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21.
Herein we present co-crystallisation as a strategy for materials discovery in the field of switchable spin crossover (SCO) systems. Using [Fe(3-bpp)2]·2A (where 3-bpp = 2,6-bis(pyrazol-3-yl)pyridine, A = BF4−/PF6−) as a starting point, a total of 11 new cocrystals have been synthesised with five different dipyridyl coformers. Eight of these systems show spin crossover behaviour, and all show dramatically different switching properties from the parent complex. The cocrystals have been studied by variable temperature single-crystal X-ray diffraction and SQUID magnetometry to develop structure–property relationships. The supramolecular architecture of the cocrystals depends on the properties of the coformer. With linear, rigid coformer molecules leading to 1D supramolecular hydrogen-bonded chains, while flexible coformers form 2D sheets and bent coformers yield 3D network structures. The SCO behaviour of the cocrystals can be modified through changing the coformer and thus co-crystallisation presents a rapid, facile and highly modular tool for the discovery of new switchable materials. The wider applicability of this strategy to the design of hybrid multifunctional materials is also discussed.The switching behaviour of spin crossover cocrystals can be modified through changing the coformer and thus co-crystallisation presents a rapid, facile and highly modular tool for the discovery of new switchable materials. 相似文献
22.
Hendargo HC Bower BA Reinstein AS Shepherd N Tao YK Izatt JA 《Optics Communications》2011,284(19):4847-4851
Spectral domain phase microscopy (SDPM) is an extension of spectral domain optical coherence tomography (SDOCT) that exploits the extraordinary phase stability of spectrometer-based systems with common-path geometry to resolve sub-wavelength displacements within a sample volume. This technique has been implemented for high resolution axial displacement and velocity measurements in biological samples, but since axial displacement information is acquired serially along the lateral dimension, it has been unable to measure fast temporal dynamics in extended samples. Depth-Encoded SDPM (DESDPM) uses multiple sample arms with unevenly spaced common path reference reflectors to multiplex independent SDPM signals from separate lateral positions on a sample simultaneously using a single interferometer, thereby reducing the time required to detect unique optical events to the integration period of the detector. Here, we introduce DESDPM and demonstrate the ability to acquire useful phase data concurrently at two laterally separated locations in a phantom sample as well as a biological preparation of spontaneously beating chick cardiomyocytes. DESDPM may be a useful tool for imaging fast cellular phenomena such as nervous conduction velocity or contractile motion. 相似文献
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Bornheim A Lipeles E Pappas SP Shapiro A Sun WM Weinstein AJ Masek G Paar HP Mahapatra R Morrison RJ Briere RA Chen GP Ferguson T Tatishvili G Vogel H Adam NE Alexander JP Bebek C Berkelman K Blanc F Boisvert V Cassel DG Drell PS Duboscq JE Ecklund KM Ehrlich R Gibbons L Gittelman B Gray SW Hartill DL Heltsley BK Hsu L Jones CD Kandaswamy J Kreinick DL Magerkurth A Mahlke-Krüger H Meyer TO Mistry NB Nordberg E Palmer M Patterson JR Peterson D Pivarski J Riley D Sadoff AJ Schwarthoff H 《Physical review letters》2002,88(23):231803
We report a new measurement of the Cabibbo-Kobayashi-Maskawa parameter Vub made with a sample of 9.7 x 10(6) BB- events collected with the CLEO II detector. Using heavy quark theory, we combine the observed yield of leptons from semileptonic B decay in the end-point momentum interval 2.2-2.6 GeV/c with recent CLEO II data on B-->X(s)gamma to find Vub = (4.08+/-0.34+/-0.44+/-0.16+/-0.24)x10(-3), where the first two uncertainties are experimental and the last two are from theory. 相似文献
25.
Taylor D.M. Bennett C.R. Shepherd T.J. Michaille L.F. Nielsen M.D. Simonsen H.R. 《Electronics letters》2006,42(6):331-332
A novel microstructured fibre has been created for use in an optical interconnection system. The fibre has low crosstalk with a high density of cores corresponding to 1150 channels/mm/sup 2/. A repeating pseudorandom binary sequence has been used to demonstrate a four-channel transmit/receive system using vertical cavity surface emitting lasers as both emitters and detectors. 相似文献
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I.W. Shepherd 《Physics letters. A》1973,45(4):297-298
Scattering of laser light from single magnons has been observed in the canted antiferromagnet FeF3 as a function of temperature (260 – 360°K) and wave-vector (2 × 105 ? 3 × 104cm?1). Measured magnon energies ranging up to 3.3 cm?1 (260°K) and line widths are in good agreement with data from microwave resonance work. 相似文献
30.
Phase locking and supermode selection in multicore photonic crystal fiber lasers with a large doped area 总被引:6,自引:0,他引:6
Michaille L Bennett CR Taylor DM Shepherd TJ Broeng J Simonsen HR Petersson A 《Optics letters》2005,30(13):1668-1670
We report on the laser properties of multicore photonic crystal fiber lasers. A stable phase locking of six- and seven-core structures through evanescent coupling is observed. Effective supermode selection is obtained by using both diffraction losses and the Talbot effect. A pure in-phase supermode is obtained (1.1 times diffraction limited). The laser operating in this mode has a slope efficiency of 70% with up to 44 W of output power. The modal area of the in-phase supermode multicore fiber is 1150 microm2, which makes it, to our knowledge, the single-mode fiber laser with the largest mode field area. In-phase laser action is stable when the fiber is bent. 相似文献