBR and VBR flows. FHCF uses queue length estimations to tune its time allocation to mobile stations. We present analytical model evaluations and a set of simulations results, and provide performance comparisons with the 802.11e HCF referenced scheduler. Our performance study indicates that FHCF provides good fairness while supporting bandwidth and delay requirements for a large range of network loads. Pierre Ansel received a multidisciplinary in-depth scientific training in different fields such as Pure and Applied Mathematics, Physics, Mechanics, Computer Science and Economics from the Ecole Polytechnique, Palaiseau, France. Then, he joined the Ecole Nationale Superieure des Telecommunications, Paris, France in 2005 where he went further into electronics, databases, computer network security and high speed networks. He received a multidisciplinary master of sciences degree and an additional master of sciences degree in telecommunications in 2005. He did a summer internship in 2003 in INRIA, Sophia Antipolis, France where he worked on the Quality of Service in 802.11 networks at Planete Group, France. Then in 2004, he joined France Telecom R&D, Issy-les-Moulineaux, France to work on Intranet Security issues. He designed a WiFi security supervision architecture based on WiFi Intrusion Detection Sensors. He is currently a French civil servant and belongs to the French Telecommunications Corps. Qiang Ni received the B.Eng., M.Sc. and Ph.D. degrees from Hua Zhong University of Science and Technology (HUST), Wuhan City, China in 1993, 1996 and 1999 respectively. He is currently a faculty member in the Electronic and Computer Engineering Division,School of Engineering and Design, Brunel University, West London, U.K. Between 2004 and 2005 he was a Senior Researcher at the Hamilton Institute, National University of Ireland, Maynooth. From 1999 to 2001, he was a post-doctoral research fellow in the multimedia and wireless communication laboratory, HUST, China. He visited and conducted research at the wireless and networking group of Microsoft Research Asia Lab during the year of 2000. From Sept. 2001 until may 2004, he was a research staff member at the Planète group of INRIA Sophia Antipolis France. Since 2002, he has been active as a voting member at the IEEE 802.11 wireless LAN standard working group. His current research interests include communication protocol design and performance analysis for wireless networks, cross-layer optimizations, vertical handover and mobility management in mobile wireless networks, and adaptive multimedia transmission over hybrid wired/wireless networks. He has authored /co-authored over 40 international journal/conference papers, book chapters, and standard drafts in this field. He is a member of IEEE. E-mail: Qiang.Ni@ieee.org Thierry Turletti received the M.S. (1990) and the Ph.D. (1995) degrees in computer science both from the University of Nice – Sophia Antipolis, France. He has done his PhD studies in the RODEO group at INRIA Sophia Antipolis. During the year 1995–96, he was a postdoctoral fellow in the Telemedia, Networks and Systems group at LCS, MIT. He is currently a research scientist at the Planete group at INRIA Sophia Antipolis. His research interests include multimedia applications, congestion control and wireless networking. Dr. Turletti currently serves on the Editorial Board of Wireless Communications and Mobile Computing.     

白光干涉条纹变密的原因探讨

讨论了在测定透明介质折射率的过程中彩色条纹变密的现象，并在其基础上分析其成因：一是由于媒质折射率加大；二是由于平形板介质平行度不好造成楔形的倾角变大，最后在实验中验证了理论结果。     

Triterpenoid Constituents of Huperzia miyoshiana

Thirteen triterpenoids, including three new ones, miyoshianois A (1), B (2) and C (3), were isolated from Huperzia miyoshiana. The structures of these new compounds were established as 3-O-dihydroferuloyltohogenol (1), 16-oxo-3β,21β-dihydrox-y-serrat-14-en-24-ferulate (2) and 16-oxo-3a, 21β-dihydroxy-serrat-14-en-24-ferulate (3), respectively, on the basis of their spectroscopic analysis.     

Synthesis,X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru_3~Ⅲ(μ_3-O)(μ-CH_3COO)_6(py)_2Cl with Four Steps One-electron Redox Processes

Great attention is currently paid to the synthesis of polynuclear transition metal complexes as well as their photochemical, photophysical, and electrochemical properties. The design of multicomponent systems capable of performing useful light- and/or redox-induced function is of special interest1. The oxo-centered carboxylate-bridge trinuclear ruthenium clusters have been investigated extensively during recent decades because they have remarkable electron-transfer properties, intense visibl…     

Time-Resolved Femtosecond Degenerate Four-Wave Mixing in LiNbO3：Fe,Mg Crystal

Forward degenerate four-wave mixing （DFWM） processes are investigated with a femtosecond pulsed laser in lithium niobate crystal doubly-doped with magnesium and iron （LiNbO3：Fe, Mg）. The pulse energy dependence reveals a pure third-order nonlinear response, and the third-order nonlinear susceptibility x^（3） in the material is evaluated to be 4.96 × 10^-13 esu. The time-resolved DFWM process shows a response time of x^（3） shorter than 100fs, which is due to the nonresonant electronic nonlinearities. Our results indicate that LiNbO3 crystals have potentials for ultrafast real-time optical processing systems, which require a large and fast x^（3） optical nonlinearity.     

Endpoint estimates for certain commutators of fractional and singular integrals

In this paper, the authors obtain the endpoint estimates for a class of non-standard commutators with higher order remainders and their variants. Moreover, the authors show that these operators are actually not bounded in certain cases.

     

聚苯硫醚／石墨基双极板复合材料性能的研究

以聚苯硫醚树脂和人造石墨为原料一次模压成型制备双极板复合材料.研究了模压成型过程中加压时机、冷却方式及人造石墨原料对复合材料电导率和弯曲强度的影响.结果表明,制备聚苯硫醚/石墨基双极板材料宜选用石墨化程度较高且结构密实的石墨粉料;采用保温后加压及空气中冷却方式制备的复合材料的综合性能较优.     

微尺度效应对螺旋槽干气密封性能的影响

本文引用考虑微尺度效应的雷诺方程,推导出了考虑微尺度效应的螺旋槽干气密封内部流动的近似算法。应用本文提供的算法对文献中干气密封的不同实验工况进行了计算,与相应的实验数据对比,计算结果和实验结果基本符合;切向动量调节系数σv对计算结果在尺度越小时影响越大;考虑微尺度效应时开启力的计算结果更趋于实验数据。