基于DOE策略的多层薄膜残余应力对太赫兹微桥形变的影响

桥面多层膜系残余应力匹配是消除太赫兹微测辐射热计微桥结构形变的重要手段.仿真建立了像元尺寸为35μm×35μm微桥单元有限元模型.基于实验设计(DOE)正交法,采用IntelliSuite软件进行应力仿真,获得支撑层、钝化层、电极层、热敏层、吸收层应力分别为+200 Mpa、+200 Mpa、+200 Mpa、0 Mpa、-400 Mpa的最佳应力组合,最小微桥单元形变(0.0385μm).通过各膜层残余应力控制,制备出基于该优化微桥单元结构的320×240太赫兹焦平面阵列,获得与仿真结果相符的极小形变微桥.     

X射线条纹相机CsI光阴极的高能电子份额

为了得到X射线条纹相机中CsI光阴极的高能电子份额数据,通过蒙特卡罗方法建立模型来研究CsI光阴极在X射线照射下的光电发射特性.研究了CsI光阴极厚度为100～1 000 nm、入射X射线能量为1～30 keV时的二次电子(SE)能量分布.模拟结果显示,入射X射线的能量越高、CsI光阴极的厚度越大,从CsI光阴极出射的二次电子中高能电子(大于50 eV)的份额越高,在入射X射线能量为30 keV、CsI光阴极厚度为1 000 nm时,出射电子中的高能电子份额可以达到10.8％.但是当CsI光阴极厚度保持为100 nm、而入射X射线能量大于15 keV时,高能电子份额维持在3.4％左右而不再随入射X射线的能量增加而增加.     

基于分子内旋转受限原理的线性共轭小分子的AIE性能研究

研究了6个线性共轭化合物4-丁基联苯(L1)、4,4’-二异丙基联苯(L2)、5,5’-二甲基-2,2’-联吡啶(L3)、2-([1,1’-联苯]-4-)噻吩(L4)、1,1’-联萘(L5)和5-苯基-2,2’-联噻吩(L6)的紫外-可见光谱和荧光发射光谱。结果表明,化合物L1、L2和L3均具有聚集诱导发光(AIE)性能,化合物L4、L5和L6则不具有AIE性能。该研究结果表明,二联苯(或两个简单芳杂环相连)系列化合物具有AIE性能,分子内旋转受限(RIR)是该系化合物产生AIE现象的机理。但是在二联苯的结构基础上继续增加链的长度,或者引入体积更大的芳环(萘环),化合物不再具有AIE性能。     

Effects of surface residual species in SBA-16 on encapsulated chiral (1S,2S)-DPEN-RuCl<Subscript>2</Subscript>(TPP)<Subscript>2</Subscript> in asymmetric hydrogenation of acetophenone

The SBA-16 obtained by different routes of elimination of organic templates were used as the hosts for encapsulation of chiral Ru complex (1S,2S)-DPEN-RuCl₂(TPP)₂ (1) (DPEN = 1,2-diphenylethylene-diamine, TPP = triphenyl phosphine). The methods for removing templates had distinct effects on the amount of residual template in SBA-16, which made the SBA-16 with different surface and structure properties. 1 encapsulated in SBA-16 extracted with the mixture of pyridine and ethanol showed higher activity and enantioselectivity for acetophenone asymmetric hydrogenation.     

一种新型片上全差分电感的设计

提出了一种新型的片上全差分电感结构。电感采用全对称的几何形状,消除了传统差分电感因跳线引起的失配,提高了差分电感的性能。基于TSMC 0.18 μm RF CMOS工艺,对设计的全差分电感进行流片与测量,结果表明,差分电感两端口之间的失配量比传统差分电感下降了28%。     

基于电力线载波通信的智能用电管理系统设计

为了构建一个智能化小型电能网络,实现对用电设备的精确计量和远程控制,设计一套基于电力线载波通信的智能用电管理系统。系统整合了电能计量、电力线载波通信和继电器等模块,包含PLC插座,以S3C6410为智能网关核心,内嵌Web服务器,通过PC或移动终端可完成各种电器的远程监测和管理。测试结果表明,系统达到了设计要求,且结构简单,通信稳定,具有广泛的应用价值。     

Microstructure and optoelectronic properties of gallium- titanium-zinc oxide thin films deposited by magnetron sputtering

Gallium-titanium-zinc oxide(GTZO) transparent conducting oxide(TCO) thin films were deposited on glass substrates by radio frequency magnetron sputtering. The dependences of the microstructure and optoelectronic properties of GTZO thin films on Ar gas pressure were observed. The X-ray diffraction(XRD) and scanning electron microscopy(SEM) results show that all the deposited films are polycrystalline with a hexagonal structure and have a preferred orientation along the c-axis perpendicular to the substrate. With the increment of Ar gas pressure, the microstructure and optoelectronic properties of GTZO thin films will be changed. When Ar gas pressure is 0.4 Pa, the deposited films possess the best crystal quality and optoelectronic properties.     

一种幅度域处理抗干扰技术

幅度域处理技术是一种非线性预处理技术,该方法是建立在统计判决基础上,通过测量和利用干扰波形的统计性质以实现干扰信号的抑制,可以有效抑制除了宽带高斯干扰以外的多种干扰信号     

新型聚中性红膜修饰碳糊电极的制备、表征及应用

运用一种新型的化学引发-电聚合方式将中性红膜固定到碳糊电极表面,制备出聚中性红薄膜修饰碳糊电极(PNR/CPE)。利用循环伏安法(CV)和交流阻抗谱(EIS)对修饰电极的电化学性能进行研究,借助于扫描电子显微镜(SEM)对修饰电极表面进行表征,并采用红外吸收光谱法(IR)和紫外可见吸收光谱法(UV-Vis)对PNR薄膜结构进行测试。结果表明,中性红成功地固定在碳糊电极表面,修饰电极的表面呈现特定的立体化结构,表面的电活性位点增多,电催化性能增大。在优化条件下,将该电极应用于鲱鱼精DNA(hs DNA)的检测,PNR电极上出现了1对较强的氧化还原峰,峰电流与其浓度在1.0×10~(-6)~8.0×10~(-5)mol/L范围内呈良好的线性关系,检出限为1.0×10~(-7)mol/L。     

Synthesis and characterization of serial random and block-copolymers based on lactide and glycolide

The objective of this study is to investigate the properties of poly(lactide-co-glycolide) with different composition ratios and PLGA-PEG-PLGA copolymers synthesized by ring-opening polymerization method. Their compositions, crystallization properties, thermal and degradation behaviors, hydrophilicity and biocompatibility were studied. Our results demonstrate that poly(lactide-co-glycolide) with a 90% lactide and PLGA-PEG-PLGA show some crystallization properties. While as the decrease of lactide content in polymers, poly(lactide-co-glycolide) become amorphous, whereas, their hydrophilicity have been improved on the contrary. Compared to poly(lactide-co-glycolide), the PLGA-PEG-PLGA copolymer has a better hydrophilicity for the existence of polyethylene glycol block. Furthermore, both these polymers display easy controlled degradation properties and good cell compatibility.