Optical Recording Properties of Metal-Azo Dye as Recording Medium with Super-Resolution Near-Field Structure

A novel metallized azo dye has been synthesized. The absorption spectra of the thin film and thermal characteristic are measured. Static optical recording properties with and without the Bi mask layer super-resolution near-field structure （Super-RENS） of the metal-azo dye are investigated. The results show that the metal-azo dye film has a broad absorbance band in the region of 450-650 nm and the maximum absorbance wavelength is located at 603 nm. It is also found that the new metallized azo dye occupies excellent thermal stability, initiatory decomposition temperature is at 270℃ and the mass loss is about 48% in a narrow temperature region （15℃）. The complex refractive index N （N = n ＋ iκ） is measured. High refractive index （n = 2.45） and low extinction coefficient （κ = 0.2） at the recording wavelength 65Ohm are attained. Static optical recording tests with and without Super-RENS are carried out using a 65Ohm semiconductor diode laser with recording power of 7mW and laser pulse duration of 200ns. The AFM images show that the diameter of recording mark on the dye film with the Bi mask layer is reduced about 42%, compared to that of recorded mark on the dye film without Super-RENS. It is indicated that Bi can well performed as a mask layer of the dye recording layer and the metallized azo dye can be a promising candidate for recording media with the super-resolution near-field structure.     

模块化蓝光光存储性能静态测试系统

蓝光光存储是信息存储领域发展的一个重要方向。测试系统是研究蓝光光存储材料的必备条件，为建立蓝光光存储研究平台，设计和搭建了一套模块化蓝光光存储性能静态测试系统。激光工作波长为406．7nm。系统采用调制解调技术降低系统噪声，提高测量粘度：采用光点移动模式降低对样品尺寸的要求；采用纳米平台提高记录点的反复定位性能。实验结果证明测试系统性能良好，可以满足蓝光光存储性能静态测试要求。     

瑶药野葛花中6种无机元素的测定

用原子吸收光谱法测定野葛花原生药、野葛花汤剂中的 Ca、Mg、Cu、Zn、Fe、Mn等 6种无机元素含量。结果表明 ,原药和水煎液中 Ca、Mg含量比较丰富 ;各种元素的煎出率存在着较大的差异 ,其中 Cu、Zn、Fe的煎出率较高 ,Zn最高 ,达到了 82 .5 6 % ;Ca最低 ,为 5 .5 8%。并且将其结果与葛根的无机元素做了比较。为探讨无机元素与中药药效之间的关系提供了基础数据。     

q←q~(-1)对称的非广延熵描述下的正则玻色子系综

将Abe引入的q q-1对称变形熵应用于玻色子的正则系综,根据最大熵原理和Lagrange乘子法,导出了系统的密度算子,进而在微变形的条件下求出了粒子数算符的期望值及其在高温、低温下的近似值。     

Effect of Ultrashort Pulsed Laser and X-Ray Irradiation on Au+ -Doped Glass

Au nanoparticles were precipitated inside Au+-doped glass samples after irradiation by femtosecond laser or x-ray. Femtosecond laser and X-ray irradiation result in decreasing of anneal temperature and critical size for the precipitation of Au nanoparticles.     

球墨铸铁材料对激光的吸收率

球墨铸铁因其优良性能而被广泛用作模具材料。对球墨铸铁冲压模具的激光表面处理已成为改善其耐磨性、提高使用寿命的重要方法。一定激光参量下吸收率的大小又直接影响到表面处理的质量。因此,确定球墨铸铁材料对激光的吸收率十分必要。通过热电偶测温,计算机数据采集系统进行定点温度采集,并结合数值模拟方法,对吸收率进行了标定,即首先根据预置的吸收率计算,预测被测点处的温度响应,并与实测响应比较,不断修正吸收率值,使预测温度响应和实验值吻合,由此获得吸收率。采用这种方法获得了球墨铸铁材料在大气条件下对激光的吸收率为23.3%。为激光处理球墨铸铁材料时工艺参量的选择和优化提供了一定参考。     

新型固液双重致孔球形离子交换剂的制备及其性能研究

以甲基丙烯酸缩水甘油酯为单体 ,采用固液联合致孔方式 ,通过一步悬浮聚合制备了一种新型双孔高分子球形载体 .经化学修饰后 ,得到含二乙胺羟丙基的阴离子交换剂 (介质A) .优化了制备条件 .并与用相同方法制备的但仅含有机溶剂致孔剂的介质B进行了比较 .介质A和B均具有较高的静态吸附容量和机械强度 .由于介质A内含有流动相可以对流通过的大孔 ,因此其动态吸附容量远高于介质B ,并且在较高的流速下表现出较好的色谱流动性能     

Influences of the Hydrophobicity of the Heme-binding Pocket on the Properties and Functions of Cytochrome b_5 Mutants

IntroductionElectrontransferreactionsarethekeystepsinphoto synthesis ,respirationandmanyotherbiochemicalprocess es.1Cytochromeb5isaredoxproteinexistingwidelyinnature ,whichactsasanelectron carrierduringvariouselectrontransferprocessesinthebiologicalsystem .2Cytochromeb5isamembraneproteinwithmolecularweightofapproximately 16kDa ,ofwhichthehydrophobicC terminaldomainanchorscytochromeb5tothemem brane ,andthehydrophilicN terminaldomaincontainshemeprostheticgroupandexhibitsthebiologicalfunctionsof…     

ADSORPTION OF 2,4-DICHLOROBENZOXYACETIC ACID ONTO HYPERCROSSLINKED RESIN MODIFIED BY PHENOLIC HYDROXYL GROUP (AM-1)

INTRODUCTIONAdsorption has been considered to be the best available technology for removing organics from water in the USSafe Drinking Water Act[1]. Due to many drawbacks of activated carbon[2-7], the most widely used adsorbent,hypercrosslinked polymeric adsorbents developed by Tsyurupa and Davankov[8] have been increasingly viewedas an alternative to activated carbon for selective removal of specific organic substances from contaminatedwater[9-12], and series of researches have been do…     

NITROXIDE-MEDIATED FREE RADICAL SYNTHESIS OF MESOGEN-JACKETED LIQUID CRYSTAL POLYMERS*

The first TEMPO-mediated "living" free radical polymerization of liquid crystallinemonomer, 2, 5-bis[(4-methoxyphenyl)oxycarbonyl]styrene(MPCS), was carried out at 130℃ withBPO as an initiator. The molecular weight of the polymer can be varied from rather low values to highvalues while maintaining narrow polydispersity. It was observed that the polymerization of MPCSproceeded much faster than that of styrene. A tentative explanation for this fast polymerization wassuggested.